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Title: Elements of Chemistry,
       In a New Systematic Order, Containing all the Modern Discoveries

Author: Antoine Lavoisier

Translator: Robert Kerr

Release Date: December 28, 2009 [EBook #30775]

Language: English

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ELEMENTS

OF

CHEMISTRY,

IN A

NEW SYSTEMATIC ORDER,

CONTAINING ALL THE

MODERN DISCOVERIES.

ILLUSTRATED WITH THIRTEEN COPPERPLATES.

By Mr LAVOISIER,

Member of the Academy of Sciences, Royal Society of Medicine, and Agricultural Society of Paris, of the Royal Society of London, and Philosophical Societies of Orleans, Bologna, Basil, Philadelphia, Haerlem, Manchester, &c. &c.

TRANSLATED FROM THE FRENCH,

By ROBERT KERR, F.R. & A.SS.E.

Member of the Royal College of Surgeons, and Surgeon to the Orphan Hospital of Edinburgh.
EDINBURGH: printed for WILLIAM CREECH, and sold in london by g. g. and j. j. robinsons.
MDCCXC.

[Pg v]

ADVERTISEMENT OF THE TRANSLATOR.

The very high character of Mr Lavoisier as a chemical philosopher, and the great revolution which, in the opinion of many excellent chemists, he has effected in the theory of chemistry, has long made it much desired to have a connected account of his discoveries, and of the new theory he has founded upon the modern experiments written by himself. This is now accomplished by the publication of his Elements of Chemistry; therefore no excuse can be at all necessary for giving the following work to the public in an English dress; and the only hesitation of the Translator is with regard to his own abilities for the task. He is most ready to confess, that his knowledge of the composition [Pg vi]of language fit for publication is far inferior to his attachment to the subject, and to his desire of appearing decently before the judgment of the world.

He has earnestly endeavoured to give the meaning of the Author with the most scrupulous fidelity, having paid infinitely greater attention to accuracy of translation than to elegance of stile. This last indeed, had he even, by proper labour, been capable of attaining, he has been obliged, for very obvious reasons, to neglect, far more than accorded with his wishes. The French copy did not reach his hands before the middle of September; and it was judged necessary by the Publisher that the Translation should be ready by the commencement of the University Session at the end of October.

He at first intended to have changed all the weights and measures used by Mr Lavoisier into their correspondent English denominations, but, upon trial, the task was found infinitely too great for the time allowed; and to have executed this part of the work inaccurately, must have been both useless and misleading to the reader. All that has been attempted in this way is adding, between brackets ( ), the degrees of Fahrenheit's[Pg vii] scale corresponding with those of Reaumeur's thermometer, which is used by the Author. Rules are added, however, in the Appendix, for converting the French weights and measures into English, by which means the reader may at any time calculate such quantities as occur, when desirous of comparing Mr Lavoisier's experiments with those of British authors.

By an oversight, the first part of the translation went to press without any distinction being preserved between charcoal and its simple elementary part, which enters into chemical combinations, especially with oxygen or the acidifying principle, forming carbonic acid. This pure element, which exists in great plenty in well made charcoal, is named by Mr Lavoisier carbone, and ought to have been so in the translation; but the attentive reader can very easily rectify the mistake. There is an error in Plate XI. which the engraver copied strictly from the original, and which was not discovered until the plate was worked off at press, when that part of the Elements which treats of the apparatus there represented came to be translated. The two tubes 21. and 24. by which the gas is conveyed[Pg viii] into the bottles of alkaline solution 22. 25. should have been made to dip into the liquor, while the other tubes 23. and 26. which carry off the gas, ought to have been cut off some way above the surface of the liquor in the bottles.

A few explanatory notes are added; and indeed, from the perspicuity of the Author, very few were found necessary. In a very small number of places, the liberty has been taken of throwing to the bottom of the page, in notes, some parenthetical expressions, only relative to the subject, which, in their original place, tended to confuse the sense. These, and the original notes of the Author, are distinguished by the letter A, and to the few which the Translator has ventured to add, the letter E is subjoined.

Mr Lavoisier has added, in an Appendix, several very useful Tables for facilitating the calculations now necessary in the advanced state of modern chemistry, wherein the most scrupulous accuracy is required. It is proper to give some account of these, and of the reasons for omitting several of them.[Pg ix]

No. I. of the French Appendix is a Table for converting ounces, gros, and grains, into the decimal fractions of the French pound; and No. II. for reducing these decimal fractions again into the vulgar subdivisions. No. III. contains the number of French cubical inches and decimals which correspond to a determinate weight of water.

The Translator would most readily have converted these Tables into English weights and measures; but the necessary calculations must have occupied a great deal more time than could have been spared in the period limited for publication. They are therefore omitted, as altogether useless, in their present state, to the British chemist.

No. IV. is a Table for converting lines or twelfth parts of the inch, and twelfth parts of lines, into decimal fractions, chiefly for the purpose of making the necessary corrections upon the quantities of gasses according to their barometrical pressure. This can hardly be at all useful or necessary, as the barometers used in Britain are graduated in decimal fractions of the inch, but, being referred to by the Author in[Pg x] the text, it has been retained, and is No. I. of the Appendix to this Translation.

No. V. Is a Table for converting the observed heights of water within the jars used in pneumato-chemical experiments into correspondent heights of mercury for correcting the volume of gasses. This, in Mr Lavoisier's Work, is expressed for the water in lines, and for the mercury in decimals of the inch, and consequently, for the reasons given respecting the Fourth Table, must have been of no use. The Translator has therefore calculated a Table for this correction, in which the water is expressed in decimals, as well as the mercury. This Table is No. II. of the English Appendix.

No. VI. contains the number of French cubical inches and decimals contained in the corresponding ounce-measures used in the experiments of our celebrated countryman Dr Priestley. This Table, which forms No. III. of the English Appendix, is retained, with the addition of a column, in which the corresponding English cubical inches and decimals are expressed.[Pg xi]

No. VII. Is a Table of the weights of a cubical foot and inch, French measure, of the different gasses expressed in French ounces, gros, grains, and decimals. This, which forms No. VI. of the English Appendix, has been, with considerable labour, calculated into English weight and measure.

No. VIII. Gives the specific gravities of a great number of bodies, with columns, containing the weights of a cubical foot and inch, French measure, of all the substances. The specific gravities of this Table, which is No. VII. of the English Appendix, are retained, but the additional columns, as useless to the British philosopher, are omitted; and to have converted these into English denominations must have required very long and painful calculations.

Rules are subjoined, in the Appendix to this translation, for converting all the weights and measures used by Mr Lavoisier into corresponding English denominations; and the Translator is proud to acknowledge his obligation to the learned Professor of Natural Philosophy in the University of Edinburgh, who kindly supplied him with the necessary information for this purpose. A Table is likewise added, No. IV. of[Pg xii] the English Appendix, for converting the degrees of Reaumeur's scale used by Mr Lavoisier into the corresponding degrees of Fahrenheit, which is universally employed in Britain[1].

This Translation is sent into the world with the utmost diffidence, tempered, however, with this consolation, that, though it must fall greatly short of the elegance, or even propriety of language, which every writer ought to endeavour to attain, it cannot fail of advancing the interests of true chemical science, by disseminating the accurate mode of analysis adopted by its justly celebrated Author. Should the public call for a second edition, every care shall be taken to correct the forced imperfections of the present translation, and to improve the work by valuable additional matter from other authors of reputation in the several subjects treated of.

Edinburgh,    }
Oct. 23. 1789. }

[Pg xiii]

PREFACE OF THE AUTHOR.

When I began the following Work, my only object was to extend and explain more fully the Memoir which I read at the public meeting of the Academy of Sciences in the month of April 1787, on the necessity of reforming and completing the Nomenclature of Chemistry. While engaged in this employment, I perceived, better than I had ever done before, the justice of the following maxims of the Abbé de Condillac, in his System of Logic, and some other of his works.

"We think only through the medium of words.—Languages are true analytical methods.—Algebra,[Pg xiv] which is adapted to its purpose in every species of expression, in the most simple, most exact, and best manner possible, is at the same time a language and an analytical method.—The art of reasoning is nothing more than a language well arranged."

Thus, while I thought myself employed only in forming a Nomenclature, and while I proposed to myself nothing more than to improve the chemical language, my work transformed itself by degrees, without my being able to prevent it, into a treatise upon the Elements of Chemistry.

The impossibility of separating the nomenclature of a science from the science itself, is owing to this, that every branch of physical science must consist of three things; the series of facts which are the objects of the science, the ideas which represent these facts, and the words by which these ideas are expressed. Like three impressions of the same seal, the word ought to produce the idea, and the idea to be a picture of the fact. And, as ideas are preserved and communicated by means of words, it necessarily follows[Pg xv] that we cannot improve the language of any science without at the same time improving the science itself; neither can we, on the other hand, improve a science, without improving the language or nomenclature which belongs to it. However certain the facts of any science may be, and, however just the ideas we may have formed of these facts, we can only communicate false impressions to others, while we want words by which these may be properly expressed.

To those who will consider it with attention, the first part of this treatise will afford frequent proofs of the truth of the above observations. But as, in the conduct of my work, I have been obliged to observe an order of arrangement essentially differing from what has been adopted in any other chemical work yet published, it is proper that I should explain the motives which have led me to do so.

It is a maxim universally admitted in geometry, and indeed in every branch of knowledge, that, in the progress of investigation, we should proceed from known facts to what is unknown. In early infancy, our ideas spring from our wants; the sensation of want excites the idea of[Pg xvi] the object by which it is to be gratified. In this manner, from a series of sensations, observations, and analyses, a successive train of ideas arises, so linked together, that an attentive observer may trace back to a certain point the order and connection of the whole sum of human knowledge.

When we begin the study of any science, we are in a situation, respecting that science, similar to that of children; and the course by which we have to advance is precisely the same which Nature follows in the formation of their ideas. In a child, the idea is merely an effect produced by a sensation; and, in the same manner, in commencing the study of a physical science, we ought to form no idea but what is a necessary consequence, and immediate effect, of an experiment or observation. Besides, he that enters upon the career of science, is in a less advantageous situation than a child who is acquiring his first ideas. To the child, Nature gives various means of rectifying any mistakes he may commit respecting the salutary or hurtful qualities of the objects which surround him. On every occasion his judgments are corrected by experience; want and pain are the necessary[Pg xvii] consequences arising from false judgment; gratification and pleasure are produced by judging aright. Under such masters, we cannot fail to become well informed; and we soon learn to reason justly, when want and pain are the necessary consequences of a contrary conduct.

In the study and practice of the sciences it is quite different; the false judgments we form neither affect our existence nor our welfare; and we are not forced by any physical necessity to correct them. Imagination, on the contrary, which is ever wandering beyond the bounds of truth, joined to self-love and that self-confidence we are so apt to indulge, prompt us to draw conclusions which are not immediately derived from facts; so that we become in some measure interested in deceiving ourselves. Hence it is by no means to be wondered, that, in the science of physics in general, men have often made suppositions, instead of forming conclusions. These suppositions, handed down from one age to another, acquire additional weight from the authorities by which they are supported, till at last they are received, even by men of genius, as fundamental truths.[Pg xviii]

The only method of preventing such errors from taking place, and of correcting them when formed, is to restrain and simplify our reasoning as much as possible. This depends entirely upon ourselves, and the neglect of it is the only source of our mistakes. We must trust to nothing but facts: These are presented to us by Nature, and cannot deceive. We ought, in every instance, to submit our reasoning to the test of experiment, and never to search for truth but by the natural road of experiment and observation. Thus mathematicians obtain the solution of a problem by the mere arrangement of data, and by reducing their reasoning to such simple steps, to conclusions so very obvious, as never to lose sight of the evidence which guides them.

Thoroughly convinced of these truths, I have imposed upon myself, as a law, never to advance but from what is known to what is unknown; never to form any conclusion which is not an immediate consequence necessarily flowing from observation and experiment; and always to arrange the facts, and the conclusions which are drawn from them, in such an order as shall render it most easy for beginners in the[Pg xix] study of chemistry thoroughly to understand them. Hence I have been obliged to depart from the usual order of courses of lectures and of treatises upon chemistry, which always assume the first principles of the science, as known, when the pupil or the reader should never be supposed to know them till they have been explained in subsequent lessons. In almost every instance, these begin by treating of the elements of matter, and by explaining the table of affinities, without considering, that, in so doing, they must bring the principal phenomena of chemistry into view at the very outset: They make use of terms which have not been defined, and suppose the science to be understood by the very persons they are only beginning to teach. It ought likewise to be considered, that very little of chemistry can be learned in a first course, which is hardly sufficient to make the language of the science familiar to the ears, or the apparatus familiar to the eyes. It is almost impossible to become a chemist in less than three or four years of constant application.

These inconveniencies are occasioned not so much by the nature of the subject, as by the method of teaching it; and, to avoid them, I[Pg xx] was chiefly induced to adopt a new arrangement of chemistry, which appeared to me more consonant to the order of Nature. I acknowledge, however, that in thus endeavouring to avoid difficulties of one kind, I have found myself involved in others of a different species, some of which I have not been able to remove; but I am persuaded, that such as remain do not arise from the nature of the order I have adopted, but are rather consequences of the imperfection under which chemistry still labours. This science still has many chasms, which interrupt the series of facts, and often render it extremely difficult to reconcile them with each other: It has not, like the elements of geometry, the advantage of being a complete science, the parts of which are all closely connected together: Its actual progress, however, is so rapid, and the facts, under the modern doctrine, have assumed so happy an arrangement, that we have ground to hope, even in our own times, to see it approach near to the highest state of perfection of which it is susceptible.

The rigorous law from which I have never deviated, of forming no conclusions which are not fully warranted by experiment, and of never[Pg xxi] supplying the absence of facts, has prevented me from comprehending in this work the branch of chemistry which treats of affinities, although it is perhaps the best calculated of any part of chemistry for being reduced into a completely systematic body. Messrs Geoffroy, Gellert, Bergman, Scheele, De Morveau, Kirwan, and many others, have collected a number of particular facts upon this subject, which only wait for a proper arrangement; but the principal data are still wanting, or, at least, those we have are either not sufficiently defined, or not sufficiently proved, to become the foundation upon which to build so very important a branch of chemistry. This science of affinities, or elective attractions, holds the same place with regard to the other branches of chemistry, as the higher or transcendental geometry does with respect to the simpler and elementary part; and I thought it improper to involve those simple and plain elements, which I flatter myself the greatest part of my readers will easily understand, in the obscurities and difficulties which still attend that other very useful and necessary branch of chemical science.

Perhaps a sentiment of self-love may, without my perceiving it, have given additional force to[Pg xxii] these reflections. Mr de Morveau is at present engaged in publishing the article Affinity in the Methodical Encyclopædia; and I had more reasons than one to decline entering upon a work in which he is employed.

It will, no doubt, be a matter of surprise, that in a treatise upon the elements of chemistry, there should be no chapter on the constituent and elementary parts of matter; but I shall take occasion, in this place, to remark, that the fondness for reducing all the bodies in nature to three or four elements, proceeds from a prejudice which has descended to us from the Greek Philosophers. The notion of four elements, which, by the variety of their proportions, compose all the known substances in nature, is a mere hypothesis, assumed long before the first principles of experimental philosophy or of chemistry had any existence. In those days, without possessing facts, they framed systems; while we, who have collected facts, seem determined to reject them, when they do not agree with our prejudices. The authority of these fathers of human philosophy still carry great weight, and there is reason to fear that it will even bear hard upon generations yet to come.[Pg xxiii]

It is very remarkable, that, notwithstanding of the number of philosophical chemists who have supported the doctrine of the four elements, there is not one who has not been led by the evidence of facts to admit a greater number of elements into their theory. The first chemists that wrote after the revival of letters, considered sulphur and salt as elementary substances entering into the composition of a great number of substances; hence, instead of four, they admitted the existence of six elements. Beccher assumes the existence of three kinds of earth, from the combination of which, in different proportions, he supposed all the varieties of metallic substances to be produced. Stahl gave a new modification to this system; and succeeding chemists have taken the liberty to make or to imagine changes and additions of a similar nature. All these chemists were carried along by the influence of the genius of the age in which they lived, which contented itself with assertions without proofs; or, at least, often admitted as proofs the slighted degrees of probability, unsupported by that strictly rigorous analysis required by modern philosophy.[Pg xxiv]

All that can be said upon the number and nature of elements is, in my opinion, confined to discussions entirely of a metaphysical nature. The subject only furnishes us with indefinite problems, which may be solved in a thousand different ways, not one of which, in all probability, is consistent with nature. I shall therefore only add upon this subject, that if, by the term elements, we mean to express those simple and indivisible atoms of which matter is composed, it is extremely probable we know nothing at all about them; but, if we apply the term elements, or principles of bodies, to express our idea of the last point which analysis is capable of reaching, we must admit, as elements, all the substances into which we are capable, by any means, to reduce bodies by decomposition. Not that we are entitled to affirm, that these substances we consider as simple may not be compounded of two, or even of a greater number of principles; but, since these principles cannot be separated, or rather since we have not hitherto discovered the means of separating them, they act with regard to us as simple substances, and we ought never to suppose them compounded until experiment and observation has proved them to be so.[Pg xxv]

The foregoing reflections upon the progress of chemical ideas naturally apply to the words by which these ideas are to be expressed. Guided by the work which, in the year 1787, Messrs de Morveau, Berthollet, de Fourcroy, and I composed upon the Nomenclature of Chemistry, I have endeavoured, as much as possible, to denominate simple bodies by simple terms, and I was naturally led to name these first. It will be recollected, that we were obliged to retain that name of any substance by which it had been long known in the world, and that in two cases only we took the liberty of making alterations; first, in the case of those which were but newly discovered, and had not yet obtained names, or at least which had been known but for a short time, and the names of which had not yet received the sanction of the public; and, secondly, when the names which had been adopted, whether by the ancients or the moderns, appeared to us to express evidently false ideas, when they confounded the substances, to which they were applied, with others possessed of different, or perhaps opposite qualities. We made no scruple, in this case, of substituting other names in their room, and the greatest number of these were borrowed from the Greek language. We[Pg xxvi] endeavoured to frame them in such a manner as to express the most general and the most characteristic quality of the substances; and this was attended with the additional advantage both of assisting the memory of beginners, who find it difficult to remember a new word which has no meaning, and of accustoming them early to admit no word without connecting with it some determinate idea.

To those bodies which are formed by the union of several simple substances we gave new names, compounded in such a manner as the nature of the substances directed; but, as the number of double combinations is already very considerable, the only method by which we could avoid confusion, was to divide them into classes. In the natural order of ideas, the name of the class or genus is that which expresses a quality common to a great number of individuals: The name of the species, on the contrary, expresses a quality peculiar to certain individuals only.

These distinctions are not, as some may imagine, merely metaphysical, but are established by Nature. "A child," says the Abbé de Condillac,[Pg xxvii] "is taught to give the name tree to the first one which is pointed out to him. The next one he sees presents the same idea, and he gives it the same name. This he does likewise to a third and a fourth, till at last the word tree, which he first applied to an individual, comes to be employed by him as the name of a class or a genus, an abstract idea, which comprehends all trees in general. But, when he learns that all trees serve not the same purpose, that they do not all produce the same kind of fruit, he will soon learn to distinguish them by specific and particular names." This is the logic of all the sciences, and is naturally applied to chemistry.

The acids, for example, are compounded of two substances, of the order of those which we consider as simple; the one constitutes acidity, and is common to all acids, and, from this substance, the name of the class or the genus ought to be taken; the other is peculiar to each acid, and distinguishes it from the rest, and from this substance is to be taken the name of the species. But, in the greatest number of acids, the two constituent elements, the acidifying principle,[Pg xxviii] and that which it acidifies, may exist in different proportions, constituting all the possible points of equilibrium or of saturation. This is the case in the sulphuric and the sulphurous acids; and these two states of the same acid we have marked by varying the termination of the specific name.

Metallic substances which have been exposed to the joint action of the air and of fire, lose their metallic lustre, increase in weight, and assume an earthy appearance. In this state, like the acids, they are compounded of a principle which is common to all, and one which is peculiar to each. In the same way, therefore, we have thought proper to class them under a generic name, derived from the common principle; for which purpose, we adopted the term oxyd; and we distinguish them from each other by the particular name of the metal to which each belongs.

Combustible substances, which in acids and metallic oxyds are a specific and particular principle, are capable of becoming, in their turn, common principles of a great number of substances. The sulphurous combinations have[Pg xxix] been long the only known ones in this kind. Now, however, we know, from the experiments of Messrs Vandermonde, Monge, and Berthollet, that charcoal may be combined with iron, and perhaps with several other metals; and that, from this combination, according to the proportions, may be produced steel, plumbago, &c. We know likewise, from the experiments of M. Pelletier, that phosphorus may be combined with a great number of metallic substances. These different combinations we have classed under generic names taken from the common substance, with a termination which marks this analogy, specifying them by another name taken from that substance which is proper to each.

The nomenclature of bodies compounded of three simple substances was attended with still greater difficulty, not only on account of their number, but, particularly, because we cannot express the nature of their constituent principles without employing more compound names. In the bodies which form this class, such as the neutral salts, for instance, we had to consider, 1st, The acidifying principle, which is common to them all; 2d, The acidifiable principle which constitutes their peculiar acid; 3d, The saline,[Pg xxx] earthy, or metallic basis, which determines the particular species of salt. Here we derived the name of each class of salts from the name of the acidifiable principle common to all the individuals of that class; and distinguished each species by the name of the saline, earthy, or metallic basis, which is peculiar to it.

A salt, though compounded of the same three principles, may, nevertheless, by the mere difference of their proportion, be in three different states. The nomenclature we have adopted would have been defective, had it not expressed these different states; and this we attained chiefly by changes of termination uniformly applied to the same state of the different salts.

In short, we have advanced so far, that from the name alone may be instantly found what the combustible substance is which enters into any combination; whether that combustible substance be combined with the acidifying principle, and in what proportion; what is the state of the acid; with what basis it is united; whether the saturation be exact, or whether the acid or the basis be in excess.[Pg xxxi]

It may be easily supposed that it was not possible to attain all these different objects without departing, in some instances, from established custom, and adopting terms which at first sight will appear uncouth and barbarous. But we considered that the ear is soon habituated to new words, especially when they are connected with a general and rational system. The names, besides, which were formerly employed, such as powder of algaroth, salt of alembroth, pompholix, phagadenic water, turbith mineral, colcathar, and many others, were neither less barbarous nor less uncommon. It required a great deal of practice, and no small degree of memory, to recollect the substances to which they were applied, much more to recollect the genus of combination to which they belonged. The names of oil of tartar per deliquium, oil of vitriol, butter of arsenic and of antimony, flowers of zinc, &c. were still more improper, because they suggested false ideas: For, in the whole mineral kingdom, and particularly in the metallic class, there exists no such thing as butters, oils, or flowers; and, in short, the substances to which they give these fallacious names, are nothing less than rank poisons.[Pg xxxii]

When we published our essay on the nomenclature of chemistry, we were reproached for having changed the language which was spoken by our masters, which they distinguished by their authority, and handed down to us. But those who reproach us on this account, have forgotten that it was Bergman and Macquer themselves who urged us to make this reformation. In a letter which the learned Professor of Upsal, M. Bergman, wrote, a short time before he died, to M. de Morveau, he bids him spare no improper names; those who are learned, will always be learned, and those who are ignorant will thus learn sooner.

There is an objection to the work which I am going to present to the public, which is perhaps better founded, that I have given no account of the opinion of those who have gone before me; that I have stated only my own opinion, without examining that of others. By this I have been prevented from doing that justice to my associates, and more especially to foreign chemists, which I wished to render them. But I beseech the reader to consider, that, if I had filled an elementary work with a multitude of quotations; if I had allowed myself to enter into[Pg xxxiii] long dissertations on the history of the science, and the works of those who have studied it, I must have lost sight of the true object I had in view, and produced a work, the reading of which must have been extremely tiresome to beginners. It is not to the history of the science, or of the human mind, that we are to attend in an elementary treatise: Our only aim ought to be ease and perspicuity, and with the utmost care to keep every thing out of view which might draw aside the attention of the student; it is a road which we should be continually rendering more smooth, and from which we should endeavour to remove every obstacle which can occasion delay. The sciences, from their own nature, present a sufficient number of difficulties, though we add not those which are foreign to them. But, besides this, chemists will easily perceive, that, in the first part of my work, I make very little use of any experiments but those which were made by myself: If at any time I have adopted, without acknowledgment, the experiments or the opinions of M. Berthollet, M. Fourcroy, M. de la Place, M. Monge, or, in general, of any of those whose principles are the same with my own, it is owing to this circumstance, that frequent intercourse, and the habit of communicating our[Pg xxxiv] ideas, our observations, and our way of thinking to each other, has established between us a sort of community of opinions, in which it is often difficult for every one to know his own.

The remarks I have made on the order which I thought myself obliged to follow in the arrangement of proofs and ideas, are to be applied only to the first part of this work. It is the only one which contains the general sum of the doctrine I have adopted, and to which I wished to give a form completely elementary.

The second part is composed chiefly of tables of the nomenclature of the neutral salts. To these I have only added general explanations, the object of which was to point out the most simple processes for obtaining the different kinds of known acids. This part contains nothing which I can call my own, and presents only a very short abridgment of the results of these processes, extracted from the works of different authors.

In the third part, I have given a description, in detail, of all the operations connected with modern chemistry. I have long thought that a[Pg xxxv] work of this kind was much wanted, and I am convinced it will not be without use. The method of performing experiments, and particularly those of modern chemistry, is not so generally known as it ought to be; and had I, in the different memoirs which I have presented to the Academy, been more particular in the detail of the manipulations of my experiments, it is probable I should have made myself better understood, and the science might have made a more rapid progress. The order of the different matters contained in this third part appeared to me to be almost arbitrary; and the only one I have observed was to class together, in each of the chapters of which it is composed, those operations which are most connected with one another. I need hardly mention that this part could not be borrowed from any other work, and that, in the principal articles it contains, I could not derive assistance from any thing but the experiments which I have made myself.

I shall conclude this preface by transcribing, literally, some observations of the Abbé de Condillac, which I think describe, with a good deal of truth, the state of chemistry at a period not far distant from our own. These observations[Pg xxxvi] were made on a different subject; but they will not, on this account, have less force, if the application of them be thought just.

'Instead of applying observation to the things we wished to know, we have chosen rather to imagine them. Advancing from one ill founded supposition to another, we have at last bewildered ourselves amidst a multitude of errors. These errors becoming prejudices, are, of course, adopted as principles, and we thus bewilder ourselves more and more. The method, too, by which we conduct our reasonings is as absurd; we abuse words which we do not understand, and call this the art of reasoning. When matters have been brought this length, when errors have been thus accumulated, there is but one remedy by which order can be restored to the faculty of thinking; this is, to forget all that we have learned, to trace back our ideas to their source, to follow the train in which they rise, and, as my Lord Bacon says, to frame the human understanding anew.

'This remedy becomes the more difficult in proportion as we think ourselves more learned.[Pg xxxvii] Might it not be thought that works which treated of the sciences with the utmost perspicuity, with great precision and order, must be understood by every body? The fact is, those who have never studied any thing will understand them better than those who have studied a great deal, and especially than those who have written a great deal.'

At the end of the fifth chapter, the Abbé de Condillac adds: 'But, after all, the sciences have made progress, because philosophers have applied themselves with more attention to observe, and have communicated to their language that precision and accuracy which they have employed in their observations: In correcting their language they reason better.'

[Pg xxxix]

CONTENTS.

PART FIRST.

Of the Formation and Decomposition of Aëriform Fluids,
    —of the Combustion of Simple Bodies, and the Formation of Acids, Page 1

CHAP. I.—Of the Combinations of Caloric, and the Formation of Elastic Aëriform Fluids or Gasses, ibid.

CHAP. II.—General Views relative to the Formation and Composition of our Atmosphere, 26

CHAP. III.—Analysis of Atmospheric Air, and its Division into two Elastic Fluids;
     one fit for Respiration, the other incapable of being respired, 32

CHAP. IV.—Nomenclature of the several constituent Parts of Atmospheric Air, 48

CHAP. V.—Of the Decomposition of Oxygen Gas by Sulphur,
     Phosphorus, and Charcoal, and [Pg xl]of the Formation of Acids in general, 54

CHAP. VI.—Of the Nomenclature of Acids in general, and particularly of those drawn from Nitre and Sea Salt, 66

CHAP. VII.—Of the Decomposition of Oxygen Gas
     by means of Metals, and the Formation of Metallic Oxyds, 78

CHAP. VIII.—Of the Radical Principle of Water, and of its Decomposition by Charcoal and Iron, 83

CHAP. IX.—Of the Quantities of Caloric disengaged from different Species of Combustion, 97

Combustion of Phosphorus, 100

SECT. I.—Combustion of Charcoal, 101

SECT. II.—Combustion of Hydrogen Gas, 102

SECT. III.—Formation of Nitric Acid, 102

SECT. IV.—Combustion of Wax, 105

SECT. V.—Combustion of Olive Oil, 106

CHAP. X.—Of the Combustion of Combustible Substances with each other, 109

CHAP. XI.—Observations upon Oxyds and Acids with several Bases,
    and upon the Composition of Animal and Vegetable Substances, 115

CHAP. XII.—Of the Decomposition of Vegetable and Animal Substances by the Action of Fire, 123

CHAP. XIII.—Of the Decomposition of Vegetable Oxyds by the Vinous Fermentation, 129

CHAP. XIV.—Of the Putrefactive Fermentation, 141

CHAP. XV.—Of the Acetous Fermentation, 146

CHAP. XVI.—Of the Formation of Neutral Salts, and of their Bases, 149
[Pg xli]
SECT. I.—Of Potash, 151

SECT. II.—Of Soda, 155

SECT. III.—Of Ammoniac, 156

SECT. IV.—Of Lime, Magnesia, Barytes, and Argill, 157

SECT. V.—Of Metallic Bodies, 159

CHAP. XVII.—Continuation of the Observations upon Salifiable Bases, and the Formation of Neutral Salts, 161


PART II.

Of the Combinations of Acids with Salifiable Bases, and of the Formation of Neutral Salts, 175

INTRODUCTION, ibid.

TABLE of Simple Substances, 175

SECT. I.—Observations upon simple Substances, 176

TABLE of Compound Oxydable and Acidifiable Bases, 179

SECT. II.—Observations upon Compound Radicals, 180

SECT. III.—Observations upon the Combinations of Light and Caloric with different Substances, 182

[Pg xlii] TABLE of the Combinations of Oxygen with the Simple Substances, to face 185

SECT. IV.—Observations upon these Combinations, 185

TABLE of the Combinations of Oxygen with Compound Radicals, 190

SECT. V.—Observations upon these Combinations, 191

TABLE of the Combinations of Azote with the Simple Substances, 194

SECT VI.—Observations upon these Combinations of Azote, 195

TABLE of the Combinations of Hydrogen with Simple Substances, 198

SECT. VII.—Observations upon Hydrogen, and its Combinations, 199

TABLE of the Binary Combinations of Sulphur with the Simple Substances, 202

SECT. VIII.—Observations upon Sulphur, and its Combinations, 203

TABLE of the Combinations of Phosphorus with Simple Substances, 204

SECT. IX.—Observations upon Phosphorus and its Combinations, 205

TABLE of the Binary Combinations of Charcoal, 207

SECT. X.—Observations upon Charcoal, and its Combinations, 208

SECT. XI.—Observations upon the Muriatic, Fluoric, and Boracic Radicals, and their Combinations, 209

[Pg xliii] SECT. XII.—Observations upon the Combinations of Metals with each other, 219

TABLE of the Combinations of Azote, in the State of Nitrous Acid, with the Salifiable Bases, 212

TABLE of the Combinations of Azote, in the State of Nitric Acid, with the Salifiable Bases, 213

SECT. XIII.—Observations upon Nitrous and Nitric Acids, and their Combinations with Salifiable Bases, 214

TABLE of the Combinations of Sulphuric Acid with the Salifiable Bases, 218

SECT. XIV.—Observations upon Sulphuric Acid, and its Combinations, 219

TABLE of the Combinations of Sulphurous Acid, 222

SECT. XV.—Observations upon Sulphurous Acid, and its Combinations with Salifiable Bases, 223

TABLE of the Combinations of Phosphorous and Phosphoric Acids, 225

SECT. XVI.—Observations upon Phosphorous and Phosphoric Acids, and their Combinations with Salifiable Bases, 226

TABLE of the Combinations of Carbonic Acid, 228

SECT. XVII.—Observations upon Carbonic Acid, and its Combinations with Salifiable Bases, 229

TABLE of the Combinations of Muriatic Acid, 231

TABLE of the Combinations of Oxygenated Muriatic Acid, 232

[Pg xliv] SECT. XVIII.—Observations upon Muriatic and Oxygenated Muriatic Acid,
     and their Combinations with Salifiable Bases, 233

TABLE of the Combinations of Nitro-Muriatic Acid, 236

SECT. XIX.—Observations upon Nitro-muriatic Acid, and its Combinations with Salifiable Bases, 237

TABLE of the Combinations of Fluoric Acid, 239

SECT. XX.—Observations upon Fluoric Acid, and its Combinations with Salifiable Bases, 240

TABLE of the Combinations of Boracic Acid, 242

SECT. XXI.—Observations upon Boracic Acid, and its Combinations with Salifiable Bases, 243

TABLE of the Combinations of Arseniac Acid, 246

SECT. XXII.—Observations upon Arseniac Acid, and its Combinations with Salifiable Bases, 247

SECT. XXIII.—Observations upon Molibdic Acid, and its Combinations with Salifiable Bases, 249

SECT. XXIV.—Observations upon Tungstic Acid, and its Combinations with Salifiable Bases,
     and a Table of these in the order of their Affinity, 251

TABLE of the Combinations of Tartarous Acid, 253

SECT. XXV.—Observations upon Tartarous Acid, and its Combinations with Salifiable Bases, 254

SECT. XXVI.—Observations upon Mallic Acid, and its Combinations with Salifiable Bases, 256

TABLE of the Combinations of Citric Acid, 258

SECT. XXVII.—Observations upon Citric Acid, and its Combinations with Salifiable Bases, 259

[Pg xlv] TABLE of the Combinations of Pyro-lignous Acid, 260

SECT. XXVIII.—Observations upon Pyro-lignous Acid, and its Combinations with Salifiable Bases, 261

SECT. XXIX.—Observations upon Pyro-tartarous Acid, and its Combinations with Salifiable Bases, ibid.

TABLE of the Combinations of Pyro-mucous Acid, 263

SECT. XXX.—Observations upon Pyro-mucous Acid, and its Combinations with Salifiable Bases, 264

TABLE of the Combinations of Oxalic Acid, 265

SECT. XXXI.—Observations upon Oxalic Acid, and its Combinations with Salifiable Bases, 266

TABLE of the Combinations of Acetous Acid, to face 267

SECT. XXXII.—Observations upon Acetous Acid, and its Combinations with the Salifiable Bases, 267

TABLE of the Combinations of Acetic Acid, 271

SECT. XXXIII.—Observations upon Acetic Acid, and its Combinations with Salifiable Bases, 272

TABLE of the Combinations of Succinic Acid, 273

SECT. XXXIV.—Observations upon Succinic Acid, and its Combinations with Salifiable Bases, 274

SECT. XXXV.—Observations upon Benzoic Acid, and its Combinations with Salifiable Bases, 275

SECT. XXXVI.—Observations upon Camphoric Acid, and its Combinations with Salifiable [Pg xlvi]Bases, 276

SECT. XXXVII.—Observations upon Gallic Acid, and its Combinations with Salifiable Bases, 277

SECT. XXXVIII.—Observations upon Lactic Acid, and its Combinations with Salifiable Bases, 278

TABLE of the Combinations of Saccholactic Acid, 280

SECT. XXXIX.—Observations upon Saccholactic Acid, and its Combination with Salifiable Bases, 281

TABLE of the Combinations of Formic Acid, 282

SECT. XL.—Observations upon Formic Acid, and its Combinations with the Salifiable Bases, 283

SECT. XLI.—Observations upon the Bombic Acid, and its Combinations with the Salifiable Bases, 284

TABLE of the Combinations of the Sebacic Acid, 285

SECT. XLII.—Observations upon the Sebacic Acid, and its Combinations with the Salifiable Bases, 286

SECT. XLIII.—Observations upon the Lithic Acid, and its Combinations with the Salifiable Bases, 287

TABLE of the Combinations of the Prussic Acid, 288

SECT. XLIV.—Observations upon the Prussic Acid, and its Combinations with the Salifiable Bases, 289


PART III.

[Pg xlvii] Description of the Instruments and Operations of Chemistry, 291

INTRODUCTION, 291

CHAP. I.—Of the Instruments necessary for determining
    the Absolute and Specific Gravities of Solid and Liquid Bodies, 295

CHAP. II.—Of Gazometry, or the Measurement of the Weight and Volume of Aëriform Substances, 304

SECT. I.—Of the Pneumato-chemical Apparatus, ibid.

SECT. II.—Of the Gazometer, 308

SECT. III.—Some other methods for Measuring the Volume of Gasses, 319

SECT. IV.—Of the method of Separating the different Gasses from each other, 323

SECT. V.—Of the necessary Corrections of the Volume of Gasses,
    according to the Pressure of the Atmosphere, 328

SECT. VI.—Of the Correction relative to the Degrees of the Thermometer, 335

SECT. VII.—Example for Calculating the Corrections
    relative to the Variations of Pressure and Temperature, 337

SECT. VIII.—Method of determining the Weight of the different Gasses, 340

CHAP. III.—Description of the Calorimeter, or Apparatus for measuring Caloric, 343

CHAP. IV.—Of the Mechanical Operations for Division of Bodies, 357

[Pg xlviii] SECT. I.—Of Trituration, Levigation, and Pulverization, ibid.

SECT. II.—Of Sifting and Washing Powdered Substances, 361

SECT. III.—Of Filtration, 363

SECT. IV.—Of Decantation, 365

CHAP. V.—Of Chemical means for Separating the Particles of Bodies
     from each other without Decomposition, and for Uniting them again, 367

SECT. I.—Of the Solution of Salts, 368

SECT. II.—Of Lixiviation, 373

SECT. III.—Of Evaporation, 375

SECT. IV.—Of Cristallization, 379

SECT. V.—Of Simple Distillation, 384

SECT. VI.—Of Sublimation, 388

CHAP. VI.—Of Pneumato-chemical Distillations, Metallic Dissolutions,
     and some other operations which require very complicated instruments, 390

SECT. I.—Of Compound and Pneumato-chemical Distillations, ibid.

SECT. II.—Of Metallic Dissolutions, 398

SECT. III.—Apparatus necessary in Experiments upon Vinous and Putrefactive Fermentations, 401

SECT. IV.—Apparatus for the Decomposition of Water, 404

CHAP. VII.—Of the Composition and Use of Lutes, 407

CHAP. VIII.—Of Operations upon Combustion and Deflagration, 414

SECT. I.—Of Combustion in general, ibid.

SECT. II.—Of the Combustion of Phosphorus, 418

[Pg xlix] SECT. III.—Of the Combustion of Charcoal, 422

SECT. IV.—Of the Combustion of Oils, 426

SECT. V.—Of the Combustion of Alkohol, 433

SECT. VI.—Of the Combustion of Ether, 435

SECT. VII.—Of the Combustion of Hydrogen Gas, and the Formation of Water, 437

SECT. VIII.—Of the Oxydation of Metals, 441

CHAP. IX.—Of Deflagration, 452

CHAP. X.—Of the Instruments necessary for Operating upon Bodies in very high Temperatures, 460

SECT. I.—Of Fusion, ibid.

SECT. II.—Of Furnaces, 462

SECT. III.—Of increasing the Action of Fire, by using Oxygen Gas instead of Atmospheric Air, 474


APPENDIX.

No. I.—Table for Converting Lines, or Twelfth Parts of an Inch,
     and Fractions of Lines, into Decimal Fractions of the Inch, 481

No. II.—Table for Converting the Observed Heighth of Water in the Jars of the Pneumato-Chemical
    Apparatus, expressed in Inches and Decimals, into Corresponding Heighths of Mercury, 482

No. III.—Table for Converting the Ounce Measures used
     by Dr Priestley into French and English Cubical Inches, 483

[Pg l] No. IV.—Table for Reducing the Degrees of
    Reaumeur's Thermometer into its corresponding Degrees of Fahrenheit's Scale, 484

No. V.—Additional.—Rules for Converting French Weights
     and Measures into correspondent English Denominations, 485

No. VI.—Table of the Weights of the different Gasses, at 28 French inches,
     or 29.84 English inches barometrical pressure, and at 10° (54.5°) of temperature,
     expressed in English measure and English Troy weight, 490

No. VII.—Tables of the Specific Gravities of different bodies, 491

No. VIII.—Additional.—Rules for Calculating the Absolute Gravity in English Troy Weight of a
     Cubic Foot and Inch, English Measure, of any Substance whose Specific Gravity is known, 505

No. IX.—Tables for Converting Ounces, Drams, and Grains, Troy, into
     Decimals of the Troy Pound of 12 Ounces, and for Converting Decimals of the Pound Troy
     into Ounces, &c. 508

No. X.—Table of the English Cubical Inches and Decimals corresponding to a determinate Troy
     Weight of Distilled Water at the Temperature of 55°, calculated from Everard's experiment, 511

[Pg 1]

ELEMENTS

OF

CHEMISTRY.

PART I.

CHAP. I.

Of the Combinations of Caloric, and the Formation of Elastic Aëriform Fluids.

That every body, whether solid or fluid, is augmented in all its dimensions by any increase of its sensible heat, was long ago fully established as a physical axiom, or universal proposition, by the celebrated Boerhaave. Such facts as have been adduced for controverting the[Pg 2] generality of this principle offer only fallacious results, or, at least, such as are so complicated with foreign circumstances as to mislead the judgment: But, when we separately consider the effects, so as to deduce each from the cause to which they separately belong, it is easy to perceive that the separation of particles by heat is a constant and general law of nature.

When we have heated a solid body to a certain degree, and have thereby caused its particles to separate from each other, if we allow the body to cool, its particles again approach each other in the same proportion in which they were separated by the increased temperature; the body returns through the same degrees of expansion which it before extended through; and, if it be brought back to the same temperature from which we set out at the commencement of the experiment, it recovers exactly the same dimensions which it formerly occupied. But, as we are still very far from being able to arrive at the degree of absolute cold, or deprivation of all heat, being unacquainted with any degree of coldness which we cannot suppose capable of still farther augmentation, it follows, that we are still incapable of causing the ultimate particles of bodies to approach each other as near as is possible; and, consequently, that the particles of all bodies do not touch each other in any state hitherto known, which, tho'[Pg 3] a very singular conclusion, is yet impossible to be denied.

It is supposed, that, since the particles of bodies are thus continually impelled by heat to separate from each other, they would have no connection between themselves; and, of consequence, that there could be no solidity in nature, unless they were held together by some other power which tends to unite them, and, so to speak, to chain them together; which power, whatever be its cause, or manner of operation, we name Attraction.

Thus the particles of all bodies may be considered as subjected to the action of two opposite powers, the one repulsive, the other attractive, between which they remain in equilibrio. So long as the attractive force remains stronger, the body must continue in a state of solidity; but if, on the contrary, heat has so far removed these particles from each other, as to place them beyond the sphere of attraction, they lose the adhesion they before had with each other, and the body ceases to be solid.

Water gives us a regular and constant example of these facts; whilst below Zero[2] of the French thermometer, or 32° of Fahrenheit,[Pg 4] it remains solid, and is called ice. Above that degree of temperature, its particles being no longer held together by reciprocal attraction, it becomes liquid; and, when we raise its temperature above 80°, (212°) its particles, giving way to the repulsion caused by the heat, assume the state of vapour or gas, and the water is changed into an aëriform fluid.

The same may be affirmed of all bodies in nature: They are either solid or liquid, or in the state of elastic aëriform vapour, according to the proportion which takes place between the attractive force inherent in their particles, and the repulsive power of the heat acting upon these; or, what amounts to the same thing, in proportion to the degree of heat to which they are exposed.

It is difficult to comprehend these phenomena, without admitting them as the effects of a real and material substance, or very subtile fluid, which, insinuating itself between the particles of bodies, separates them from each other; and, even allowing the existence of this fluid to be hypothetical, we shall see in the sequel, that it explains the phenomena of nature in a very satisfactory manner.

This substance, whatever it is, being the cause of heat, or, in other words, the sensation which we call warmth being caused by the accumulation of this substance, we cannot, in strict language,[Pg 5] distinguish it by the term heat; because the same name would then very improperly express both cause and effect. For this reason, in the memoir which I published in 1777[3], I gave it the names of igneous fluid and matter of heat. And, since that time, in the work[4] published by Mr de Morveau, Mr Berthollet, Mr de Fourcroy, and myself, upon the reformation of chemical nomenclature, we thought it necessary to banish all periphrastic expressions, which both lengthen physical language, and render it more tedious and less distinct, and which even frequently does not convey sufficiently just ideas of the subject intended. Wherefore, we have distinguished the cause of heat, or that exquisitely elastic fluid which produces it, by the term of caloric. Besides, that this expression fulfils our object in the system which we have adopted, it possesses this farther advantage, that it accords with every species of opinion, since, strictly speaking, we are not obliged to suppose this to be a real substance; it being sufficient, as will more clearly appear in the sequel of this work, that it be considered as the repulsive cause, whatever that may be, which separates the particles of matter from each other; so that[Pg 6] we are still at liberty to investigate its effects in an abstract and mathematical manner.

In the present state of our knowledge, we are unable to determine whether light be a modification of caloric, or if caloric be, on the contrary, a modification of light. This, however, is indisputable, that, in a system where only decided facts are admissible, and where we avoid, as far as possible, to suppose any thing to be that is not really known to exist, we ought provisionally to distinguish, by distinct terms, such things as are known to produce different effects. We therefore distinguish light from caloric; though we do not therefore deny that these have certain qualities in common, and that, in certain circumstances, they combine with other bodies almost in the same manner, and produce, in part, the same effects.

What I have already said may suffice to determine the idea affixed to the word caloric; but there remains a more difficult attempt, which is, to give a just conception of the manner in which caloric acts upon other bodies. Since this subtile matter penetrates through the pores of all known substances; since there are no vessels through which it cannot escape, and, consequently, as there are none which are capable of retaining it, we can only come at the knowledge of its properties by effects which are fleeting, and difficultly ascertainable. It is in[Pg 7] these things which we neither see nor feel, that it is especially necessary to guard against the extravagancy of our imagination, which forever inclines to step beyond the bounds of truth, and is very difficultly restrained within the narrow line of facts.

We have already seen, that the same body becomes solid, or fluid, or aëriform, according to the quantity of caloric by which it is penetrated; or, to speak more strictly, according as the repulsive force exerted by the caloric is equal to, stronger, or weaker, than the attraction of the particles of the body it acts upon.

But, if these two powers only existed, bodies would become liquid at an indivisible degree of the thermometer, and would almost instantaneously pass from the solid state of aggregation to that of aëriform elasticity. Thus water, for instance, at the very moment when it ceases to be ice, would begin to boil, and would be transformed into an aëriform fluid, having its particles scattered indefinitely through the surrounding space. That this does not happen, must depend upon the action of some third power. The pressure of the atmosphere prevents this separation, and causes the water to remain in the liquid state till it be raised to 80° of temperature (212°) above zero of the French thermometer, the quantity of caloric which it receives in the lowest temperature being insufficient[Pg 8] to overcome the pressure of the atmosphere.

Whence it appears that, without this atmospheric pressure, we should not have any permanent liquid, and should only be able to see bodies in that state of existence in the very instant of melting, as the smallest additional caloric would instantly separate their particles, and dissipate them through the surrounding medium. Besides, without this atmospheric pressure, we should not even have any aëriform fluids, strictly speaking, because the moment the force of attraction is overcome by the repulsive power of the caloric, the particles would separate themselves indefinitely, having nothing to give limits to their expansion, unless their own gravity might collect them together, so as to form an atmosphere.

Simple reflection upon the most common experiments is sufficient to evince the truth of these positions. They are more particularly proved by the following experiment, which I published in the Memoirs of the French Academy for 1777, p. 426.

Having filled with sulphuric ether[5] a small narrow glass vessel, A, (Plate VII. Fig. 17.), standing[Pg 9] upon its stalk P, the vessel, which is from twelve to fifteen lines diameter, is to be covered by a wet bladder, tied round its neck with several turns of strong thread; for greater security, fix a second bladder over the first. The vessel should be filled in such a manner with the ether, as not to leave the smallest portion of air between the liquor and the bladder. It is now to be placed under the recipient BCD of an air-pump, of which the upper part B ought to be fitted with a leathern lid, through which passes a wire EF, having its point F very sharp; and in the same receiver there ought to be placed the barometer GH. The whole being thus disposed, let the recipient be exhausted, and then, by pushing down the wire EF, we make a hole in the bladder. Immediately the ether begins to boil with great violence, and is changed into an elastic aëriform fluid, which fills the receiver. If the quantity of ether be sufficient to leave a few drops in the phial after the evaporation is finished, the elastic fluid produced will sustain the mercury in the barometer attached to the air-pump, at eight or ten inches in winter, and from[Pg 10] twenty to twenty-five in summer[6]. To render this experiment more complete, we may introduce a small thermometer into the phial A, containing the ether, which will descend considerably during the evaporation.

The only effect produced in this experiment is, the taking away the weight of the atmosphere, which, in its ordinary state, presses on the surface of the ether; and the effects resulting from this removal evidently prove, that, in the ordinary temperature of the earth, ether would always exist in an aëriform state, but for the pressure of the atmosphere, and that the passing of the ether from the liquid to the aëriform state is accompanied by a considerable lessening of heat; because, during the evaporation, a part of the caloric, which was before in a free state, or at least in equilibrio in the surrounding bodies, combines with the ether, and causes it to assume the aëriform state.

The same experiment succeeds with all evaporable fluids, such as alkohol, water, and even mercury; with this difference, that the atmosphere formed in the receiver by alkohol only[Pg 11] supports the attached barometer about one inch in winter, and about four or five inches in summer; that formed by water, in the same situation, raises the mercury only a few lines, and that by quicksilver but a few fractions of a line. There is therefore less fluid evaporated from alkohol than from ether, less from water than from alkohol, and still less from mercury than from either; consequently there is less caloric employed, and less cold produced, which quadrates exactly with the results of these experiments.

Another species of experiment proves very evidently that the aëriform state is a modification of bodies dependent on the degree of temperature, and on the pressure which these bodies undergo. In a Memoir read by Mr de la Place and me to the Academy in 1777, which has not been printed, we have shown, that, when ether is subjected to a pressure equal to twenty-eight inches of the barometer, or about the medium pressure of the atmosphere, it boils at the temperature of about 32° (104°), or 33° (106.25°), of the thermometer. Mr de Luc, who has made similar experiments with spirit of wine, finds it boils at 67° (182.75°). And all the world knows that water boils at 80° (212°). Now, boiling being only the evaporation of a liquid, or the moment of its passing from the fluid to the aëriform state, it is evident that, if we keep[Pg 12] ether continually at the temperature of 33° (106.25°), and under the common pressure of the atmosphere, we shall have it always in an elastic aëriform state; and that the same thing will happen with alkohol when above 67° (182.75°), and with water when above 80° (212°); all which are perfectly conformable to the following experiment[7].

I filled a large vessel ABCD (Plate VII. Fig. 16.) with water, at 35° (110.75°), or 36° (113°); I suppose the vessel transparent, that we may see what takes place in the experiment; and we can easily hold the hands in water at that temperature without inconvenience. Into it I plunged some narrow necked bottles F, G, which were filled with the water, after which they were turned up, so as to rest on their mouths on the bottom of the vessel. Having next put some ether into a very small matrass, with its neck a b c, twice bent as in the Plate, I plunged this matrass into the water, so as to have its neck inserted into the mouth of one of the bottles F. Immediately upon feeling the effects of the heat communicated to it by the water in the vessel ABCD it began to boil; and the caloric entering into combination with it, changed it into elastic aëriform fluid, with which I filled several bottles successively, F, G, &c.

[Pg 13]

This is not the place to enter upon the examination of the nature and properties of this aëriform fluid, which is extremely inflammable; but, confining myself to the object at present in view, without anticipating circumstances, which I am not to suppose the reader to know, I shall only observe, that the ether, from this experiment, is almost only capable of existing in the aëriform state in our world; for, if the weight of our atmosphere was only equal to between 20 and 24 inches of the barometer, instead of 28 inches, we should never be able to obtain ether in the liquid state, at least in summer; and the formation of ether would consequently be impossible upon mountains of a moderate degree of elevation, as it would be converted into gas immediately upon being produced, unless we employed recipients of extraordinary strength, together with refrigeration and compression. And, lastly, the temperature of the blood being nearly that at which ether passes from the liquid to the aëriform state, it must evaporate in the primae viae, and consequently it is very probable the medical properties of this fluid depend chiefly upon its mechanical effect.

These experiments succeed better with nitrous ether, because it evaporates in a lower temperature than sulphuric ether. It is more difficult to obtain alkohol in the aëriform state; because, as it requires 67° (182.75°) to reduce it to vapour,[Pg 14] the water of the bath must be almost boiling, and consequently it is impossible to plunge the hands into it at that temperature.

It is evident that, if water were used in the foregoing experiment, it would be changed into gas, when exposed to a temperature superior to that at which it boils. Although thoroughly convinced of this, Mr de la Place and myself judged it necessary to confirm it by the following direct experiment. We filled a glass jar A, (Plate VII. Fig. 5.) with mercury, and placed it with its mouth downwards in a dish B, likewise filled with mercury, and having introduced about two gross of water into the jar, which rose to the top of the mercury at CD; we then plunged the whole apparatus into an iron boiler EFGH, full of boiling sea-water of the temperature of 85° (123.25°), placed upon the furnace GHIK. Immediately upon the water over the mercury attaining the temperature of 80° (212°), it began to boil; and, instead of only filling the small space ACD, it was converted into an aëriform fluid, which filled the whole jar; the mercury even descended below the surface of that in the dish B; and the jar must have been overturned, if it had not been very thick and heavy, and fixed to the dish by means of iron-wire. Immediately after withdrawing the apparatus from the boiler, the vapour in the jar began to condense, and the[Pg 15] mercury rose to its former station; but it returned again to the aëriform state a few seconds after replacing the apparatus in the boiler.

We have thus a certain number of substances, which are convertible into elastic aëriform fluids by degrees of temperature, not much superior to that of our atmosphere. We shall afterwards find that there are several others which undergo the same change in similar circumstances, such as muriatic or marine acid, ammoniac or volatile alkali, the carbonic acid or fixed air, the sulphurous acid, &c. All of these are permanently elastic in or about the mean temperature of the atmosphere, and under its common pressure.

All these facts, which could be easily multiplied if necessary, give me full right to assume, as a general principle, that almost every body in nature is susceptible of three several states of existence, solid, liquid, and aëriform, and that these three states of existence depend upon the quantity of caloric combined with the body. Henceforwards I shall express these elastic aëriform fluids by the generic term gas; and in each species of gas I shall distinguish between the caloric, which in some measure serves the purpose of a solvent, and the substance, which in combination with the caloric, forms the base of the gas.[Pg 16]

To these bases of the different gases, which are hitherto but little known, we have been obliged to assign names; these I shall point out in Chap. IV. of this work, when I have previously given an account of the phenomena attendant upon the heating and cooling of bodies, and when I have established precise ideas concerning the composition of our atmosphere.

We have already shown, that the particles of every substance in nature exist in a certain state of equilibrium, between that attraction which tends to unite and keep the particles together, and the effects of the caloric which tends to separate them. Hence the caloric not only surrounds the particles of all bodies on every side, but fills up every interval which the particles of bodies leave between each other. We may form an idea of this, by supposing a vessel filled with small spherical leaden bullets, into which a quantity of fine sand is poured, which, insinuating into the intervals between the bullets, will fill up every void. The balls, in this comparison, are to the sand which surrounds them exactly in the same situation as the particles of bodies are with respect to the caloric; with this difference only, that the balls are supposed to touch each other, whereas the particles of bodies are not in contact, being retained at a small distance from each other, by the caloric.[Pg 17]

If, instead of spherical balls, we substitute solid bodies of a hexahedral, octohedral, or any other regular figure, the capacity of the intervals between them will be lessened, and consequently will no longer contain the same quantity of sand. The same thing takes place, with respect to natural bodies; the intervals left between their particles are not of equal capacity, but vary in consequence of the different figures and magnitude of their particles, and of the distance at which these particles are maintained, according to the existing proportion between their inherent attraction, and the repulsive force exerted upon them by the caloric.

In this manner we must understand the following expression, introduced by the English philosophers, who have given us the first precise ideas upon this subject; the capacity of bodies for containing the matter of heat. As comparisons with sensible objects are of great use in assisting us to form distinct notions of abstract ideas, we shall endeavour to illustrate this, by instancing the phenomena which take place between water and bodies which are wetted and penetrated by it, with a few reflections.

If we immerge equal pieces of different kinds of wood, suppose cubes of one foot each, into water, the fluid gradually insinuates itself into their pores, and the pieces of wood are augmented both in weight and magnitude: But[Pg 18] each species of wood will imbibe a different quantity of water; the lighter and more porous woods will admit a larger, the compact and closer grained will admit of a lesser quantity; for the proportional quantities of water imbibed by the pieces will depend upon the nature of the constituent particles of the wood, and upon the greater or lesser affinity subsisting between them and water. Very resinous wood, for instance, though it may be at the same time very porous, will admit but little water. We may therefore say, that the different kinds of wood possess different capacities for receiving water; we may even determine, by means of the augmentation of their weights, what quantity of water they have actually absorbed; but, as we are ignorant how much water they contained, previous to immersion, we cannot determine the absolute quantity they contain, after being taken out of the water.

The same circumstances undoubtedly take place, with bodies that are immersed in caloric; taking into consideration, however, that water is an incompressible fluid, whereas caloric is, on the contrary, endowed with very great elasticity; or, in other words, the particles of caloric have a great tendency to separate from each other, when forced by any other power to approach; this difference must of necessity occasion[Pg 19] very considerable diversities in the results of experiments made upon these two substances.

Having established these clear and simple propositions, it will be very easy to explain the ideas which ought to be affixed to the following expressions, which are by no means synonimous, but possess each a strict and determinate meaning, as in the following definitions:

Free caloric, is that which is not combined in any manner with any other body. But, as we live in a system to which caloric has a very strong adhesion, it follows that we are never able to obtain it in the state of absolute freedom.

Combined caloric, is that which is fixed in bodies by affinity or elective attraction, so as to form part of the substance of the body, even part of its solidity.

By the expression specific caloric of bodies, we understand the respective quantities of caloric requisite for raising a number of bodies of the same weight to an equal degree of temperature. This proportional quantity of caloric depends upon the distance between the constituent particles of bodies, and their greater or lesser degrees of cohesion; and this distance, or rather the space or void resulting from it, is, as I have already observed, called the capacity of bodies for containing caloric.[Pg 20]

Heat, considered as a sensation, or, in other words, sensible heat, is only the effect produced upon our sentient organs, by the motion or passage of caloric, disengaged from the surrounding bodies. In general, we receive impressions only in consequence of motion, and we might establish it as an axiom, That, without motion, there is no sensation. This general principle applies very accurately to the sensations of heat and cold: When we touch a cold body, the caloric which always tends to become in equilibrio in all bodies, passes from our hand into the body we touch, which gives us the feeling or sensation of cold. The direct contrary happens, when we touch a warm body, the caloric then passing from the body into our hand, produces the sensation of heat. If the hand and the body touched be of the same temperature, or very nearly so, we receive no impression, either of heat or cold, because there is no motion or passage of caloric; and thus no sensation can take place, without some correspondent motion to occasion it.

When the thermometer rises, it shows, that free caloric is entering into the surrounding bodies: The thermometer, which is one of these, receives its share in proportion to its mass, and to the capacity which it possesses for containing caloric. The change therefore which takes place upon the thermometer, only announces a[Pg 21] change of place of the caloric in those bodies, of which the thermometer forms one part; it only indicates the portion of caloric received, without being a measure of the whole quantity disengaged, displaced, or absorbed.

The most simple and most exact method for determining this latter point, is that described by Mr de la Place, in the Memoirs of the Academy, No. 1780, p. 364; a summary explanation of which will be found towards the conclusion of this work. This method consists in placing a body, or a combination of bodies, from which caloric is disengaging, in the midst of a hollow sphere of ice; and the quantity of ice melted becomes an exact measure of the quantity of caloric disengaged. It is possible, by means of the apparatus which we have caused to be constructed upon this plan, to determine, not as has been pretended, the capacity of bodies for containing heat, but the ratio of the increase or diminution of capacity produced by determinate degrees of temperature. It is easy with the same apparatus, by means of divers combinations of experiments, to determine the quantity of caloric requisite for converting solid substances into liquids, and liquids into elastic aëriform fluids; and, vice versa, what quantity of caloric escapes from elastic vapours in changing to liquids, and what quantity escapes from liquids during their conversion into solids. Perhaps,[Pg 22] when experiments have been made with sufficient accuracy, we may one day be able to determine the proportional quantity of caloric, necessary for producing the several species of gasses. I shall hereafter, in a separate chapter, give an account of the principal results of such experiments as have been made upon this head.

It remains, before finishing this article, to say a few words relative to the cause of the elasticity of gasses, and of fluids in the state of vapour. It is by no means difficult to perceive that this elasticity depends upon that of caloric, which seems to be the most eminently elastic body in nature. Nothing is more readily conceived, than that one body should become elastic by entering into combination with another body possessed of that quality. We must allow that this is only an explanation of elasticity, by an assumption of elasticity, and that we thus only remove the difficulty one step farther, and that the nature of elasticity, and the reason for caloric being elastic, remains still unexplained. Elasticity in the abstract is nothing more than that quality of the particles of bodies by which they recede from each other when forced together. This tendency in the particles of caloric to separate, takes place even at considerable distances. We shall be satisfied of this, when we consider that air is susceptible of undergoing great compression, which supposes that its particles[Pg 23] were previously very distant from each other; for the power of approaching together certainly supposes a previous distance, at least equal to the degree of approach. Consequently, those particles of the air, which are already considerably distant from each other, tend to separate still farther. In fact, if we produce Boyle's vacuum in a large receiver, the very last portion of air which remains spreads itself uniformly through the whole capacity of the vessel, however large, fills it completely throughout, and presses every where against its sides: We cannot, however, explain this effect, without supposing that the particles make an effort to separate themselves on every side, and we are quite ignorant at what distance, or what degree of rarefaction, this effort ceases to act.

Here, therefore, exists a true repulsion between the particles of elastic fluids; at least, circumstances take place exactly as if such a repulsion actually existed; and we have very good right to conclude, that the particles of caloric mutually repel each other. When we are once permitted to suppose this repelling force, the rationale of the formation of gasses, or aëriform fluids, becomes perfectly simple; tho' we must, at the same time, allow, that it is extremely difficult to form an accurate conception of this repulsive force acting upon very minute[Pg 24] particles placed at great distances from each other.

It is, perhaps, more natural to suppose, that the particles of caloric have a stronger mutual attraction than those of any other substance, and that these latter particles are forced asunder in consequence of this superior attraction between the particles of the caloric, which forces them between the particles of other bodies, that they may be able to reunite with each other. We have somewhat analogous to this idea in the phenomena which occur when a dry sponge is dipt into water: The sponge swells; its particles separate from each other; and all its intervals are filled up by the water. It is evident, that the sponge, in the act of swelling, has acquired a greater capacity for containing water than it had when dry. But we cannot certainly maintain, that the introduction of water between the particles of the sponge has endowed them with a repulsive power, which tends to separate them from each other; on the contrary, the whole phenomena are produced by means of attractive powers; and these are, first, The gravity of the water, and the power which it exerts on every side, in common with all other fluids; 2dly, The force of attraction which takes place between the particles of the water, causing them to unite together; 3dly, The mutual attraction of the particles of the sponge with each other;[Pg 25] and, lastly, The reciprocal attraction which exists between the particles of the sponge and those of the water. It is easy to understand, that the explanation of this fact depends upon properly appreciating the intensity of, and connection between, these several powers. It is probable, that the separation of the particles of bodies, occasioned by caloric, depends in a similar manner upon a certain combination of different attractive powers, which, in conformity with the imperfection of our knowledge, we endeavour to express by saying, that caloric communicates a power of repulsion to the particles of bodies.

[Pg 26]

CHAP. II.

General Views relative to the Formation and Composition of our Atmosphere.

These views which I have taken of the formation of elastic aëriform fluids or gasses, throw great light upon the original formation of the atmospheres of the planets, and particularly that of our earth. We readily conceive, that it must necessarily consist of a mixture of the following substances: First, Of all bodies that are susceptible of evaporation, or, more strictly speaking, which are capable of retaining the state of aëriform elasticity in the temperature of our atmosphere, and under a pressure equal to that of a column of twenty-eight inches of quicksilver in the barometer; and, secondly, Of all substances, whether liquid or solid, which are capable of being dissolved by this mixture of different gasses.

The better to determine our ideas relating to this subject, which has not hitherto been sufficiently considered, let us, for a moment, conceive what change would take place in the various[Pg 27] substances which compose our earth, if its temperature were suddenly altered. If, for instance, we were suddenly transported into the region of the planet Mercury, where probably the common temperature is much superior to that of boiling water, the water of the earth, and all the other fluids which are susceptible of the gasseous state, at a temperature near to that of boiling water, even quicksilver itself, would become rarified; and all these substances would be changed into permanent aëriform fluids or gasses, which would become part of the new atmosphere. These new species of airs or gasses would mix with those already existing, and certain reciprocal decompositions and new combinations would take place, until such time as all the elective attractions or affinities subsisting amongst all these new and old gasseous substances had operated fully; after which, the elementary principles composing these gasses, being saturated, would remain at rest. We must attend to this, however, that, even in the above hypothetical situation, certain bounds would occur to the evaporation of these substances, produced by that very evaporation itself; for as, in proportion to the increase of elastic fluids, the pressure of the atmosphere would be augmented, as every degree of pressure tends, in some measure, to prevent evaporation, and as even the most evaporable[Pg 28] fluids can resist the operation of a very high temperature without evaporating, if prevented by a proportionally stronger compression, water and all other liquids being able to sustain a red heat in Papin's digester; we must admit, that the new atmosphere would at last arrive at such a degree of weight, that the water which had not hitherto evaporated would cease to boil, and, of consequence, would remain liquid; so that, even upon this supposition, as in all others of the same nature, the increasing gravity of the atmosphere would find certain limits which it could not exceed. We might even extend these reflections greatly farther, and examine what change might be produced in such situations upon stones, salts, and the greater part of the fusible substances which compose the mass of our earth. These would be softened, fused, and changed into fluids, &c.: But these speculations carry me from my object, to which I hasten to return.

By a contrary supposition to the one we have been forming, if the earth were suddenly transported into a very cold region, the water which at present composes our seas, rivers, and springs, and probably the greater number of the fluids we are acquainted with, would be converted into solid mountains and hard rocks, at first diaphanous[Pg 29] and homogeneous, like rock crystal, but which, in time, becoming mixed with foreign and heterogeneous substances, would become opake stones of various colours. In this case, the air, or at least some part of the aëriform fluids which now compose the mass of our atmosphere, would doubtless lose its elasticity for want of a sufficient temperature to retain them in that state: They would return to the liquid state of existence, and new liquids would be formed, of whose properties we cannot, at present, form the most distant idea.

These two opposite suppositions give a distinct proof of the following corollaries: First, That solidity, liquidity, and aëriform elasticity, are only three different states of existence of the same matter, or three particular modifications which almost all substances are susceptible of assuming successively, and which solely depend upon the degree of temperature to which they are exposed; or, in other words, upon the quantity of caloric with which they are penetrated[8]. 2dly, That it is extremely probable that air is a fluid naturally existing in a state of vapour; or, as we may better express it, that our atmosphere is a compound of all the fluids[Pg 30] which are susceptible of the vaporous or permanently elastic state, in the usual temperature, and under the common pressure. 3dly, That it is not impossible we may discover, in our atmosphere, certain substances naturally very compact, even metals themselves; as a metallic substance, for instance, only a little more volatile than mercury, might exist in that situation.

Amongst the fluids with which we are acquainted, some, as water and alkohol, are susceptible of mixing with each other in all proportions; whereas others, on the contrary, as quicksilver, water, and oil, can only form a momentary union; and, after being mixed together, separate and arrange themselves according to their specific gravities. The same thing ought to, or at least may, take place in the atmosphere. It is possible, and even extremely probable, that, both at the first creation, and every day, gasses are formed, which are difficultly miscible with atmospheric air, and are continually separating from it. If these gasses be specifically lighter than the general atmospheric mass, they must, of course, gather in the higher regions, and form strata that float upon the common air. The phenomena which accompany igneous meteors induce me to believe, that there exists in the upper parts[Pg 31] of our atmosphere a stratum of inflammable fluid in contact with those strata of air which produce the phenomena of the aurora borealis and other fiery meteors.—I mean hereafter to pursue this subject in a separate treatise.

CHAP. III.

[Pg 32]

Analysis of Atmospheric Air, and its Division into two Elastic Fluids; the one fit for Respiration, the other incapable of being respired.

From what has been premised, it follows, that our atmosphere is composed of a mixture of every substance capable of retaining the gasseous or aëriform state in the common temperature, and under the usual pressure which it experiences. These fluids constitute a mass, in some measure homogeneous, extending from the surface of the earth to the greatest height hitherto attained, of which the density continually decreases in the inverse ratio of the superincumbent weight. But, as I have before observed, it is possible that this first stratum is surmounted by several others consisting of very different fluids.

Our business, in this place, is to endeavour to determine, by experiments, the nature of the elastic fluids which compose the inferior stratum of air which we inhabit. Modern chemistry has made great advances in this research; and it will appear by the following details that the analysis of atmospherical air has been more[Pg 33] rigorously determined than that of any other substance of the class. Chemistry affords two general methods of determining the constituent principles of bodies, the method of analysis, and that of synthesis. When, for instance, by combining water with alkohol, we form the species of liquor called, in commercial language, brandy or spirit of wine, we certainly have a right to conclude, that brandy, or spirit of wine, is composed of alkohol combined with water. We can produce the same result by the analytical method; and in general it ought to be considered as a principle in chemical science, never to rest satisfied without both these species of proofs.

We have this advantage in the analysis of atmospherical air, being able both to decompound it, and to form it a new in the most satisfactory manner. I shall, however, at present confine myself to recount such experiments as are most conclusive upon this head; and I may consider most of these as my own, having either first invented them, or having repeated those of others, with the intention of analysing atmospherical air, in perfectly new points of view.

I took a matrass (A, fig. 14. plate II.) of about 36 cubical inches capacity, having a long neck B C D E, of six or seven lines internal diameter, and having bent the neck as in Plate IV. Fig. 2. so as to allow of its being placed in[Pg 34] the furnace M M N N, in such a manner that the extremity of its neck E might be inserted under a bell-glass F G, placed in a trough of quicksilver R R S S; I introduced four ounces of pure mercury into the matrass, and, by means of a syphon, exhausted the air in the receiver F G, so as to raise the quicksilver to L L, and I carefully marked the height at which it stood by pasting on a slip of paper. Having accurately noted the height of the thermometer and barometer, I lighted a fire in the furnace M M N N, which I kept up almost continually during twelve days, so as to keep the quicksilver always almost at its boiling point. Nothing remarkable took place during the first day: The Mercury, though not boiling, was continually evaporating, and covered the interior surface of the vessels with small drops, at first very minute, which gradually augmenting to a sufficient size, fell back into the mass at the bottom of the vessel. On the second day, small red particles began to appear on the surface of the mercury, which, during the four or five following days, gradually increased in size and number; after which they ceased to increase in either respect. At the end of twelve days, seeing that the calcination of the mercury did not at all increase, I extinguished the fire, and allowed the vessels to cool. The bulk of air in the body and neck of the matrass, and in the bell-glass, reduced to[Pg 35] a medium of 28 inches of the barometer and 10° (54.5°) of the thermometer, at the commencement of the experiment was about 50 cubical inches. At the end of the experiment the remaining air, reduced to the same medium pressure and temperature, was only between 42 and 43 cubical inches; consequently it had lost about 1/6 of its bulk. Afterwards, having collected all the red particles, formed during the experiment, from the running mercury in which they floated, I found these to amount to 45 grains.

I was obliged to repeat this experiment several times, as it is difficult in one experiment both to preserve the whole air upon which we operate, and to collect the whole of the red particles, or calx of mercury, which is formed during the calcination. It will often happen in the sequel, that I shall, in this manner, give in one detail the results of two or three experiments of the same nature.

The air which remained after the calcination of the mercury in this experiment, and which was reduced to 5/6 of its former bulk, was no longer fit either for respiration or for combustion; animals being introduced into it were suffocated in a few seconds, and when a taper was plunged into it, it was extinguished as if it had been immersed into water.[Pg 36]

In the next place, I took the 45 grains of red matter formed during this experiment, which I put into a small glass retort, having a proper apparatus for receiving such liquid, or gasseous product, as might be extracted: Having applied a fire to the retort in a furnace, I observed that, in proportion as the red matter became heated, the intensity of its colour augmented. When the retort was almost red hot, the red matter began gradually to decrease in bulk, and in a few minutes after it disappeared altogether; at the same time 41-1/2 grains of running mercury were collected in the recipient, and 7 or 8 cubical inches of elastic fluid, greatly more capable of supporting both respiration and combustion than atmospherical air, were collected in the bell-glass.

A part of this air being put into a glass tube of about an inch diameter, showed the following properties: A taper burned in it with a dazzling splendour, and charcoal, instead of consuming quietly as it does in common air, burnt with a flame, attended with a decrepitating noise, like phosphorus, and threw out such a brilliant light that the eyes could hardly endure it. This species of air was discovered almost at the same time by Mr Priestley, Mr Scheele, and myself. Mr Priestley gave it the name of dephlogisticated air, Mr Scheele called it empyreal air. At first I named it highly respirable air, to[Pg 37] which has since been substituted the term of vital air. We shall presently see what we ought to think of these denominations.

In reflecting upon the circumstances of this experiment, we readily perceive, that the mercury, during its calcination, absorbs the salubrious and respirable part of the air, or, to speak more strictly, the base of this respirable part; that the remaining air is a species of mephitis, incapable of supporting combustion or respiration; and consequently that atmospheric air is composed of two elastic fluids of different and opposite qualities. As a proof of this important truth, if we recombine these two elastic fluids, which we have separately obtained in the above experiment, viz. the 42 cubical inches of mephitis, with the 8 cubical inches of respirable air, we reproduce an air precisely similar to that of the atmosphere, and possessing nearly the same power of supporting combustion and respiration, and of contributing to the calcination of metals.

Although this experiment furnishes us with a very simple means of obtaining the two principal elastic fluids which compose our atmosphere, separate from each other, yet it does not give us an exact idea of the proportion in which these two enter into its composition: For the attraction of mercury to the respirable part of the air, or rather to its base, is not sufficiently strong to overcome all the circumstances which[Pg 38] oppose this union. These obstacles are the mutual adhesion of the two constituent parts of the atmosphere for each other, and the elective attraction which unites the base of vital air with caloric; in consequence of these, when the calcination ends, or is at least carried as far as is possible, in a determinate quantity of atmospheric air, there still remains a portion of respirable air united to the mephitis, which the mercury cannot separate. I shall afterwards show, that, at least in our climate, the atmospheric air is composed of respirable and mephitic airs, in the proportion of 27 and 73; and I shall then discuss the causes of the uncertainty which still exists with respect to the exactness of that proportion.

Since, during the calcination of mercury, air is decomposed, and the base of its respirable part is fixed and combined with the mercury, it follows, from the principles already established, that caloric and light must be disengaged during the process: But the two following causes prevent us from being sensible of this taking place: As the calcination lasts during several days, the disengagement of caloric and light, spread out in a considerable space of time, becomes extremely small for each particular moment of that time, so as not to be perceptible; and, in the next place, the operation being carried on by means of fire in a furnace, the heat[Pg 39] produced by the calcination itself becomes confounded with that proceeding from the furnace. I might add the respirable part of the air, or rather its base, in entering into combination with the mercury, does not part with all the caloric which it contained, but still retains a part of it after forming the new compound; but the discussion of this point, and its proofs from experiment, do not belong to this part of our subject.

It is, however, easy to render this disengagement of caloric and light evident to the senses, by causing the decomposition of air to take place in a more rapid manner. And for this purpose, iron is excellently adapted, as it possesses a much stronger affinity for the base of respirable air than mercury. The elegant experiment of Mr Ingenhouz, upon the combustion of iron, is well known. Take a piece of fine iron wire, twisted into a spiral, (BC, Plate IV. Fig. 17.) fix one of its extremities B into the cork A, adapted to the neck of the bottle DEFG, and fix to the other extremity of the wire C, a small morsel of tinder. Matters being thus prepared, fill the bottle DEFG with air deprived of its mephitic part; then light the tinder, and introduce it quickly with the wire upon which it is fixed, into the bottle which you stop up with the cork A, as is shown in the figure (17 Plate IV.) The instant the[Pg 40] tinder comes into contact with the vital air it begins to burn with great intensity; and, communicating the inflammation to the iron-wire, it too takes fire, and burns rapidly, throwing out brilliant sparks, which fall to the bottom of the vessel in rounded globules, which become black in cooling, but retain a degree of metallic splendour. The iron thus burnt is more brittle even than glass, and is easily reduced into powder, and is still attractable by the magnet, though not so powerfully as it was before combustion. As Mr Ingenhouz has neither examined the change produced on iron, nor upon the air by this operation, I have repeated the experiment under different circumstances, in an apparatus adapted to answer my particular views, as follows.

Having filled a bell-glass (A, Plate IV. Fig. 3.) of about six pints measure, with pure air, or the highly respirable part of air, I transported this jar by means of a very flat vessel, into a quicksilver bath in the bason BC, and I took care to render the surface of the mercury perfectly dry both within and without the jar with blotting paper. I then provided a small capsule of china-ware D, very flat and open, in which I placed some small pieces of iron, turned spirally, and arranged in such a way as seemed most favourable for the combustion being communicated to every part. To the end of one of these pieces of iron was[Pg 41] fixed a small morsel of tinder, to which was added about the sixteenth part of a grain of phosphorus, and, by raising the bell-glass a little, the china capsule, with its contents, were introduced into the pure air. I know that, by this means, some common air must mix with the pure air in the glass; but this, when it is done dexterously, is so very trifling, as not to injure the success of the experiment. This being done, a part of the air is sucked out from the bell-glass, by means of a syphon GHI, so as to raise the mercury within the glass to EF; and, to prevent the mercury from getting into the syphon, a small piece of paper is twisted round its extremity. In sucking out the air, if the motion of the lungs only be used, we cannot make the mercury rise above an inch or an inch and a half; but, by properly using the muscles of the mouth, we can, without difficulty, cause it to rise six or seven inches.

I next took an iron wire, (MN, Plate IV. Fig. 16.) properly bent for the purpose, and making it red hot in the fire, passed it through the mercury into the receiver, and brought it in contact with the small piece of phosphorus attached to the tinder. The phosphorus instantly takes fire, which communicates to the tinder, and from that to the iron. When the pieces have been properly arranged, the whole iron burns, even to the last particle,[Pg 42] throwing out a white brilliant light similar to that of Chinese fireworks. The great heat produced by this combustion melts the iron into round globules of different sizes, most of which fall into the China cup; but some are thrown out of it, and swim upon the surface of the mercury. At the beginning of the combustion, there is a slight augmentation in the volume of the air in the bell-glass, from the dilatation caused by the heat; but, presently afterwards, a rapid diminution of the air takes place, and the mercury rises in the glass; insomuch that, when the quantity of iron is sufficient, and the air operated upon is very pure, almost the whole air employed is absorbed.

It is proper to remark in this place, that, unless in making experiments for the purpose of discovery, it is better to be contented with burning a moderate quantity of iron; for, when this experiment is pushed too far, so as to absorb much of the air, the cup D, which floats upon the quicksilver, approaches too near the bottom of the bell-glass; and the great heat produced, which is followed by a very sudden cooling, occasioned by the contact of the cold mercury, is apt to break the glass. In which case, the sudden fall of the column of mercury, which happens the moment the least flaw is produced in the glass, causes such a wave, as throws a great part of the quicksilver from the bason. To avoid[Pg 43] this inconvenience, and to ensure success to the experiment, one gross and a half of iron is sufficient to burn in a bell-glass, which holds about eight pints of air. The glass ought likewise to be strong, that it may be able to bear the weight of the column of mercury which it has to support.

By this experiment, it is not possible to determine, at one time, both the additional weight acquired by the iron, and the changes which have taken place in the air. If it is wished to ascertain what additional weight has been gained by the iron, and the proportion between that and the air absorbed, we must carefully mark upon the bell-glass, with a diamond, the height of the mercury, both before and after the experiment[9]. After this, the syphon (GH, Pl. IV. fig. 3.) guarded, as before, with a bit of paper, to prevent its filling with mercury, is to be introduced under the bell-glass, having the thumb placed upon the extremity, G, of the syphon, to regulate the passage of the air; and by this means the air is gradually admitted, so as to let the mercury fall to its level. This being done, the bell-glass is to be carefully removed, the[Pg 44] globules of melted iron contained in the cup, and those which have been scattered about, and swim upon the mercury, are to be accurately collected, and the whole is to be weighed. The iron will be found in that state called martial ethiops by the old chemists, possessing a degree of metallic brilliancy, very friable, and readily reducible into powder, under the hammer, or with a pestle and mortar. If the experiment has succeeded well, from 100 grains of iron will be obtained 135 or 136 grains of ethiops, which is an augmentation of 35 per cent.

If all the attention has been paid to this experiment which it deserves, the air will be found diminished in weight exactly equal to what the iron has gained. Having therefore burnt 100 grains of iron, which has acquired an additional weight of 35 grains, the diminution of air will be found exactly 70 cubical inches; and it will be found, in the sequel, that the weight of vital air is pretty nearly half a grain for each cubical inch; so that, in effect, the augmentation of weight in the one exactly coincides with the loss of it in the other.

I shall observe here, once for all, that, in every experiment of this kind, the pressure and temperature of the air, both before and after the experiment, must be reduced, by calculation, to a common standard of 10° (54.5°) of the thermometer, and 28 inches of the barometer.[Pg 45] Towards the end of this work, the manner of performing this very necessary reduction will be found accurately detailed.

If it be required to examine the nature of the air which remains after this experiment, we must operate in a somewhat different manner. After the combustion is finished, and the vessels have cooled, we first take out the cup, and the burnt iron, by introducing the hand through the quicksilver, under the bell-glass; we next introduce some solution of potash, or caustic alkali, or of the sulphuret of potash, or such other substance as is judged proper for examining their action upon the residuum of air. I shall, in the sequel, give an account of these methods of analysing air, when I have explained the nature of these different substances, which are only here in a manner accidentally mentioned. After this examination, so much water must be let into the glass as will displace the quicksilver, and then, by means of a shallow dish placed below the bell-glass, it is to be removed into the common water pneumato-chemical apparatus, where the air remaining may be examined at large, and with great facility.

When very soft and very pure iron has been employed in this experiment, and, if the combustion has been performed in the purest respirable or vital air, free from all admixture of the noxious or mephitic part, the air which remains[Pg 46] after the combustion will be found as pure as it was before; but it is difficult to find iron entirely free from a small portion of charry matter, which is chiefly abundant in steel. It is likewise exceedingly difficult to procure the pure air perfectly free from some admixture of mephitis, with which it is almost always contaminated; but this species of noxious air does not, in the smallest degree, disturb the result of the experiment, as it is always found at the end exactly in the same proportion as at the beginning.

I mentioned before, that we have two ways of determining the constituent parts of atmospheric air, the method of analysis, and that by synthesis. The calcination of mercury has furnished us with an example of each of these methods, since, after having robbed the respirable part of its base, by means of the mercury, we have restored it, so as to recompose an air precisely similar to that of the atmosphere. But we can equally accomplish this synthetic composition of atmospheric air, by borrowing the materials of which it is composed from different kingdoms of nature. We shall see hereafter that, when animal substances are dissolved in the nitric acid, a great quantity of gas is disengaged, which extinguishes light, and is unfit for animal respiration, being exactly similar to the noxious or mephitic part of atmospheric air. And, if we take 73 parts, by weight, of this elastic[Pg 47] fluid, and mix it with 27 parts of highly respirable air, procured from calcined mercury, we will form an elastic fluid precisely similar to atmospheric air in all its properties.

There are many other methods of separating the respirable from the noxious part of the atmospheric air, which cannot be taken notice of in this part, without anticipating information, which properly belongs to the subsequent chapters. The experiments already adduced may suffice for an elementary treatise; and, in matters of this nature, the choice of our evidences is of far greater consequence than their number.

I shall close this article, by pointing out the property which atmospheric air, and all the known gasses, possess of dissolving water, which is of great consequence to be attended to in all experiments of this nature. Mr Saussure found, by experiment, that a cubical foot of atmospheric air is capable of holding 12 grains of water in solution: Other gasses, as the carbonic acid, appear capable of dissolving a greater quantity; but experiments are still wanting by which to determine their several proportions. This water, held in solution by gasses, gives rise to particular phenomena in many experiments, which require great attention, and which has frequently proved the source of great errors to chemists in determining the results of their experiments.

CHAP. IV.

[Pg 48]

Nomenclature of the several Constituent Parts of Atmospheric Air.

Hitherto I have been obliged to make use of circumlocution, to express the nature of the several substances which constitute our atmosphere, having provisionally used the terms of respirable and noxious, or non-respirable parts of the air. But the investigations I mean to undertake require a more direct mode of expression; and, having now endeavoured to give simple and distinct ideas of the different substances which enter into the composition of the atmosphere, I shall henceforth express these ideas by words equally simple.

The temperature of our earth being very near to that at which water becomes solid, and reciprocally changes from solid to fluid, and as this phenomenon takes place frequently under our observation, it has very naturally followed, that, in the languages of at least every climate subjected to any degree of winter, a term has been used for signifying water in the state of solidity, when deprived of its caloric. The same, however, has not been found necessary[Pg 49] with respect to water reduced to the state of vapour by an additional dose of caloric; since those persons who do not make a particular study of objects of this kind, are still ignorant that water, when in a temperature only a little above the boiling heat, is changed into an elastic aëriform fluid, susceptible, like all other gasses, of being received and contained in vessels, and preserving its gasseous form so long as it remains at the temperature of 80° (212°), and under a pressure not exceeding 28 inches of the mercurial barometer. As this phenomenon has not been generally observed, no language has used a particular term for expressing water in this state[10]; and the same thing occurs with all fluids, and all substances, which do not evaporate in the common temperature, and under the usual pressure of our atmosphere.

For similar reasons, names have not been given to the liquid or concrete states of most of the aëriform fluids: These were not known to arise from the combination of caloric with certain bases; and, as they had not been seen either in the liquid or solid states, their existence, under these forms, was even unknown to natural philosophers.[Pg 50]

We have not pretended to make any alteration upon such terms as are sanctified by ancient custom; and, therefore, continue to use the words water and ice in their common acceptation: We likewise retain the word air, to express that collection of elastic fluids which composes our atmosphere; but we have not thought it necessary to preserve the same respect for modern terms, adopted by latter philosophers, having considered ourselves as at liberty to reject such as appeared liable to occasion erroneous ideas of the substances they are meant to express, and either to substitute new terms, or to employ the old ones, after modifying them in such a manner as to convey more determinate ideas. New words have been drawn, chiefly from the Greek language, in such a manner as to make their etymology convey some idea of what was meant to be represented; and these we have always endeavoured to make short, and of such a nature as to be changeable into adjectives and verbs.

Following these principles, we have, after Mr Macquer's example, retained the term gas, employed by Vanhelmont, having arranged the numerous class of elastic aëriform fluids under that name, excepting only atmospheric air. Gas, therefore, in our nomenclature, becomes a generic term, expressing the fullest degree of saturation in any body with caloric; being, in[Pg 51] fact, a term expressive of a mode of existence. To distinguish each species of gas, we employ a second term from the name of the base, which, saturated with caloric, forms each particular gas. Thus, we name water combined to saturation with caloric, so as to form an elastic fluid, aqueous gas; ether, combined in the same manner, etherial gas; the combination of alkohol with caloric, becomes alkoholic gas; and, following the same principles, we have muriatic acid gas, ammoniacal gas, and so on of every substance susceptible of being combined with caloric, in such a manner as to assume the gasseous or elastic aëriform state.

We have already seen, that the atmospheric air is composed of two gasses, or aëriform fluids, one of which is capable, by respiration, of contributing to animal life, and in which metals are calcinable, and combustible bodies may burn; the other, on the contrary, is endowed with directly opposite qualities; it cannot be breathed by animals, neither will it admit of the combustion of inflammable bodies, nor of the calcination of metals. We have given to the base of the former, or respirable portion of the air, the name of oxygen, from οξυς acidum, and γεινομας, gignor; because, in reality, one of the most general properties of this base is to form acids, by combining with many different substances. The union of this base with caloric[Pg 52] we term oxygen gas, which is the same with what was formerly called pure, or vital air. The weight of this gas, at the temperature of 10° (54.50), and under a pressure equal to 28 inches of the barometer, is half a grain for each cubical inch, or one ounce and a half to each cubical foot.

The chemical properties of the noxious portion of atmospheric air being hitherto but little known, we have been satisfied to derive the name of its base from its known quality of killing such animals as are forced to breathe it, giving it the name of azote, from the Greek privitive particle α and ξαη, vita; hence the name of the noxious part of atmospheric air is azotic gas; the weight of which, in the same temperature, and under the same pressure, is 1 oz. 2 gros. and 48 grs. to the cubical foot, or 0.4444 of a grain to the cubical inch. We cannot deny that this name appears somewhat extraordinary; but this must be the case with all new terms, which cannot be expected to become familiar until they have been some time in use. We long endeavoured to find a more proper designation without success; it was at first proposed to call it alkaligen gas, as, from the experiments of Mr Berthollet, it appears to enter into the composition of ammoniac, or volatile alkali; but then, we have as yet no proof of its making one of the constituent elements of[Pg 53] the other alkalies; beside, it is proved to compose a part of the nitric acid, which gives as good reason to have called it nitrigen. For these reasons, finding it necessary to reject any name upon systematic principles, we have considered that we run no risk of mistake in adopting the terms of azote, and azotic gas, which only express a matter of fact, or that property which it possesses, of depriving such animals as breathe it of their lives.

I should anticipate subjects more properly reserved for the subsequent chapters, were I in this place to enter upon the nomenclature of the several species of gasses: It is sufficient, in this part of the work, to establish the principles upon which their denominations are founded. The principal merit of the nomenclature we have adopted is, that, when once the simple elementary substance is distinguished by an appropriate term, the names of all its compounds derive readily, and necessarily, from this first denomination.

[Pg 54]

CHAP. V.

Of the Decomposition of Oxygen Gas by Sulphur, Phosphorus, and Charcoal—and of the Formation of Acids in general.

In performing experiments, it is a necessary principle, which ought never to be deviated from, that they be simplified as much as possible, and that every circumstance capable of rendering their results complicated be carefully removed. Wherefore, in the experiments which form the object of this chapter, we have never employed atmospheric air, which is not a simple substance. It is true, that the azotic gas, which forms a part of its mixture, appears to be merely passive during combustion and calcination; but, besides that it retards these operations very considerably, we are not certain but it may even alter their results in some circumstances; for which reason, I have thought it necessary to remove even this possible cause of doubt, by only making use of pure oxygen gas in the following experiments, which show the effects produced by combustion in that gas; and I shall advert to such differences as take place in the results of these, when the oxygen gas, or pure[Pg 55] vital air, is mixed, in different proportions, with azotic gas.

Having filled a bell-glass (A. Pl. iv. fig. 3), of between five and six pints measure, with oxygen gas, I removed it from the water trough, where it was filled, into the quicksilver bath, by means of a shallow glass dish slipped underneath, and having dried the mercury, I introduced 61-1/4 grains of Kunkel's phosphorus in two little China cups, like that represented at D, fig. 3. under the glass A; and that I might set fire to each of the portions of phosphorus separately, and to prevent the one from catching fire from the other, one of the dishes was covered with a piece of flat glass. I next raised the quicksilver in the bell-glass up to E F, by sucking out a sufficient portion of the gas by means of the syphon G H I. After this, by means of the crooked iron wire (fig. 16.), made red hot, I set fire to the two portions of phosphorus successively, first burning that portion which was not covered with the piece of glass. The combustion was extremely rapid, attended with a very brilliant flame, and considerable disengagement of light and heat. In consequence of the great heat induced, the gas was at first much dilated, but soon after the mercury returned to its level, and a considerable absorption of gas took place; at the same time, the[Pg 56] whole inside of the glass became covered with white light flakes of concrete phosphoric acid.

At the beginning of the experiment, the quantity of oxygen gas, reduced, as above directed, to a common standard, amounted to 162 cubical inches; and, after the combustion was finished, only 23-1/4 cubical inches, likewise reduced to the standard, remained; so that the quantity of oxygen gas absorbed during the combustion was 138-3/4 cubical inches, equal to 69.375 grains.

A part of the phosphorus remained unconsumed in the bottom of the cups, which being washed on purpose to separate the acid, weighed about 16-1/4 grains; so that about 45 grains of phosphorus had been burned: But, as it is hardly possible to avoid an error of one or two grains, I leave the quantity so far qualified. Hence, as nearly 45 grains of phosphorus had, in this experiment, united with 69.375 grains of oxygen, and as no gravitating matter could have escaped through the glass, we have a right to conclude, that the weight of the substance resulting from the combustion in form of white flakes, must equal that of the phosphorus and oxygen employed, which amounts to 114.375 grains. And we shall presently find, that these flakes consisted entirely of a solid or concrete acid. When we reduce these weights to hundredth parts, it will be found, that 100 parts of[Pg 57] phosphorus require 154 parts of oxygen for saturation, and that this combination will produce 254 parts of concrete phosphoric acid, in form of white fleecy flakes.

This experiment proves, in the most convincing manner, that, at a certain degree of temperature, oxygen possesses a stronger elective attraction, or affinity, for phosphorus than for caloric; that, in consequence of this, the phosphorus attracts the base of oxygen gas from the caloric, which, being set free, spreads itself over the surrounding bodies. But, though this experiment be so far perfectly conclusive, it is not sufficiently rigorous, as, in the apparatus described, it is impossible to ascertain the weight of the flakes of concrete acid which are formed; we can therefore only determine this by calculating the weights of oxygen and phosphorus employed; but as, in physics, and in chemistry, it is not allowable to suppose what is capable of being ascertained by direct experiment, I thought it necessary to rep at this experiment, as follows, upon a larger scale, and by means of a different apparatus.

I took a large glass baloon (A. Pl. iv. fig. 4.) with an opening three inches diameter, to which was fitted a crystal stopper ground with emery, and pierced with two holes for the tubes yyy, xxx. Before shutting the baloon with its stopper, I introduced the support BC, surmounted[Pg 58] by the china cup D, containing 150 grs. of phosphorus; the stopper was then fitted to the opening of the baloon, luted with fat lute, and covered with slips of linen spread with quick-lime and white of eggs: When the lute was perfectly dry, the weight of the whole apparatus was determined to within a grain, or a grain and a half. I next exhausted the baloon, by means of an air pump applied to the tube xxx, and then introduced oxygen gas by means of the tube yyy, having a stop cock adapted to it. This kind of experiment is most readily and most exactly performed by means of the hydro-pneumatic machine described by Mr Meusnier and me in the Memoirs of the Academy for 1782, pag. 466. and explained in the latter part of this work, with several important additions and corrections since made to it by Mr Meusnier. With this instrument we can readily ascertain, in the most exact manner, both the quantity of oxygen gas introduced into the baloon, and the quantity consumed during the course of the experiment.

When all things were properly disposed, I set fire to the phosphorus with a burning glass. The combustion was extremely rapid, accompanied with a bright flame, and much heat; as the operation went on, large quantities of white flakes attached themselves to the inner surface of the baloon, so that at last it was rendered[Pg 59] quite opake. The quantity of these flakes at last became so abundant, that, although fresh oxygen gas was continually supplied, which ought to have supported the combustion, yet the phosphorus was soon extinguished. Having allowed the apparatus to cool completely, I first ascertained the quantity of oxygen gas employed, and weighed the baloon accurately, before it was opened. I next washed, dried, and weighed the small quantity of phosphorus remaining in the cup, on purpose to determine the whole quantity of phosphorus consumed in the experiment; this residuum of the phosphorus was of a yellow ochrey colour. It is evident, that by these several precautions, I could easily determine, 1st, the weight of the phosphorus consumed; 2d, the weight of the flakes produced by the combustion; and, 3d, the weight of the oxygen which had combined with the phosphorus. This experiment gave very nearly the same results with the former, as it proved that the phosphorus, during its combustion, had absorbed a little more than one and a half its weight of oxygen; and I learned with more certainty, that the weight of the new substance, produced in the experiment, exactly equalled the sum of the weights of the phosphorus consumed, and oxygen absorbed, which indeed was easily determinable a priori. If the oxygen gas employed be pure, the residuum after combustion[Pg 60] is as pure as the gas employed; this proves that nothing escapes from the phosphorus, capable of altering the purity of the oxygen gas, and that the only action of the phosphorus is to separate the oxygen from the caloric, with which it was before united.

I mentioned above, that when any combustible body is burnt in a hollow sphere of ice, or in an apparatus properly constructed upon that principle, the quantity of ice melted during the combustion is an exact measure of the quantity of caloric disengaged. Upon this head, the memoir given by M. de la Place and me, Aº. 1780, p. 355, may be consulted. Having submitted the combustion of phosphorus to this trial, we found that one pound of phosphorus melted a little more than 100 pounds of ice during its combustion.

The combustion of phosphorus succeeds equally well in atmospheric air as in oxygen gas, with this difference, that the combustion is vastly slower, being retarded by the large proportion of azotic gas mixed with the oxygen gas, and that only about one-fifth part of the air employed is absorbed, because as the oxygen gas only is absorbed, the proportion of the azotic gas becomes so great toward the close of the experiment, as to put an end to the combustion.[Pg 61]

I have already shown, that phosphorus is changed by combustion into an extremely light, white, flakey matter; and its properties are entirely altered by this transformation: From being insoluble in water, it becomes not only soluble, but so greedy of moisture, as to attract the humidity of the air with astonishing rapidity; by this means it is converted into a liquid, considerably more dense, and of more specific gravity than water. In the state of phosphorus before combustion, it had scarcely any sensible taste, by its union with oxygen it acquires an extremely sharp and sour taste: in a word, from one of the class of combustible bodies, it is changed into an incombustible substance, and becomes one of those bodies called acids.

This property of a combustible substance to be converted into an acid, by the addition of oxygen, we shall presently find belongs to a great number of bodies: Wherefore, strict logic requires that we should adopt a common term for indicating all these operations which produce analogous results; this is the true way to simplify the study of science, as it would be quite impossible to bear all its specifical details in the memory, if they were not classically arranged. For this reason, we shall distinguish this conversion of phosphorus into an acid, by its union with oxygen, and in general every combination of oxygen with a combustible substance,[Pg 62] by the term of oxygenation: from which I shall adopt the verb to oxygenate, and of consequence shall say, that in oxygenating phosphorus we convert it into an acid.

Sulphur is likewise a combustible body, or, in other words, it is a body which possesses the power of decomposing oxygen gas, by attracting the oxygen from the caloric with which it was combined. This can very easily be proved, by means of experiments quite similar to those we have given with phosphorus; but it is necessary to premise, that in these operations with sulphur, the same accuracy of result is not to be expected as with phosphorus; because the acid which is formed by the combustion of sulphur is difficultly condensible, and because sulphur burns with more difficulty, and is soluble in the different gasses. But I can safely assert, from my own experiments, that sulphur in burning absorbs oxygen gas; that the resulting acid is considerably heavier than the sulphur burnt; that its weight is equal to the sum of the weights of the sulphur which has been burnt, and of the oxygen absorbed; and, lastly that this acid is weighty, incombustible, and miscible with water in all proportions: The only uncertainty remaining upon this head, is with regard to the proportions of sulphur and of oxygen which enter into the composition of the acid.[Pg 63]

Charcoal, which, from all our present knowledge regarding it, must be considered as a simple combustible body, has likewise the property of decomposing oxygen gas, by absorbing its base from the caloric: But the acid resulting from this combustion does not condense in the common temperature; under the pressure of our atmosphere, it remains in the state of gas, and requires a large proportion of water to combine with or be dissolved in. This acid has, however, all the known properties of other acids, though in a weaker degree, and combines, like them, with all the bases which are susceptible of forming neutral salts.

The combustion of charcoal in oxygen gas, may be effected like that of phosphorus in the bell-glass, (A. Pl. IV. fig. 3.) placed over mercury: but, as the heat of red hot iron is not sufficient to set fire to the charcoal, we must add a small morsel of tinder, with a minute particle of phosphorus, in the same manner as directed in the experiment for the combustion of iron. A detailed account of this experiment will be found in the memoirs of the academy for 1781, p. 448. By that experiment it appears, that 28 parts by weight of charcoal require 72 parts of oxygen for saturation, and that the aëriform acid produced is precisely equal in weight to the sum of the weights of the charcoal and oxygen gas employed.[Pg 64] This aëriform acid was called fixed or fixable air by the chemists who first discovered it; they did not then know whether it was air resembling that of the atmosphere, or some other elastic fluid, vitiated and corrupted by combustion; but since it is now ascertained to be an acid, formed like all others by the oxygenation of its peculiar base, it is obvious that the name of fixed air is quite ineligible[11].

By burning charcoal in the apparatus mentioned p. 60, Mr de la Place and I found that one lib. of charcoal melted 96 libs. 6 oz. of ice; that, during the combustion, 2 libs. 9 oz. 1 gros. 10 grs. of oxygen were absorbed, and that 3 libs. 9 oz. 1 gros. 10 grs. of acid gas were formed. This gas weighs 0.695 parts of a grain for each cubical inch, in the common standard temperature and pressure mentioned above, so that 34,242 cubical inches of acid gas are produced by the combustion of one pound of charcoal.

I might multiply these experiments, and show by a numerous succession of facts, that all acids are formed by the combustion of certain substances; but I am prevented from doing so in[Pg 65] place, by the plan which I have laid down, of proceeding only from facts already ascertained, to such as are unknown, and of drawing my examples only from circumstances already explained. In the mean time, however, the three examples above cited may suffice for giving a clear and accurate conception of the manner in which acids are formed. By these it may be clearly seen, that oxygen is an element common to them all, which constitutes their acidity; and that they differ from each other, according to the nature of the oxygenated or acidified substance. We must therefore, in every acid, carefully distinguish between the acidifiable, base, which Mr de Morveau calls the radical, and the acidifiing principle or oxygen.

[Pg 66]

CHAP. VI.

Of the Nomenclature of Acids in general, and particularly of those drawn from Nitre and Sea-Salt.

It becomes extremely easy, from the principles laid down in the preceding chapter, to establish a systematic nomenclature for the acids: The word acid, being used as a generic term, each acid falls to be distinguished in language, as in nature, by the name of its base or radical. Thus, we give the generic name of acids to the products of the combustion or oxygenation of phosphorus, of sulphur, and of charcoal; and these products are respectively named, the phosphoric acid, the sulphuric acid, and the carbonic acid.

There is however, a remarkable circumstance in the oxygenation of combustible bodies, and of a part of such bodies as are convertible into acids, that they are susceptible of different degrees of saturation with oxygen, and that the resulting acids, though formed by the union of the same elements, are possessed of different properties, depending upon that difference of proportion. Of this, the phosphoric acid, and more especially the sulphuric, furnishes us with examples.[Pg 67] When sulphur is combined with a small proportion of oxygen, it forms, in this first or lower degree of oxygenation, a volatile acid, having a penetrating odour, and possessed of very particular qualities. By a larger proportion of oxygen, it is changed into a fixed, heavy acid, without any odour, and which, by combination with other bodies, gives products quite different from those furnished by the former. In this instance, the principles of our nomenclature seem to fail; and it seems difficult to derive such terms from the name of the acidifiable base, as shall distinctly express these two degrees of saturation, or oxygenation, without circumlocution. By reflection, however, upon the subject, or perhaps rather from the necessity of the case, we have thought it allowable to express these varieties in the oxygenation of the acids, by simply varying the termination of their specific names. The volatile acid produced from sulphur was anciently known to Stahl under the name of sulphurous acid[12]. We have[Pg 68] preserved that term for this acid from sulphur under-saturated with oxygen; and distinguish the other, or completely saturated or oxygenated acid, by the name of sulphuric acid. We shall therefore say, in this new chemical language, that sulphur, in combining with oxygen, is susceptible of two degrees of saturation; that the first, or lesser degree, constitutes sulphurous acid, which is volatile and penetrating; whilst the second, or higher degree of saturation, produces sulphuric acid, which is fixed and inodorous. We shall adopt this difference of termination for all the acids which assume several degrees of saturation. Hence we have a phosphorous and a phosphoric acid, an acetous and an acetic acid; and so on, for others in similar circumstances.

This part of chemical science would have been extremely simple, and the nomenclature of the acids would not have been at all perplexed, as it is now in the old nomenclature, if the base or radical of each acid had been known when the acid itself was discovered. Thus, for instance, phosphorus being a known substance before the discovery of its acid, this latter was rightly distinguished by a term drawn from the name of its acidifiable base. But when, on the contrary, an acid happened to be discovered before its base, or rather, when the acidifiable base from which it was formed remained unknown,[Pg 69] names were adopted for the two, which have not the smallest connection; and thus, not only the memory became burthened with useless appellations, but even the minds of students, nay even of experienced chemists, became filled with false ideas, which time and reflection alone is capable of eradicating. We may give an instance of this confusion with respect to the acid sulphur: The former chemists having procured this acid from the vitriol of iron, gave it the name of the vitriolic acid from the name of the substance which produced it; and they were then ignorant that the acid procured from sulphur by combustion was exactly the same.

The same thing happened with the aëriform acid formerly called fixed air; it not being known that this acid was the result of combining charcoal with oxygen, a variety of denominations have been given to it, not one of which conveys just ideas of its nature or origin. We have found it extremely easy to correct and modify the ancient language with respect to these acids proceeding from known bases, having converted the name of vitriolic acid into that of sulphuric, and the name of fixed air into that of carbonic acid; but it is impossible to follow this plan with the acids whose bases are still unknown; with these we have been obliged to use a contrary plan, and, instead of forming the name of the acid from that of its[Pg 70] base, have been forced to denominate the unknown base from the name of the known acid, as happens in the case of the acid which is procured from sea salt.

To disengage this acid from the alkaline base with which it is combined, we have only to pour sulphuric acid upon sea-salt, immediately a brisk effervescence takes place, white vapours arise, of a very penetrating odour, and, by only gently heating the mixture, all the acid is driven off. As, in the common temperature and pressure of our atmosphere, this acid is naturally in the state of gas, we must use particular precautions for retaining it in proper vessels. For small experiments, the most simple and most commodious apparatus consists of a small retort G, (Pl. V. Fig. 5.), into which the sea-salt is introduced, well dried[13], we then pour on some concentrated sulphuric acid, and immediately introduce the beak of the retort under little jars or bell-glasses A, (same Plate and Fig.), previously filled with quicksilver. In proportion as the acid gas is disengaged, it passes into the jar, and gets to the top of the quicksilver, which it displaces. When the disengagement[Pg 71] of the gas slackens, a gentle heat is applied to the retort, and gradually increased till nothing more passes over. This acid gas has a very strong affinity with water, which absorbs an enormous quantity of it, as is proved by introducing a very thin layer of water into the glass which contains the gas; for, in an instant, the whole acid gas disappears, and combines with the water.

This latter circumstance is taken advantage of in laboratories and manufactures, on purpose to obtain the acid of sea-salt in a liquid form; and for this purpose the apparatus (Pl. IV. Fig. 1.) is employed. It consists, 1st, of a tubulated retort A, into which the sea-salt, and after it the sulphuric acid, are introduced through the opening H; 2d, of the baloon or recipient c, b, intended for containing the small quantity of liquid which passes over during the process; and, 3d, of a set of bottles, with two mouths, L, L, L, L, half filled with water, intended for absorbing the gas disengaged by the distillation. This apparatus will be more amply described in the latter part of this work.

Although we have not yet been able, either to compose or to decompound this acid of sea-salt, we cannot have the smallest doubt that it, like all other acids, is composed by the union of oxygen with an acidifiable base. We have therefore called this unknown substance the[Pg 72] muriatic base, or muriatic radical, deriving this name, after the example of Mr Bergman and Mr de Morveau, from the Latin word muria, which was anciently used to signify sea-salt. Thus, without being able exactly to determine the component parts of muriatic acid, we design, by that term, a volatile acid, which retains the form of gas in the common temperature and pressure of our atmosphere, which combines with great facility, and in great quantity, with water, and whose acidifiable base adheres so very intimately with oxygen, that no method has hitherto been devised for separating them. If ever this acidifiable base of the muriatic acid is discovered to be a known substance, though now unknown in that capacity, it will be requisite to change its present denomination for one analogous with that of its base.

In common with sulphuric acid, and several other acids, the muriatic is capable of different degrees of oxygenation; but the excess of oxygen produces quite contrary effects upon it from what the same circumstance produces upon the acid of sulphur. The lower degree of oxygenation converts sulphur into a volatile gasseous acid, which only mixes in small proportions with water, whilst a higher oxygenation forms an acid possessing much stronger acid properties, which is very fixed and cannot remain in the state of gas but in a very high temperature, which has[Pg 73] no smell, and which mixes in large proportion with water. With muriatic acid, the direct reverse takes place; an additional saturation with oxygen renders it more volatile, of a more penetrating odour, less miscible with water, and diminishes its acid properties. We were at first inclined to have denominated these two degrees of saturation in the same manner as we had done with the acid of sulphur, calling the less oxygenated muriatous acid, and that which is more saturated with oxygen muriatic acid: But, as this latter gives very particular results in its combinations, and as nothing analogous to it is yet known in chemistry, we have left the name of muriatic acid to the less saturated, and give the latter the more compounded appellation of oxygenated muriatic acid.

Although the base or radical of the acid which is extracted from nitre or saltpetre be better known, we have judged proper only to modify its name in the same manner with that of the muriatic acid. It is drawn from nitre, by the intervention of sulphuric acid, by a process similar to that described for extracting the muriatic acid, and by means of the same apparatus (Pl. IV. Fig. 1.). In proportion as the acid passes over, it is in part condensed in the baloon or recipient, and the rest is absorbed by the water contained in the bottles L,L,L,L; the water becomes first green,[Pg 74] then blue, and at last yellow, in proportion to the concentration of the acid. During this operation, a large quantity of oxygen gas, mixed with a small proportion of azotic gas, is disengaged.

This acid, like all others, is composed of oxygen, united to an acidifiable base, and is even the first acid in which the existence of oxygen was well ascertained. Its two constituent elements are but weakly united, and are easily separated, by presenting any substance with which oxygen has a stronger affinity than with the acidifiable base peculiar to this acid. By some experiments of this kind, it was first discovered that azote, or the base of mephitis or azotic gas, constituted its acidifiable base or radical; and consequently that the acid of nitre was really an azotic acid, having azote for its base, combined with oxygen. For these reasons, that we might be consistent with our principles, it appeared necessary, either to call the acid by the name of azotic, or to name the base nitric radical; but from either of these we were dissuaded, by the following considerations. In the first place, it seemed difficult to change the name of nitre or saltpetre, which has been universally adopted in society, in manufactures, and in chemistry; and, on the other hand, azote having been discovered by Mr Berthollet to be the base of volatile alkali, or ammoniac, as well as of this acid,[Pg 75] we thought it improper to call it nitric radical. We have therefore continued the term of azote to the base of that part of atmospheric air which is likewise the nitric and ammoniacal radical; and we have named the acid of nitre, in its lower and higher degrees of oxygenation, nitrous acid in the former, and nitric acid in the latter state; thus preserving its former appellation properly modified.

Several very respectable chemists have disapproved of this deference for the old terms, and wished us to have persevered in perfecting a new chemical language, without paying any respect for ancient usage; so that, by thus steering a kind of middle course, we have exposed ourselves to the censures of one sect of chemists, and to the expostulations of the opposite party.

The acid of nitre is susceptible of assuming a great number of separate states, depending upon its degree of oxygenation, or upon the proportions in which azote and oxygen enter into its composition. By a first or lowest degree of oxygenation, it forms a particular species of gas, which we shall continue to name nitrous gas; this is composed nearly of two parts, by weight, of oxygen combined with one part of azote; and in this state it is not miscible with water. In this gas, the azote is by no means saturated with oxygen, but, on the contrary, has[Pg 76] still a very great affinity for that element, and even attracts it from atmospheric air, immediately upon getting into contact with it. This combination of nitrous gas with atmospheric air has even become one of the methods for determining the quantity of oxygen contained in air, and consequently for ascertaining its degree of salubrity.

This addition of oxygen converts the nitrous gas into a powerful acid, which has a strong affinity with water, and which is itself susceptible of various additional degrees of oxygenation. When the proportions of oxygen and azote is below three parts, by weight, of the former, to one of the latter, the acid is red coloured, and emits copious fumes. In this state, by the application of a gentle heat, it gives out nitrous gas; and we term it, in this degree of oxygenation, nitrous acid. When four parts, by weight, of oxygen, are combined with one part of azote, the acid is clear and colourless, more fixed in the fire than the nitrous acid, has less odour, and its constituent elements are more firmly united. This species of acid, in conformity with our principles of nomenclature, is called nitric acid.

Thus, nitric acid is the acid of nitre, surcharged with oxygen; nitrous acid is the acid of nitre surcharged with azote; or, what is the same thing, with nitrous gas; and this latter is[Pg 77] azote not sufficiently saturated with oxygen to possess the properties of an acid. To this degree of oxygenation, we have afterwards, in the course of this work, given the generical name of oxyd[14].

[Pg 78]

CHAP. VII.

Of the Decomposition of Oxygen Gas by means of Metals, and the Formation of Metallic Oxyds.

Oxygen has a stronger affinity with metals heated to a certain degree than with caloric; in consequence of which, all metallic bodies, excepting gold, silver, and platina, have the property of decomposing oxygen gas, by attracting its base from the caloric with which it was combined. We have already shown in what manner this decomposition takes place, by means of mercury and iron; having observed, that, in the case of the first, it must be considered as a kind of gradual combustion, whilst, in the latter, the combustion is extremely rapid, and attended with a brilliant flame. The use of the heat employed in these operations is to separate the particles of the metal from each other, and to diminish their attraction of cohesion or aggregation, or, what is the same thing, their mutual attraction for each other.

The absolute weight of metallic substances is augmented in proportion to the quantity of oxygen they absorb; they, at the same time, lose their metallic splendour, and are reduced into[Pg 79] an earthy pulverulent matter. In this state metals must not be considered as entirely saturated with oxygen, because their action upon this element is counterbalanced by the power of affinity between it and caloric. During the calcination of metals, the oxygen is therefore acted upon by two separate and opposite powers, that of its attraction for caloric, and that exerted by the metal, and only tends to unite with the latter in consequence of the excess of the latter over the former, which is, in general, very inconsiderable. Wherefore, when metallic substances are oxygenated in atmospheric air, or in oxygen gas, they are not converted into acids like sulphur, phosphorus, and charcoal, but are only changed into intermediate substances, which, though approaching to the nature of salts, have not acquired all the saline properties. The old chemists have affixed the name of calx not only to metals in this state, but to every body which has been long exposed to the action of fire without being melted. They have converted this word calx into a generical term, under which they confound calcareous earth, which, from a neutral salt, which it really was before calcination, has been changed by fire into an earthy alkali, by losing half of its weight, with metals which, by the same means, have joined themselves to a new substance, whose quantity often exceeds half their weight, and by which they[Pg 80] have been changed almost into the nature of acids. This mode of classifying substances of so very opposite natures, under the same generic name, would have been quite contrary to our principles of nomenclature, especially as, by retaining the above term for this state of metallic substances, we must have conveyed very false ideas of its nature. We have, therefore, laid aside the expression metallic calx altogether, and have substituted in its place the term oxyd, from the Greek word οξυς.

By this may be seen, that the language we have adopted is both copious and expressive. The first or lowest degree of oxygenation in bodies, converts them into oxyds; a second degree of additional oxygenation constitutes the class of acids, of which the specific names, drawn from their particular bases, terminate in ous, as the nitrous and sulphurous acids; the third degree of oxygenation changes these into the species of acids distinguished by the termination in ic, as the nitric and sulphuric acids; and, lastly, we can express a fourth, or highest degree of oxygenation, by adding the word oxygenated to the name of the acid, as has been already done with the oxygenated muriatic acid.

We have not confined the term oxyd to expressing the combinations of metals with oxygen, but have extended it to signify that first degree of oxygenation in all bodies, which,[Pg 81] without converting them into acids, causes them to approach to the nature of salts. Thus, we give the name of oxyd of sulphur to that soft substance into which sulphur is converted by incipient combustion; and we call the yellow matter left by phosphorus, after combustion, by the name of oxyd of phosphorus. In the same manner, nitrous gas, which is azote in its first degree of oxygenation, is the oxyd of azote. We have likewise oxyds in great numbers from the vegetable and animal kingdoms; and I shall show, in the sequel, that this new language throws great light upon all the operations of art and nature.

We have already observed, that almost all the metallic oxyds have peculiar and permanent colours. These vary not only in the different species of metals, but even according to the various degrees of oxygenation in the same metal. Hence we are under the necessity of adding two epithets to each oxyd, one of which indicates the metal oxydated[15], while the other indicates[Pg 82] the peculiar colour of the oxyd. Thus, we have the black oxyd of iron, the red oxyd of iron, and the yellow oxyd of iron; which expressions respectively answer to the old unmeaning terms of martial ethiops, colcothar, and rust of iron, or ochre. We have likewise the gray, yellow, and red oxyds of lead, which answer to the equally false or insignificant terms, ashes of lead, massicot, and minium.

These denominations sometimes become rather long, especially when we mean to indicate whether the metal has been oxydated in the air, by detonation with nitre, or by means of acids; but then they always convey just and accurate ideas of the corresponding object which we wish to express by their use. All this will be rendered perfectly clear and distinct by means of the tables which are added to this work.

[Pg 83]

CHAP. VIII.

Of the Radical Principle of Water, and of its Decomposition by Charcoal and Iron.

Until very lately, water has always been thought a simple substance, insomuch that the older chemists considered it as an element. Such it undoubtedly was to them, as they were unable to decompose it; or, at least, since the decomposition which took place daily before their eyes was entirely unnoticed. But we mean to prove, that water is by no means a simple or elementary substance. I shall not here pretend to give the history of this recent, and hitherto contested discovery, which is detailed in the Memoirs of the Academy for 1781, but shall only bring forwards the principal proofs of the decomposition and composition of water; and, I may venture to say, that these will be convincing to such as consider them impartially.

Experiment First.

Having fixed the glass tube EF, (Pl. vii. fig. 11.) of from 8 to 12 lines diameter, across a furnace, with a small inclination from E to F,[Pg 84] lute the superior extremity E to the glass retort A, containing a determinate quantity of distilled water, and to the inferior extremity F, the worm SS fixed into the neck of the doubly tubulated bottle H, which has the bent tube KK adapted to one of its openings, in such a manner as to convey such aëriform fluids or gasses as may be disengaged, during the experiment, into a proper apparatus for determining their quantity and nature.

To render the success of this experiment certain, it is necessary that the tube EF be made of well annealed and difficultly fusible glass, and that it be coated with a lute composed of clay mixed with powdered stone-ware; besides which, it must be supported about its middle by means of an iron bar passed through the furnace, lest it should soften and bend during the experiment. A tube of China-ware, or porcellain, would answer better than one of glass for this experiment, were it not difficult to procure one so entirely free from pores as to prevent the passage of air or of vapours.

When things are thus arranged, a fire is lighted in the furnace EFCD, which is supported of such a strength as to keep the tube EF red hot, but not to make it melt; and, at the same time, such a fire is kept up in the furnace VVXX, as to keep the water in the retort A continually boiling.[Pg 85]

In proportion as the water in the retort A is evaporated, it fills the tube EF, and drives out the air it contained by the tube KK; the aqueous gas formed by evaporation is condensed by cooling in the worm SS, and falls, drop by drop, into the tubulated bottle H. Having continued this operation until all the water be evaporated from the retort, and having carefully emptied all the vessels employed, we find that a quantity of water has passed over into the bottle H, exactly equal to what was before contained in the retort A, without any disengagement of gas whatsoever: So that this experiment turns out to be a simple distillation; and the result would have been exactly the same, if the water had been run from one vessel into the other, through the tube EF, without having undergone the intermediate incandescence.

Experiment Second.

The apparatus being disposed, as in the former experiment, 28 grs. of charcoal, broken into moderately small parts, and which has previously been exposed for a long time to a red heat in close vessels, are introduced into the tube EF. Every thing else is managed as in the preceding experiment.

The water contained in the retort A is distilled, as in the former experiment, and, being[Pg 86] condensed in the worm, falls into the bottle H; but, at the same time, a considerable quantity of gas is disengaged, which, escaping by the tube KK, is received in a convenient apparatus for that purpose. After the operation is finished, we find nothing but a few atoms of ashes remaining in the tube EF; the 28 grs. of charcoal having entirely disappeared.

When the disengaged gasses are carefully examined, they are sound to weigh 113.7 grs.[16]; these are of two kinds, viz. 144 cubical inches of carbonic acid gas, weighing 100 grs. and 380 cubical inches of a very light gas, weighing only 13.7 grs. which takes fire when in contact with air, by the approach of a lighted body; and, when the water which has passed over into the bottle H is carefully examined, it is found to have lost 85.7 grs. of its weight. Thus, in this experiment, 85.7 grs. of water, joined to 28 grs. of charcoal, have combined in such a way as to form 100 grs. of carbonic acid, and 13.7 grs. of a particular gas capable of being burnt.

I have already shown, that 100 grs. of carbonic acid gas consists of 72 grs. of oxygen, combined with 28 grs. of charcoal; hence the 28[Pg 87] grs. of charcoal placed in the glass tube have acquired 72 grs. of oxygen from the water; and it follows, that 85.7 grs. of water are composed of 72 grs. of oxygen, combined with 13.7 grs. of a gas susceptible of combustion. We shall see presently that this gas cannot possibly have been disengaged from the charcoal, and must, consequently, have been produced from the water.

I have suppressed some circumstances in the above account of this experiment, which would only have complicated and obscured its results in the minds of the reader. For instance, the inflammable gas dissolves a very small part of the charcoal, by which means its weight is somewhat augmented, and that of the carbonic gas proportionally diminished. Altho' the alteration produced by this circumstance is very inconsiderable; yet I have thought it necessary to determine its effects by rigid calculation, and to report, as above, the results of the experiment in its simplified state, as if this circumstance had not happened. At any rate, should any doubts remain respecting the consequences I have drawn from this experiment, they will be fully dissipated by the following experiments, which I am going to adduce in support of my opinion.[Pg 88]

Experiment Third.

The apparatus being disposed exactly as in the former experiment, with this difference, that instead of the 28 grs. of charcoal, the tube EF is filled with 274 grs. of soft iron in thin plates, rolled up spirally. The tube is made red hot by means of its furnace, and the water in the retort A is kept constantly boiling till it be all evaporated, and has passed through the tube EF, so as to be condensed in the bottle H.

No carbonic acid gas is disengaged in this experiment, instead of which we obtain 416 cubical inches, or 15 grs. of inflammable gas, thirteen times lighter than atmospheric air. By examining the water which has been distilled, it is found to have lost 100 grs. and the 274 grs. of iron confined in the tube are found to have acquired 85 grs. additional weight, and its magnitude is considerably augmented. The iron is now hardly at all attractable by the magnet; it dissolves in acids without effervescence; and, in short, it is converted into a black oxyd, precisely similar to that which has been burnt in oxygen gas.

In this experiment we have a true oxydation of iron, by means of water, exactly similar to that produced in air by the assistance of heat. One hundred grains of water having been decomposed,[Pg 89] 85 grs. of oxygen have combined with the iron, so as to convert it into the state of black oxyd, and 15 grs. of a peculiar inflammable gas are disengaged: From all this it clearly follows, that water is composed of oxygen combined with the base of an inflammable gas, in the respective proportions of 85 parts, by weight of the former, to 15 parts of the latter.

Thus water, besides the oxygen, which is one of its elements in common with many other substances, contains another element as its constituent base or radical, and for which we must find an appropriate term. None that we could think of seemed better adapted than the word hydrogen, which signifies the generative principle of water, from υδορ aqua, and γεινομας gignor[17]. We call the combination of this element with caloric hydrogen gas; and the term hydrogen expresses the base of that gas, or the radical of water.

[Pg 90]

This experiment furnishes us with a new combustible body, or, in other words, a body which has so much affinity with oxygen as to draw it from its connection with caloric, and to decompose air or oxygen gas. This combustible body has itself so great affinity with caloric, that, unless when engaged in a combination with some other body, it always subsists in the aëriform or gasseous state, in the usual temperature and pressure of our atmosphere. In this state of gas it is about 1/13 of the weight of an equal bulk of atmospheric air; it is not absorbed by water, though it is capable of holding a small quantity of that fluid in solution, and it is incapable of being used for respiration.

As the property this gas possesses, in common with all other combustible bodies, is nothing more than the power of decomposing air, and carrying off its oxygen from the caloric with which it was combined, it is easily understood that it cannot burn, unless in contact with air or oxygen gas. Hence, when we set fire to a bottle full of this gas, it burns gently, first at the neck of the bottle, and then in the inside of it, in proportion as the external air gets in: This combustion is slow and successive, and only takes place at the surface of contact between the two gasses. It is quite different when the two gasses are mixed before they are set on fire: If, for instance, after having introduced one part of[Pg 91] oxygen gas into a narrow mouthed bottle, we fill it up with two parts of hydrogen gas, and bring a lighted taper, or other burning body, to the mouth of the bottle, the combustion of the two gasses takes place instantaneously with a violent explosion. This experiment ought only to be made in a bottle of very strong green glass, holding not more than a pint, and wrapped round with twine, otherwise the operator will be exposed to great danger from the rupture of the bottle, of which the fragments will be thrown about with great force.

If all that has been related above, concerning the decomposition of water, be exactly conformable to truth;—if, as I have endeavoured to prove, that substance be really composed of hydrogen, as its proper constituent element, combined with oxygen, it ought to follow, that, by reuniting these two elements together, we should recompose water; and that this actually happens may be judged of by the following experiment.

Experiment Fourth.

I took a large cristal baloon, A, Pl. iv. fig. 5. holding about 30 pints, having a large opening, to which was cemented the plate of copper BC, pierced with four holes, in which four tubes terminate. The first tube, H h, is intended to[Pg 92] be adapted to an air pump, by which the baloon is to be exhausted of its air. The second tube gg, communicates, by its extremity MM, with a reservoir of oxygen gas, with which the baloon is to be filled. The third tube d D d', communicates, by its extremity d NN, with a reservoir of hydrogen gas. The extremity d' of this tube terminates in a capillary opening, through which the hydrogen gas contained in the reservoir is forced, with a moderate degree of quickness, by the pressure of one or two inches of water. The fourth tube contains a metallic wire GL, having a knob at its extremity L, intended for giving an electrical spark from L to d', on purpose to set fire to the hydrogen gas: This wire is moveable in the tube, that we may be able to separate the knob L from the extremity d' of the tube D d'. The three tubes d D d', gg, and H h, are all provided with stop-cocks.

That the hydrogen gas and oxygen gas may be as much as possible deprived of water, they are made to pass, in their way to the baloon A, through the tubes MM, NN, of about an inch diameter, and filled with salts, which, from their deliquescent nature, greedily attract the moisture of the air: Such are the acetite of potash, and the muriat or nitrat of lime[18]. These salts[Pg 93] must only be reduced to a coarse powder, lest they run into lumps, and prevent the gasses from geting through their interstices.

We must be provided before hand with a sufficient quantity of oxygen gas, carefully purified from all admixture of carbonic acid, by long contact with a solution of potash[19].

We must likewise have a double quantity of hydrogen gas, carefully purified in the same manner by long contact with a solution of potash in water. The best way of obtaining this gas free from mixture is, by decomposing water with very pure soft iron, as directed in Exp. 3. of this chapter.

Having adjusted every thing properly, as above directed, the tube H h is adapted to an air-pump, and the baloon A is exhausted of its air. We next admit the oxygen gas so as to fill the baloon, and then, by means of pressure, as is before mentioned, force a small stream of hydrogen gas through its tube D d', which we immediately set on fire by an electric spark. By means of the above described apparatus, we can[Pg 94] continue the mutual combustion of these two gasses for a long time, as we have the power of supplying them to the baloon from their reservoirs, in proportion as they are consumed. I have in another place[20] given a description of the apparatus used in this experiment, and have explained the manner of ascertaining the quantities of the gasses consumed with the most scrupulous exactitude.

In proportion to the advancement of the combustion, there is a deposition of water upon the inner surface of the baloon or matrass A: The water gradually increases in quantity, and, gathering into large drops, runs down to the bottom of the vessel. It is easy to ascertain the quantity of water collected, by weighing the baloon both before and after the experiment. Thus we have a twofold verification of our experiment, by ascertaining both the quantities of the gasses employed, and of the water formed by their combustion: These two quantities must be equal to each other. By an operation of this kind, Mr Meusnier and I ascertained that it required 85 parts, by weight, of oxygen, united to 15 parts of hydrogen, to compose 100 parts of water. This experiment, which has not hitherto been published, was made in presence of a numerous committee from the Royal Academy.[Pg 95] We exerted the most scrupulous attention to its accuracy; and have reason to believe that the above propositions cannot vary a two hundredth part from absolute truth.

From these experiments, both analytical and synthetic, we may now affirm that we have ascertained, with as much certainty as is possible in physical or chemical subjects, that water is not a simple elementary substance, but is composed of two elements, oxygen and hydrogen; which elements, when existing separately, have so strong affinity for caloric, as only to subsist under the form of gas in the common temperature and pressure of our atmosphere.

This decomposition and recomposition of water is perpetually operating before our eyes, in the temperature of the atmosphere, by means of compound elective attraction. We shall presently see that the phenomena attendant upon vinous fermentation, putrefaction, and even vegetation, are produced, at least in a certain degree, by decomposition of water. It is very extraordinary that this fact should have hitherto been overlooked by natural philosophers and chemists: Indeed, it strongly proves, that, in chemistry, as in moral philosophy, it is extremely difficult to overcome prejudices imbibed in early education, and to search for truth in any other road than the one we have been accustomed to follow.[Pg 96]

I shall finish this chapter by an experiment much less demonstrative than those already related, but which has appeared to make more impression than any other upon the minds of many people. When 16 ounces of alkohol are burnt in an apparatus[21] properly adapted for collecting all the water disengaged during the combustion, we obtain from 17 to 18 ounces of water. As no substance can furnish a product larger than its original bulk, it follows, that something else has united with the alkohol during its combustion; and I have already shown that this must be oxygen, or the base of air. Thus alkohol contains hydrogen, which is one of the elements of water; and the atmospheric air contains oxygen, which is the other element necessary to the composition of water. This experiment is a new proof that water is a compound substance.

[Pg 97]

CHAP. IX.

Of the quantities of Caloric disengaged from different species of Combustion.

We have already mentioned, that, when any body is burnt in the center of a hollow sphere of ice and supplied with air at the temperature of zero (32°), the quantity of ice melted from the inside of the sphere becomes a measure of the relative quantities of caloric disengaged. Mr de la Place and I gave a description of the apparatus employed for this kind of experiment in the Memoirs of the Academy for 1780, p. 355; and a description and plate of the same apparatus will be found in the third part of this work. With this apparatus, phosphorus, charcoal, and hydrogen gas, gave the following results:

One pound of phosphorus melted 100 libs. of ice.

One pound of charcoal melted 96 libs. 8 oz.

One pound of hydrogen gas melted 295 libs. 9 oz. 3-1/2 gros.

As a concrete acid is formed by the combustion of phosphorus, it is probable that very little caloric remains in the acid, and, consequently,[Pg 98] that the above experiment gives us very nearly the whole quantity of caloric contained in the oxygen gas. Even if we suppose the phosphoric acid to contain a good deal of caloric, yet, as the phosphorus must have contained nearly an equal quantity before combustion, the error must be very small, as it will only consist of the difference between what was contained in the phosphorus before, and in the phosphoric acid after combustion.

I have already shown in Chap. V. that one pound of phosphorus absorbs one pound eight ounces of oxygen during combustion; and since, by the same operation, 100 lib. of ice are melted, it follows, that the quantity of caloric contained in one pound of oxygen gas is capable of melting 66 libs. 10 oz. 5 gros 24 grs. of ice.

One pound of charcoal during combustion melts only 96 libs. 8 oz. of ice, whilst it absorbs 2 libs. 9 oz. 1 gros 10 grs. of oxygen. By the experiment with phosphorus, this quantity of oxygen gas ought to disengage a quantity of caloric sufficient to melt 171 libs. 6 oz. 5 gros of ice; consequently, during this experiment, a quantity of caloric, sufficient to melt 74 libs. 14 oz. 5 gros of ice disappears. Carbonic acid is not, like phosphoric acid, in a concrete state after combustion but in the state of gas, and requires to be united with caloric to enable it to[Pg 99] subsist in that state; the quantity of caloric missing in the last experiment is evidently employed for that purpose. When we divide that quantity by the weight of carbonic acid, formed by the combustion of one pound of charcoal, we find that the quantity of caloric necessary for changing one pound of carbonic acid from the concrete to the gasseous state, would be capable of melting 20 libs. 15 oz. 5 gros of ice.

We may make a similar calculation with the combustion of hydrogen gas and the consequent formation of water. During the combustion of one pound of hydrogen gas, 5 libs. 10 oz. 5 gros 24 grs. of oxygen gas are absorbed, and 295 libs. 9 oz. 3-1/2 gros of ice are melted. But 5 libs. 10 oz. 5 gros 24 grs. of oxygen gas, in changing from the aëriform to the solid state, loses, according to the experiment with phosphorus, enough of caloric to have melted 377 libs. 12 oz. 3 gros of ice. There is only disengaged, from the same quantity of oxygen, during its combustion with hydrogen gas, as much caloric as melts 295 libs. 2 oz. 3-1/2 gros; wherefore there remains in the water at Zero (32°), formed, during this experiment, as much caloric as would melt 82 libs. 9 oz. 7-1/2 gros of ice.

Hence, as 6 libs. 10 oz. 5 gros 24 grs. of water are formed from the combustion of one pound of hydrogen gas with 5 libs. 10 oz. 5 gros 24 grs. of oxygen, it follows that, in each[Pg 100] pound of water, at the temperature of Zero, (32°), there exists as much caloric as would melt 12 libs. 5 oz. 2 gros 48 grs. of ice, without taking into account the quantity originally contained in the hydrogen gas, which we have been obliged to omit, for want of data to calculate its quantity. From this it appears that water, even in the state of ice, contains a considerable quantity of caloric, and that oxygen, in entering into that combination, retains likewise a good proportion.

From these experiments, we may assume the following results as sufficiently established.

Combustion of Phosphorus.

From the combustion of phosphorus, as related in the foregoing experiments, it appears, that one pound of phosphorus requires 1 lib. 8 oz. of oxygen gas for its combustion, and that 2 libs. 8 oz. of concrete phosphoric acid are produced.

[Note A: We here suppose the phosphoric acid not to contain any caloric, which is not strictly true; but, as I have before observed, the quantity it really contains is probably very small, and we have not given it a value, for want of a sufficient data to go upon.—A.][Pg 101]

Combustion of Charcoal.

In the combustion of one pound of charcoal, 2 libs. 9 oz. 1 gros 10 grs. of oxygen gas are absorbed, and 3 libs. 9 oz. 1 gros 10 grs. of carbonic acid gas are formed.

[Note A: All these relative quantities of caloric are expressed by the number of pounds of ice, and decimal parts, melted during the several operations.—E.][Pg 102]

Combustion of Hydrogen Gas.

In the combustion of one pound of hydrogen gas, 5 libs. 10 oz. 5 gros 24 grs. of oxygen gas are absorbed, and 6 libs. 10 oz. 5 gros 24 grs. of water are formed.

Of the Formation of Nitric Acid.

When we combine nitrous gas with oxygen gas, so as to form nitric or nitrous acid a degree of heat is produced, which is much less considerable than what is evolved during the other combinations of oxygen; whence it follows that oxygen, when it becomes fixed in nitric acid, retains a great part of the heat which it possessed[Pg 103] in the state of gas. It is certainly possible to determine the quantity of caloric which is disengaged during the combination of these two gasses, and consequently to determine what quantity remains after the combination takes place. The first of these quantities might be ascertained, by making the combination of the two gasses in an apparatus surrounded by ice; but, as the quantity of caloric disengaged is very inconsiderable, it would be necessary to operate upon a large quantity of the two gasses in a very troublesome and complicated apparatus. By this consideration, Mr de la Place and I have hitherto been prevented from making the attempt. In the mean time, the place of such an experiment may be supplied by calculations, the results of which cannot be very far from truth.

Mr de la Place and I deflagrated a convenient quantity of nitre and charcoal in an ice apparatus, and found that twelve pounds of ice were melted by the deflagration of one pound of nitre. We shall see, in the sequel, that one pound of nitre is composed, as under, of

The above quantity of dry acid is composed of[Pg 104]

By this we find that, during the above deflagration, 2 gros 1-1/3 gr. of charcoal have suffered combustion, alongst with 3738.34 grs. or 6 oz. 3 gros 66.34 grs. of oxygen. Hence, since 12 libs. of ice were melted during the combustion, it follows, that one pound of oxygen burnt in the same manner would have melted 29.58320 libs. of ice. To which the quantity of caloric, retained by a pound of oxygen after combining with charcoal to form carbonic acid gas, being added, which was already ascertained to be capable of melting 29.13844 libs. of ice, we have for the total quantity of caloric remaining in a pound of oxygen, when combined with nitrous gas in the nitric acid 58.72164; which is the number of pounds of ice the caloric remaining in the oxygen in that state is capable of melting.

We have before seen that, in the state of oxygen gas, it contained at least 66.66667; wherefore it follows that, in combining with azote to form nitric acid, it only loses 7.94502. Farther experiments upon this subject are necessary to ascertain how far the results of this calculation may agree with direct fact. This enormous quantity of caloric retained by oxygen in its combination into nitric acid, explains the[Pg 105] cause of the great disengagement of caloric during the deflagrations of nitre; or, more strictly speaking, upon all occasions of the decomposition of nitric acid.

Of the Combustion of Wax.

Having examined several cases of simple combustion, I mean now to give a few examples of a more complex nature. One pound of wax-taper being allowed to burn slowly in an ice apparatus, melted 133 libs. 2 oz. 5-1/3 gros of ice. According to my experiments in the Memoirs of the Academy for 1784, p. 606, one pound of wax-taper consists of 13 oz. 1 gros 23 grs. of charcoal, and 2 oz. 6 gros 49 grs. of hydrogen.

Thus, we see the quantity of caloric disengaged from a burning taper, is pretty exactly conformable to what was obtained by burning separately a quantity of charcoal and hydrogen[Pg 106] equal to what enters into its composition. These experiments with the taper were several times repeated, so that I have reason to believe them accurate.

Combustion of Olive Oil.

We included a burning lamp, containing a determinate quantity of olive-oil, in the ordinary apparatus, and, when the experiment was finished, we ascertained exactly the quantities of oil consumed, and of ice melted; the result was, that, during the combustion of one pound of olive-oil, 148 libs. 14 oz. 1 gros of ice were melted. By my experiments in the Memoirs of the Academy for 1784, and of which the following Chapter contains an abstract, it appears that one pound of olive-oil consists of 12 oz. 5 gros 5 grs. of charcoal, and 3 oz. 2 gros 67 grs. of hydrogen. By the foregoing experiments, that quantity of charcoal should melt 76.18723 libs. of ice, and the quantity of hydrogen in a pound of the oil should melt 62.15053 libs. The sum of these two gives 138.33776 libs. of ice, which the two constituent elements of the oil would have melted, had they separately suffered combustion, whereas the oil really melted 148.88330 libs. which gives an excess of 10.54554 in the result of the experiment[Pg 107] above the calculated result, from data furnished by former experiments.

This difference, which is by no means very considerable, may arise from errors which are unavoidable in experiments of this nature, or it may be owing to the composition of oil not being as yet exactly ascertained. It proves, however, that there is a great agreement between the results of our experiments, respecting the combination of caloric, and those which regard its disengagement.

The following desiderata still remain to be determined, viz. What quantity of caloric is retained by oxygen, after combining with metals, so as to convert them into oxyds; What quantity is contained by hydrogen, in its different states of existence; and to ascertain, with more precision than is hitherto attained, how much caloric is disengaged during the formation of water, as there still remain considerable doubts with respect to our present determination of this point, which can only be removed by farther experiments. We are at present occupied with this inquiry; and, when once these several points are well ascertained, which we hope they will soon be, we shall probably be under the necessity of making considerable corrections upon most of the results of the experiments and calculations in this Chapter. I did not, however, consider this as a sufficient reason for withholding[Pg 108] so much as is already known from such as may be inclined to labour upon the same subject. It is difficult, in our endeavours to discover the principles of a new science, to avoid beginning by guess-work; and it is rarely possible to arrive at perfection from the first setting out.

[Pg 109]

CHAP. X.

Of the Combination of Combustible Substances with each other.

As combustible substances in general have a great affinity for oxygen, they ought likewise to attract, or tend to combine with each other; quae sunt eadem uni tertio, sunt eadem inter se; and the axiom is found to be true. Almost all the metals, for instance, are capable of uniting with each other, and forming what are called alloys[22], in common language. Most of these, like all combinations, are susceptible of several degrees of saturation; the greater number of these alloys are more brittle than the pure metals of which they are composed, especially when the metals alloyed together are considerably different in their degrees of fusibility. To this difference in fusibility, part of the phenomena attendant upon alloyage are owing, particularly the property of iron, called by workmen[Pg 110] hotshort. This kind of iron must be considered as an alloy, or mixture of pure iron, which is almost infusible, with a small portion of some other metal which fuses in a much lower degree of heat. So long as this alloy remains cold, and both metals are in the solid state, the mixture is malleable; but, if heated to a sufficient degree to liquify the more fusible metal, the particles of the liquid metal, which are interposed between the particles of the metal remaining solid, must destroy their continuity, and occasion the alloy to become brittle. The alloys of mercury, with the other metals, have usually been called amalgams, and we see no inconvenience from continuing the use of that term.

Sulphur, phosphorus, and charcoal, readily unite with metals. Combinations of sulphur with metals are usually named pyrites. Their combinations with phosphorus and charcoal are either not yet named, or have received new names only of late; so that we have not scrupled to change them according to our principles. The combinations of metal and sulphur we call sulphurets, those with phosphorus phosphurets, and those formed with charcoal carburets. These denominations are extended to all the combinations into which the above three substances enter, without being previously oxygenated.[Pg 111] Thus, the combination of sulphur with potash, or fixed vegetable alkali, is called sulphuret of potash; that which it forms with ammoniac, or volatile alkali, is termed sulphuret of ammoniac.

Hydrogen is likewise capable of combining with many combustible substances. In the state of gas, it dissolves charcoal, sulphur, phosphorus, and several metals; we distinguish these combinations by the terms, carbonated hydrogen gas, sulphurated hydrogen gas, and phosphorated hydrogen gas. The sulphurated hydrogen gas was called hepatic air by former chemists, or foetid air from sulphur, by Mr Scheele. The virtues of several mineral waters, and the foetid smell of animal excrements, chiefly arise from the presence of this gas. The phosphorated hydrogen gas is remarkable for the property, discovered by Mr Gengembre, of taking fire spontaneously upon getting into contact with atmospheric air, or, what is better, with oxygen gas. This gas has a strong flavour, resembling that of putrid fish; and it is very probable that the phosphorescent quality of fish, in the state of putrefaction, arises from the escape of this species of gas. When hydrogen and charcoal are combined together, without the intervention of caloric, to bring the hydrogen into the state of gas, they form oil, which is either fixed or volatile, according to the proportions of hydrogen and[Pg 112] charcoal in its composition. The chief difference between fixed or fat oils drawn from vegetables by expression, and volatile or essential oils, is, that the former contains an excess of charcoal, which is separated when the oils are heated above the degree of boiling water; whereas the volatile oils, containing a just proportion of these two constituent ingredients, are not liable to be decomposed by that heat, but, uniting with caloric into the gasseous state, pass over in distillation unchanged.

In the Memoirs of the Academy for 1784, p. 593. I gave an account of my experiments upon the composition of oil and alkohol, by the union of hydrogen with charcoal, and of their combination with oxygen. By these experiments, it appears that fixed oils combine with oxygen during combustion, and are thereby converted into water and carbonic acid. By means of calculation applied to the products of these experiments, we find that fixed oil is composed of 21 parts, by weight, of hydrogen combined with 79 parts of charcoal. Perhaps the solid substances of an oily nature, such as wax, contain a proportion of oxygen, to which they owe their state of solidity. I am at present engaged in a series of experiments, which I hope will throw great light upon this subject.

It is worthy of being examined, whether hydrogen in its concrete state, uncombined with[Pg 113] caloric, be susceptible of combination with sulphur, phosphorus, and the metals. There is nothing that we know of, which, a priori, should render these combinations impossible; for combustible bodies being in general susceptible of combination with each other, there is no evident reason for hydrogen being an exception to the rule: However, no direct experiment as yet establishes either the possibility or impossibility of this union. Iron and zinc are the most likely, of all the metals, for entering into combination with hydrogen; but, as these have the property of decomposing water, and as it is very difficult to get entirely free from moisture in chemical experiments, it is hardly possible to determine whether the small portions of hydrogen gas, obtained in certain experiments with these metals, were previously combined with the metal in the state of solid hydrogen, or if they were produced by the decomposition of a minute quantity of water. The more care we take to prevent the presence of water in these experiments, the less is the quantity of hydrogen gas procured; and, when very accurate precautions are employed, even that quantity becomes hardly sensible.

However this inquiry may turn out respecting the power of combustible bodies, as sulphur, phosphorus, and metals, to absorb hydrogen, we are certain that they only absorb a very small[Pg 114] portion; and that this combination, instead of being essential to their constitution, can only be considered as a foreign substance, which contaminates their purity. It is the province of the advocates[23] for this system to prove, by decisive experiments, the real existence of this combined hydrogen, which they have hitherto only done by conjectures founded upon suppositions.

[Pg 115]

CHAP. XI.

Observations upon Oxyds and Acids with several Bases—and upon the Composition of Animal and Vegetable Substances.

We have, in Chap. V. and VIII. examined the products resulting from the combustion of the four simple combustible substances, sulphur, phosphorus, charcoal, and hydrogen: We have shown, in Chap. X that the simple combustible substances are capable of combining with each other into compound combustible substances, and have observed that oils in general, and particularly the fixed vegetable oils, belong to this class, being composed of hydrogen and charcoal. It remains, in this chapter, to treat of the oxygenation of these compound combustible substances, and to show that there exist acids and oxyds having double and triple bases. Nature furnishes us with numerous examples of this kind of combinations, by means of which, chiefly, she is enabled to produce a vast variety of compounds from a very limited number of elements, or simple substances.[Pg 116]

It was long ago well known, that, when muriatic and nitric acids were mixed together, a compound acid was formed, having properties quite distinct from those of either of the acids taken separately. This acid was called aqua regia, from its most celebrated property of dissolving gold, called king of metals by the alchymists. Mr Berthollet has distinctly proved that the peculiar properties of this acid arise from the combined action of its two acidifiable bases; and for this reason we have judged it necessary to distinguish it by an appropriate name: That of nitro-muriatic acid appears extremely applicable, from its expressing the nature of the two substances which enter into its composition.

This phenomenon of a double base in one acid, which had formerly been observed only in the nitro-muriatic acid, occurs continually in the vegetable kingdom, in which a simple acid, or one possessed of a single acidifiable base, is very rarely found. Almost all the acids procurable from this kingdom have bases composed of charcoal and hydrogen, or of charcoal, hydrogen, and phosphorus, combined with more or less oxygen. All these bases, whether double or triple, are likewise formed into oxyds, having less oxygen than is necessary to give them the properties of acids. The acids and oxyds from the animal kingdom are still more compound, as their bases generally consist of a combination[Pg 117] of charcoal, phosphorus, hydrogen, and azote.

As it is but of late that I have acquired any clear and distinct notions of these substances, I shall not, in this place, enlarge much upon the subject, which I mean to treat of very fully in some memoirs I am preparing to lay before the Academy. Most of my experiments are already performed; but, to be able to give exact reports of the resulting quantities, it is necessary that they be carefully repeated, and increased in number: Wherefore, I shall only give a short enumeration of the vegetable and animal acids and oxyds, and terminate this article by a few reflections upon the composition of vegetable and animal bodies.

Sugar, mucus, under which term we include the different kinds of gums, and starch, are vegetable oxyds, having hydrogen and charcoal combined, in different proportions, as their radicals or bases, and united with oxygen, so as to bring them to the state of oxyds. From the state of oxyds they are capable of being changed into acids by the addition of a fresh quantity of oxygen; and, according to the degrees of oxygenation, and the proportion of hydrogen and charcoal in their bases, they form the several kinds of vegetable acids.

It would be easy to apply the principles of our nomenclature to give names to these vegetable[Pg 118] acids and oxyds, by using the names of the two substances which compose their bases: They would thus become hydro-carbonous acids and oxyds: In this method we might indicate which of their elements existed in excess, without circumlocution, after the manner used by Mr Rouelle for naming vegetable extracts: He calls these extracto-resinous when the extractive matter prevails in their composition, and resino-extractive when they contain a larger proportion of resinous matter. Upon that plan, and by varying the terminations according to the formerly established rules of our nomenclature, we have the following denominations: Hydro-carbonous, hydro-carbonic; carbono-hydrous, and carbono-hydric oxyds. And for the acids: Hydro-carbonous, hydro carbonic, oxygenated hydro-carbonic; carbono-hydrous, carbono-hydric, and oxygenated carbono-hydric. It is probable that the above terms would suffice for indicating all the varieties in nature, and that, in proportion as the vegetable acids become well understood, they will naturally arrange themselves under these denominations. But, though we know the elements of which these are composed, we are as yet ignorant of the proportions of these ingredients, and are still far from being able to class them in the above methodical manner; wherefore, we have determined to retain[Pg 119] the ancient names provisionally. I am somewhat farther advanced in this inquiry than at the time of publishing our conjunct essay upon chemical nomenclature; yet it would be improper to draw decided consequences from experiments not yet sufficiently precise: Though I acknowledge that this part of chemistry still remains in some degree obscure, I must express my expectations of its being very soon elucidated.

I am still more forcibly necessitated to follow the same plan in naming the acids, which have three or four elements combined in their bases; of these we have a considerable number from the animal kingdom, and some even from vegetable substances. Azote, for instance, joined to hydrogen and charcoal, form the base or radical of the Prussic acid; we have reason to believe that the same happens with the base of the Gallic acid; and almost all the animal acids have their bases composed of azote, phosphorus, hydrogen, and charcoal. Were we to endeavour to express at once all these four component parts of the bases, our nomenclature would undoubtedly be methodical; it would have the property of being clear and determinate; but this assemblage of Greek and Latin substantives and adjectives, which are not yet universally admitted by chemists, would have the appearance of a[Pg 120] barbarous language, difficult both to pronounce and to be remembered. Besides, this part of chemistry being still far from that accuracy it must arrive to, the perfection of the science ought certainly to precede that of its language; and we must still, for some time, retain the old names for the animal oxyds and acids. We have only ventured to make a few slight modifications of these names, by changing the termination into ous, when we have reason to suppose the base to be in excess, and into ic, when we suspect the oxygen predominates.

The following are all the vegetable acids hitherto known:

Though all these acids, as has been already said, are chiefly, and almost entirely, composed of hydrogen, charcoal, and oxygen, yet, properly speaking, they contain neither water carbonic acid nor oil, but only the elements necessary for forming these substances. The power of affinity reciprocally exerted by the hydrogen, charcoal, and oxygen, in these acids, is in a state[Pg 121] of equilibrium only capable of existing in the ordinary temperature of the atmosphere; for, when they are heated but a very little above the temperature of boiling water, this equilibrium is destroyed, part of the oxygen and hydrogen unite, and form water; part of the charcoal and hydrogen combine into oil; part of the charcoal and oxygen unite to form carbonic acid; and, lastly, there generally remains a small portion of charcoal, which, being in excess with respect to the other ingredients, is left free. I mean to explain this subject somewhat farther in the succeeding chapter.

The oxyds of the animal kingdom are hitherto less known than those from the vegetable kingdom, and their number is as yet not at all determined. The red part of the blood, lymph, and most of the secretions, are true oxyds, under which point of view it is very important to consider them. We are only acquainted with six animal acids, several of which, it is probable, approach very near each other in their nature, or, at least, differ only in a scarcely sensible degree. I do not include the phosphoric acid amongst these, because it is found in all the kingdoms of nature. They are,

The connection between the constituent elements of the animal oxyds and acids is not more permanent than in those from the vegetable kingdom, as a small increase of temperature is sufficient to overturn it. I hope to render this subject more distinct than has been done hitherto in the following chapter.

[Pg 123]

CHAP. XII.

Of the Decomposition of Vegetable and Animal Substances by the Action of Fire.

Before we can thoroughly comprehend what takes place during the decomposition of vegetable substances by fire, we must take into consideration the nature of the elements which enter into their composition, and the different affinities which the particles of these elements exert upon each other, and the affinity which caloric possesses with them. The true constituent elements of vegetables are hydrogen, oxygen, and charcoal: These are common to all vegetables, and no vegetable can exist without them: Such other substances as exist in particular vegetables are only essential to the composition of those in which they are found, and do not belong to vegetables in general.

Of these elements, hydrogen and oxygen have a strong tendency to unite with caloric, and be converted into gas, whilst charcoal is a fixed element, having but little affinity with caloric. On the other hand, oxygen, which, in the usual temperature, tends nearly equally to unite with hydrogen and with charcoal, has a much stronger[Pg 124] affinity with charcoal when at the red heat[24], and then unites with it to form carbonic acid.

Although we are far from being able to appreciate all these powers of affinity, or to express their proportional energy by numbers, we are certain, that, however variable they may be when considered in relation to the quantity of caloric with which they are combined, they are all nearly in equilibrium in the usual temperature of the atmosphere; hence vegetables neither contain oil[25], water, nor carbonic acid, tho' they contain all the elements of these substances. The hydrogen is neither combined with the oxygen nor with the charcoal, and reciprocally; the particles of these three substances form a triple combination, which remains in equilibrium[Pg 125] whilst undisturbed by caloric but a very slight increase of temperature is sufficient to overturn this structure of combination.

If the increased temperature to which the vegetable is exposed does not exceed the heat of boiling water, one part of the hydrogen combines with the oxygen, and forms water, the rest of the hydrogen combines with a part of the charcoal, and forms volatile oil, whilst the remainder of the charcoal, being set free from its combination with the other elements, remains fixed in the bottom of the distilling vessel.

When, on the contrary, we employ a red heat, no water is formed, or, at least, any that may have been produced by the first application of the heat is decomposed, the oxygen having a greater affinity with the charcoal at this degree of heat, combines with it to form carbonic acid, and the hydrogen being left free from combination with the other elements, unites with caloric, and escapes in the state of hydrogen gas. In this high temperature, either no oil is formed, or, if any was produced during the lower temperature at the beginning of the experiment, it is decomposed by the action of the red heat. Thus the decomposition of vegetable matter, under a high temperature, is produced by the action of double and triple affinities; while the charcoal attracts the oxygen,[Pg 126] on purpose to form carbonic acid, the caloric attracts the hydrogen, and converts it into hydrogen gas.

The distillation of every species of vegetable substance confirms the truth of this theory, if we can give that name to a simple relation of facts. When sugar is submitted to distillation, so long as we only employ a heat but a little below that of boiling water, it only loses its water of cristallization, it still remains sugar, and retains all its properties; but, immediately upon raising the heat only a little above that degree, it becomes blackened, a part of the charcoal separates from the combination, water slightly acidulated passes over accompanied by a little oil, and the charcoal which remains in the retort is nearly a third part of the original weight of the sugar.

The operation of affinities which take place during the decomposition, by fire, of vegetables which contain azote, such as the cruciferous plants, and of those containing phosphorus, is more complicated; but, as these substances only enter into the composition of vegetables in very small quantities, they only, apparently, produce slight changes upon the products of distillation; the phosphorus seems to combine with the charcoal, and, acquiring fixity from that union, remains behind in the retort, while the[Pg 127] azote, combining with a part of the hydrogen, forms ammoniac, or volatile alkali.

Animal substances, being composed nearly of the same elements with cruciferous plants, give the same products in distillation, with this difference, that, as they contain a greater quantity of hydrogen and azote, they produce more oil and more ammoniac. I shall only produce one fact as a proof of the exactness with which this theory explains all the phenomena which occur during the distillation of animal substances, which is the rectification and total decomposition of volatile animal oil, commonly known by the name of Dippel's oil. When these oils are procured by a first distillation in a naked fire they are brown, from containing a little charcoal almost in a free state; but they become quite colourless by rectification. Even in this state the charcoal in their composition has so slight a connection with the other elements as to separate by mere exposure to the air. If we put a quantity of this animal oil, well rectified, and consequently clear, limpid, and transparent, into a bell-glass filled with oxygen gas over mercury, in a short time the gas is much diminished, being absorbed by the oil, the oxygen combining with the hydrogen of the oil forms water, which sinks to the bottom, at the same time the charcoal which was combined with the hydrogen being set free, manifests itself[Pg 128] by rendering the oil black. Hence the only way of preserving these oils colourless and transparent, is by keeping them in bottles perfectly full and accurately corked, to hinder the contact of air, which always discolours them.

Successive rectifications of this oil furnish another phenomenon confirming our theory. In each distillation a small quantity of charcoal remains in the retort, and a little water is formed by the union of the oxygen contained in the air of the distilling vessels with the hydrogen of the oil. As this takes place in each successive distillation, if we make use of large vessels and a considerable degree of heat, we at last decompose the whole of the oil, and change it entirely into water and charcoal. When we use small vessels, and especially when we employ a slow fire, or degree of heat little above that of boiling water, the total decomposition of these oils, by repeated distillation, is greatly more tedious, and more difficultly accomplished. I shall give a particular detail to the Academy, in a separate memoir, of all my experiments upon the decomposition of oil; but what I have related above may suffice to give just ideas of the composition of animal and vegetable substances, and of their decomposition by the action of fire.

[Pg 129]

CHAP. XIII.

Of the Decomposition of Vegetable Oxyds by the Vinous Fermentation.

The manner in which wine, cyder, mead, and all the liquors formed by the spiritous fermentation, are produced, is well known to every one. The juice of grapes or of apples being expressed, and the latter being diluted with water, they are put into large vats, which are kept in a temperature of at least 10° (54.5°) of the thermometer. A rapid intestine motion, or fermentation, very soon takes place, numerous globules of gas form in the liquid and burst at the surface; when the fermentation is at its height, the quantity of gas disengaged is so great as to make the liquor appear as if boiling violently over a fire. When this gas is carefully gathered, it is found to be carbonic acid perfectly pure, and free from admixture with any other species of air or gas whatever.

When the fermentation is completed, the juice of grapes is changed from being sweet, and full of sugar, into a vinous liquor which no longer contains any sugar, and from which we procure, by distillation, an inflammable liquor,[Pg 130] known in commerce under the name of Spirit of Wine. As this liquor is produced by the fermentation of any saccharine matter whatever diluted with water, it must have been contrary to the principles of our nomenclature to call it spirit of wine rather than spirit of cyder, or of fermented sugar; wherefore, we have adopted a more general term, and the Arabic word alkohol seems extremely proper for the purpose.

This operation is one of the most extraordinary in chemistry: We must examine whence proceed the disengaged carbonic acid and the inflammable liquor produced, and in what manner a sweet vegetable oxyd becomes thus converted into two such opposite substances, whereof one is combustible, and the other eminently the contrary. To solve these two questions, it is necessary to be previously acquainted with the analysis of the fermentable substance, and of the products of the fermentation. We may lay it down as an incontestible axiom, that, in all the operations of art and nature, nothing is created; an equal quantity of matter exists both before and after the experiment; the quality and quantity of the elements remain precisely the same; and nothing takes place beyond changes and modifications in the combination of these elements. Upon this principle the whole art of performing chemical experiments[Pg 131] depends: We must always suppose an exact equality between the elements of the body examined and those of the products of its analysis.

Hence, since from must of grapes we procure alkohol and carbonic acid, I have an undoubted right to suppose that must consists of carbonic acid and alkohol. From these premises, we have two methods of ascertaining what passes during vinous fermentation, by determining the nature of, and the elements which compose, the fermentable substances, or by accurately examining the produces resulting from fermentation; and it is evident that the knowledge of either of these must lead to accurate conclusions concerning the nature and composition of the other. From these considerations, it became necessary accurately to determine the constituent elements of the fermentable substances; and, for this purpose, I did not make use of the compound juices of fruits, the rigorous analysis of which is perhaps impossible, but made choice of sugar, which is easily analysed, and the nature of which I have already explained. This substance is a true vegetable oxyd with two bases, composed of hydrogen and charcoal brought to the state of an oxyd, by a certain proportion of oxygen; and these three elements are combined in such a way, that a very slight force is sufficient to destroy the equilibrium of their connection. By[Pg 132] a long train of experiments, made in various ways, and often repeated, I ascertained that the proportion in which these ingredients exist in sugar, are nearly eight parts of hydrogen, 64 parts of oxygen, and 28 parts of charcoal, all by weight, forming 100 parts of sugar.

Sugar must be mixed with about four times its weight of water, to render it susceptible of fermentation; and even then the equilibrium of its elements would remain undisturbed, without the assistance of some substance, to give a commencement to the fermentation. This is accomplished by means of a little yeast from beer; and, when the fermentation is once excited, it continues of itself until completed. I shall, in another place, give an account of the effects of yeast, and other ferments, upon fermentable substances. I have usually employed 10 libs. of yeast, in the state of paste, for each 100 libs. of sugar, with as much water as is four times the weight of the sugar. I shall give the results of my experiments exactly as they were obtained, preserving even the fractions produced by calculation.[Pg 133]

Table I. Materials of Fermentation.

Table II. Constituent Elements of the Materials of Fermentation.

[Pg 134]

Table III. Recapitulation of these Elements.

Having thus accurately determined the nature and quantity of the constituent elements of the materials submitted to fermentation, we have next to examine the products resulting from that process. For this purpose, I placed the above 510 libs. of fermentable liquor in a proper[26] apparatus, by means of which I could accurately determine the quantity and quality of gas disengaged during the fermentation, and could even weigh every one of the products[Pg 135] separately, at any period of the process I judged proper. An hour or two after the substances are mixed together, especially if they are kept in a temperature of from 15° (65.75°) to 18° (72.5°) of the thermometer, the first marks of fermentation commence; the liquor turns thick and frothy, little globules of air are disengaged, which rise and burst at the surface; the quantity of these globules quickly increases, and there is a rapid and abundant production of very pure carbonic acid, accompanied with a scum, which is the yeast separating from the mixture. After some days, less or more according to the degree of heat, the intestine motion and disengagement of gas diminish; but these do not cease entirely, nor is the fermentation completed for a considerable time. During the process, 35 libs. 5 oz. 4 gros 19 grs. of dry carbonic acid are disengaged, which carry alongst with them 13 libs. 14 oz. 5 gros of water. There remains in the vessel 460 libs. 11 oz. 6 gros 53 grs. of vinous liquor, slightly acidulous. This is at first muddy, but clears of itself, and deposits a portion of yeast. When we separately analise all these substances, which is effected by very troublesome processes, we have the results as given in the following Tables. This process, with all the subordinate calculations and analyses, will be detailed at large in the Memoirs of the Academy.

[Pg 136]

Table IV. Product of Fermentation.

[Pg 137]

Table V. Recapitulation of the Products.

In these results, I have been exact, even to grains; not that it is possible, in experiments of this nature, to carry our accuracy so far, but as the experiments were made only with a few pounds of sugar, and as, for the sake of comparison, I reduced the results of the actual experiments to the quintal or imaginary hundred[Pg 138] pounds, I thought it necessary to leave the fractional parts precisely as produced by calculation.

When we consider the results presented by these tables with attention, it is easy to discover exactly what occurs during fermentation. In the first place, out of the 100 libs. of sugar employed, 4 libs. 1 oz. 4 gros 3 grs. remain, without having suffered decomposition; so that, in reality, we have only operated upon 95 libs. 14 oz. 3 gros 69 grs. of sugar; that is to say, upon 61 libs. 6 oz. 45 grs. of oxygen, 7 libs. 10 oz. 6 gros 6 grs. of hydrogen, and 26 libs. 13 oz. 5 gros 19 grs. of charcoal. By comparing these quantities, we find that they are fully sufficient for forming the whole of the alkohol, carbonic acid and acetous acid produced by the fermentation. It is not, therefore, necessary to suppose that any water has been decomposed during the experiment, unless it be pretended that the oxygen and hydrogen exist in the sugar in that state. On the contrary, I have already made it evident that hydrogen, oxygen and charcoal, the three constituent elements of vegetables, remain in a state of equilibrium or mutual union with each other which subsists so long as this union remains undisturbed by increased temperature, or by some new compound attraction; and that then[Pg 139] only these elements combine, two and two together, to form water and carbonic acid.

The effects of the vinous fermentation upon sugar is thus reduced to the mere separation of its elements into two portions; one part is oxygenated at the expence of the other, so as to form carbonic acid, whilst the other part, being deoxygenated in favour of the former, is converted into the combustible substance alkohol; therefore, if it were possible to reunite alkohol and carbonic acid together, we ought to form sugar. It is evident that the charcoal and hydrogen in the alkohol do not exist in the state of oil, they are combined with a portion of oxygen, which renders them miscible with water; wherefore these three substances, oxygen, hydrogen, and charcoal, exist here likewise in a species of equilibrium or reciprocal combination; and in fact, when they are made to pass through a red hot tube of glass or porcelain, this union or equilibrium is destroyed, the elements become combined, two and two, and water and carbonic acid are formed.

I had formally advanced, in my first Memoirs upon the formation of water, that it was decomposed in a great number of chemical experiments, and particularly during the vinous fermentation. I then supposed that water existed ready formed in sugar, though I am now convinced that sugar only contains the elements[Pg 140] proper for composing it. It may be readily conceived, that it must have cost me a good deal to abandon my first notions, but by several years reflection, and after a great number of experiments and observations upon vegetable substances, I have fixed my ideas as above.

I shall finish what I have to say upon vinous fermentation, by observing, that it furnishes us with the means of analysing sugar and every vegetable fermentable matter. We may consider the substances submitted to fermentation, and the products resulting from that operation, as forming an algebraic equation; and, by successively supposing each of the elements in this equation unknown, we can calculate their values in succession, and thus verify our experiments by calculation, and our calculation by experiment reciprocally. I have often successfully employed this method for correcting the first results of my experiments, and to direct me in the proper road for repeating them to advantage. I have explained myself at large upon this subject, in a Memoir upon vinous fermentation already presented to the Academy, and which will speedily be published.

[Pg 141]

CHAP. XIV.

Of the Putrefactive Fermentation.

The phenomena of putrefaction are caused, like those of vinous fermentation, by the operation of very complicated affinities. The constituent elements of the bodies submitted to this process cease to continue in equilibrium in the threefold combination, and form themselves anew into binary combinations[27], or compounds, consisting of two elements only; but these are entirely different from the results produced by the vinous fermentation. Instead of one part of the hydrogen remaining united with part of the water and charcoal to form alkohol, as in the vinous fermentation, the whole of the hydrogen is dissipated, during putrefaction, in the form of hydrogen gas, whilst, at the same time, the oxygen and charcoal, uniting with caloric, escape in the form of carbonic acid gas; so that, when the whole process is finished, especially[Pg 142] if the materials have been mixed with a sufficient quantity of water, nothing remains but the earth of the vegetable mixed with a small portion of charcoal and iron. Thus putrefaction is nothing more than a complete analysis of vegetable substance, during which the whole of the constituent elements is disengaged in form of gas, except the earth, which remains in the state of mould[28].

Such is the result of putrefaction when the substances submitted to it contain only oxygen, hydrogen, charcoal and a little earth. But this case is rare, and these substances putrify imperfectly and with difficulty, and require a considerable time to complete their putrefaction. It is otherwise with substances containing azote, which indeed exists in all animal matters, and even in a considerable number of vegetable substances. This additional element is remarkably favourable to putrefaction; and for this reason animal matter is mixed with vegetable, when the putrefaction of these is wished to be hastened. The whole art of forming composts and dunghills, for the purposes of agriculture, consists in the proper application of this admixture.

The addition of azote to the materials of putrefaction not only accelerates the process,[Pg 143] that element likewise combines with part of the hydrogen, and forms a new substance called volatile alkali or ammoniac. The results obtained by analysing animal matters, by different processes, leave no room for doubt with regard to the constituent elements of ammoniac; whenever the azote has been previously separated from these substances, no ammoniac is produced; and in all cases they furnish ammoniac only in proportion to the azote they contain. This composition of ammoniac is likewise fully proved by Mr Berthollet, in the Memoirs of the Academy for 1785, p. 316. where he gives a variety of analytical processes by which ammoniac is decomposed, and its two elements, azote and hydrogen, procured separately.

I already mentioned in Chap. X. that almost all combustible bodies were capable of combining with each other; hydrogen gas possesses this quality in an eminent degree, it dissolves charcoal, sulphur, and phosphorus, producing the compounds named carbonated hydrogen gas, sulphurated hydrogen gas, and phosphorated hydrogen gas. The two latter of these gasses have a peculiarly disagreeable flavour; the sulphurated hydrogen gas has a strong resemblance to the smell of rotten eggs, and the phosphorated smells exactly like putrid fish. Ammoniac has likewise a peculiar odour, not less penetrating, or less disagreeable, than these other gasses. From[Pg 144] the mixture of these different flavours proceeds the fetor which accompanies the putrefaction of animal substances. Sometimes ammoniac predominates, which is easily perceived by its sharpness upon the eyes; sometimes, as in feculent matters, the sulphurated gas is most prevalent; and sometimes, as in putrid herrings, the phosphorated hydrogen gas is most abundant.

I long supposed that nothing could derange or interrupt the course of putrefaction; but Mr Fourcroy and Mr Thouret have observed some peculiar phenomena in dead bodies, buried at a certain depth, and preserved to a certain degree, from contact with air; having found the muscular flesh frequently converted into true animal fat. This must have arisen from the disengagement of the azote, naturally contained in the animal substance, by some unknown cause, leaving only the hydrogen and charcoal remaining, which are the elements proper for producing fat or oil. This observation upon the possibility of converting animal substances into fat may some time or other lead to discoveries of great importance to society. The faeces of animals, and other excrementitious matters, are chiefly composed of charcoal and hydrogen, and approach considerably to the nature of oil, of which they furnish a considerable quantity by distillation with a naked fire; but the intolerable foetor which accompanies all the products[Pg 145] of these substances prevents our expecting that, at least for a long time, they can be rendered useful in any other way than as manures.

I have only given conjectural approximations in this Chapter upon the composition of animal substances, which is hitherto but imperfectly understood. We know that they are composed of hydrogen, charcoal, azote, phosphorus, and sulphur, all of which, in a state of quintuple combination, are brought to the state of oxyd by a larger or smaller quantity of oxygen. We are, however, still unacquainted with the proportions in which these substances are combined, and must leave it to time to complete this part of chemical analysis, as it has already done with several others.

[Pg 146]

CHAP. XV.

Of the Acetous Fermentation.

The acetous fermentation is nothing more than the acidification or oxygenation of wine[29], produced in the open air by means of the absorption of oxygen. The resulting acid is the acetous acid, commonly called Vinegar, which is composed of hydrogen and charcoal united together in proportions not yet ascertained, and changed into the acid state by oxygen. As vinegar is an acid, we might conclude from analogy that it contains oxygen, but this is put beyond doubt by direct experiments: In the first place, we cannot change wine into vinegar without the contact of air containing oxygen; secondly, this process is accompanied by a diminution of the volume of the air in which it is carried on from the absorption of its oxygen; and, thirdly, wine may be changed into vinegar by any other means of oxygenation.

[Pg 147]

Independent of the proofs which these facts furnish of the acetous acid being produced by the oxygenation of wine, an experiment made by Mr Chaptal, Professor of Chemistry at Montpellier, gives us a distinct view of what takes place in this process. He impregnated water with about its own bulk of carbonic acid from fermenting beer, and placed this water in a cellar in vessels communicating with the air, and in a short time the whole was converted into acetous acid. The carbonic acid gas procured from beer vats in fermentation is not perfectly pure, but contains a small quantity of alkohol in solution, wherefore water impregnated with it contains all the materials necessary for forming the acetous acid. The alkohol furnishes hydrogen and one portion of charcoal, the carbonic acid furnishes oxygen and the rest of the charcoal, and the air of the atmosphere furnishes the rest of the oxygen necessary for changing the mixture into acetous acid. From this observation it follows, that nothing but hydrogen is wanting to convert carbonic acid into acetous acid; or more generally, that, by means of hydrogen, and according to the degree of oxygenation, carbonic acid may be changed into all the vegetable acids; and, on the contrary, that, by depriving any of the vegetable acids of their hydrogen, they may be converted into carbonic acid.[Pg 148]

Although the principal facts relating to the acetous acid are well known, yet numerical exactitude is still wanting, till furnished by more exact experiments than any hitherto performed; wherefore I shall not enlarge any farther upon the subject. It is sufficiently shown by what has been said, that the constitution of all the vegetable acids and oxyds is exactly conformable to the formation of vinegar; but farther experiments are necessary to teach us the proportion of the constituent elements in all these acids and oxyds. We may easily perceive, however, that this part of chemistry, like all the rest of its divisions, makes rapid progress towards perfection, and that it is already rendered greatly more simple than was formerly believed.

[Pg 149]

CHAP. XVI.

Of the Formation of Neutral Salts, and of their different Bases.

We have just seen that all the oxyds and acids from the animal and vegetable kingdoms are formed by means of a small number of simple elements, or at least of such as have not hitherto been susceptible of decomposition, by means of combination with oxygen; these are azote, sulphur, phosphorus, charcoal, hydrogen, and the muriatic radical[30]. We may justly admire the simplicity of the means employed by nature to multiply qualities and forms, whether by combining three or four acidifiable bases in different proportions, or by altering the dose of oxygen employed for oxydating or acidifying them. We shall find the means no less simple and diversified, and as abundantly productive of forms and qualities, in the order of bodies we are now about to treat of.

[Pg 150]

Acidifiable substances, by combining with oxygen, and their consequent conversion into acids, acquire great susceptibility of farther combination; they become capable of uniting with earthy and metallic bodies, by which means neutral salts are formed. Acids may therefore be considered as true salifying principles, and the substances with which they unite to form neutral salts may be called salifiable bases: The nature of the union which these two principles form with each other is meant as the subject of the present chapter.

This view of the acids prevents me from considering them as salts, though they are possessed of many of the principal properties of saline bodies, as solubility in water, &c. I have already observed that they are the result of a first order of combination, being composed of two simple elements, or at least of elements which act as if they were simple, and we may therefore rank them, to use the language of Stahl, in the order of mixts. The neutral salts, on the contrary, are of a secondary order of combination, being formed by the union of two mixts with each other, and may therefore be termed compounds. Hence I shall not arrange the alkalies[31] or earths in the class of salts, to which I[Pg 151] allot only such as are composed of an oxygenated substance united to a base.

I have already enlarged sufficiently upon the formation of acids in the preceding chapter, and shall not add any thing farther upon that subject; but having as yet given no account of the salifiable bases which are capable of uniting with them to form neutral salts, I mean, in this chapter, to give an account of the nature and origin of each of these bases. These are potash, soda, ammoniac, lime, magnesia, barytes, argill[32], and all the metallic bodies.

§ 1. Of Potash.

We have already shown, that, when a vegetable substance is submitted to the action of fire in distilling vessels, its component elements, oxygen, hydrogen, and charcoal, which formed a threefold combination in a state of equilibrium, unite, two and two, in obedience to affinities which act conformable to the degree of heat[Pg 152] employed. Thus, at the first application of the fire, whenever the heat produced exceeds the temperature of boiling water, part of the oxygen and hydrogen unite to form water; soon after the rest of the hydrogen, and part of the charcoal, combine into oil; and, lastly, when the fire is pushed to the red heat, the oil and water, which had been formed in the early part of the process, become again decomposed, the oxygen and charcoal unite to form carbonic acid, a large quantity of hydrogen gas is set free, and nothing but charcoal remains in the retort.

A great part of these phenomena occur during the combustion of vegetables in the open air; but, in this case, the presence of the air introduces three new substances, the oxygen and azote of the air and caloric, of which two at least produce considerable changes in the results of the operation. In proportion as the hydrogen of the vegetable, or that which results from the decomposition of the water, is forced out in the form of hydrogen gas by the progress of the fire, it is set on fire immediately upon getting in contact with the air, water is again formed, and the greater part of the caloric of the two gasses becoming free produces flame. When all the hydrogen gas is driven out, burnt, and again reduced to water, the remaining charcoal continues to burn, but without flame; it is[Pg 153] formed into carbonic acid, which carries off a portion of caloric sufficient to give it the gasseous form; the rest of the caloric, from the oxygen of the air, being set free, produces the heat and light observed during the combustion of charcoal. The whole vegetable is thus reduced into water and carbonic acid, and nothing remains but a small portion of gray earthy matter called ashes, being the only really fixed principles which enter into the constitution of vegetables.

The earth, or rather ashes, which seldom exceeds a twentieth part of the weight of the vegetable, contains a substance of a particular nature, known under the name of fixed vegetable alkali, or potash. To obtain it, water is poured upon the ashes, which dissolves the potash, and leaves the ashes which are insoluble; by afterwards evaporating the water, we obtain the potash in a white concrete form: It is very fixed even in a very high degree of heat. I do not mean here to describe the art of preparing potash, or the method of procuring it in a state of purity, but have entered upon the above detail that I might not use any word not previously explained.

The potash obtained by this process is always less or more saturated with carbonic acid, which is easily accounted for: As the potash does not form, or at least is not set free, but in proportion[Pg 154] as the charcoal of the vegetable is converted into carbonic acid by the addition of oxygen, either from the air or the water, it follows, that each particle of potash, at the instant of its formation, or at least of its liberation, is in contact with a particle of carbonic acid, and, as there is a considerable affinity between these two substances, they naturally combine together. Although the carbonic acid has less affinity with potash than any other acid, yet it is difficult to separate the last portions from it. The most usual method of accomplishing this is to dissolve the potash in water; to this solution add two or three times its weight of quick-lime, then filtrate the liquor and evaporate it in close vessels; the saline substance left by the evaporation is potash almost entirely deprived of carbonic acid. In this state it is soluble in an equal weight of water, and even attracts the moisture of the air with great avidity; by this property it furnishes us with an excellent means of rendering air or gas dry by exposing them to its action. In this state it is soluble in alkohol, though not when combined with carbonic acid; and Mr Berthollet employs this property as a method of procuring potash in the state of perfect purity.

All vegetables yield less or more of potash in consequence of combustion, but it is furnished in various degrees of purity by different vegetables; usually, indeed, from all of them it is[Pg 155] mixed with different salts from which it is easily separable. We can hardly entertain a doubt that the ashes, or earth which is left by vegetables in combustion, pre-existed in them before they were burnt, forming what may be called the skeleton, or osseous part of the vegetable. But it is quite otherwise with potash; this substance has never yet been procured from vegetables but by means of processes or intermedia capable of furnishing oxygen and azote, such as combustion, or by means of nitric acid; so that it is not yet demonstrated that potash may not be a produce from these operations. I have begun a series of experiments upon this object, and hope soon to be able to give an account of their results.

§ 2. Of Soda.

Soda, like potash, is an alkali procured by lixiviation from the ashes of burnt plants, but only from those which grow upon the sea-side, and especially from the herb kali, whence is derived the name alkali, given to this substance by the Arabians. It has some properties in common with potash, and others which are entirely different: In general, these two substances have peculiar characters in their saline combinations which are proper to each, and consequently distinguish them from each other; thus soda,[Pg 156] which, as obtained from marine plants, is usually entirely saturated with carbonic acid, does not attract the humidity of the atmosphere like potash, but, on the contrary, desiccates, its cristals effloresce, and are converted into a white powder having all the properties of soda, which it really is, having only lost its water of cristallization.

Hitherto we are not better acquainted with the constituent elements of soda than with those of potash, being equally uncertain whether it previously existed ready formed in the vegetable or is a combination of elements effected by combustion. Analogy leads us to suspect that azote is a constituent element of all the alkalies, as is the case with ammoniac; but we have only slight presumptions, unconfirmed by any decisive experiments, respecting the composition of potash and soda.

§ 3. Of Ammoniac.

We have, however, very accurate knowledge of the composition of ammoniac, or volatile alkali, as it is called by the old chemists. Mr Berthollet, in the Memoirs of the Academy for 1784, p. 316. has proved by analysis, that 1000 parts of this substance consist of about 807 parts of azote combined with 193 parts of hydrogen.[Pg 157]

Ammoniac is chiefly procurable from animal substances by distillation, during which process the azote and hydrogen necessary to its formation unite in proper proportions; it is not, however, procured pure by this process, being mixed with oil and water, and mostly saturated with carbonic acid. To separate these substances it is first combined with an acid, the muriatic for instance, and then disengaged from that combination by the addition of lime or potash. When ammoniac is thus produced in its greatest degree of purity it can only exist under the gasseous form, at least in the usual temperature of the atmosphere, it has an excessively penetrating smell, is absorbed in large quantities by water, especially if cold and assisted by compression. Water thus saturated with ammoniac has usually been termed volatile alkaline fluor; we shall call it either simply ammoniac, or liquid ammoniac, and ammoniacal gas when it exists in the aëriform state.

§ 4. Of Lime, Magnesia, Barytes, and Argill.

The composition of these four earths is totally unknown, and, until by new discoveries their constituent elements are ascertained, we are certainly authorised to consider them as simple bodies. Art has no share in the production of these earths, as they are all procured ready formed[Pg 158] from nature; but, as they have all, especially the three first, great tendency to combination, they are never found pure. Lime is usually saturated with carbonic acid in the state of chalk, calcarious spars, most of the marbles, &c.; sometimes with sulphuric acid, as in gypsum and plaster stones; at other times with fluoric acid forming vitreous or fluor spars; and, lastly, it is found in the waters of the sea, and of saline springs, combined with muriatic acid. Of all the salifiable bases it is the most universally spread through nature.

Magnesia is found in mineral waters, for the most part combined with sulphuric acid; it is likewise abundant in sea-water, united with muriatic acid; and it exists in a great number of stones of different kinds.

Barytes is much less common than the three preceding earths; it is found in the mineral kingdom, combined with sulphuric acid, forming heavy spars, and sometimes, though rarely, united to carbonic acid.

Argill, or the base of alum, having less tendency to combination than the other earths, is often found in the state of argill, uncombined with any acid. It is chiefly procurable from clays, of which, properly speaking, it is the base, or chief ingredient.[Pg 159]

§ 5. Of Metallic Bodies.

The metals, except gold, and sometimes silver, are rarely found in the mineral kingdom in their metallic state, being usually less or more saturated with oxygen, or combined with sulphur, arsenic, sulphuric acid, muriatic acid, carbonic acid, or phosphoric acid. Metallurgy, or the docimastic art, teaches the means of separating them from these foreign matters; and for this purpose we refer to such chemical books as treat upon these operations.

We are probably only acquainted as yet with a part of the metallic substances existing in nature, as all those which have a stronger affinity to oxygen, than charcoal possesses, are incapable of being reduced to the metallic state, and, consequently, being only presented to our observation under the form of oxyds, are confounded with earths. It is extremely probable that barytes, which we have just now arranged with earths, is in this situation; for in many experiments it exhibits properties nearly approaching to those of metallic bodies. It is even possible that all the substances we call earths may be only metallic oxyds, irreducible by any hitherto known process.

Those metallic bodies we are at present acquainted with, and which we can reduce to the[Pg 160] metallic or reguline state, are the following seventeen:

I only mean to consider these as salifiable bases, without entering at all upon the consideration of their properties in the arts, and for the uses of society. In these points of view each metal would require a complete treatise, which would lead me far beyond the bounds I have prescribed for this work.

[Pg 161]

CHAP. XVII.

Continuation of the Observations upon Salifiable Bases, and the Formation of Neutral Salts.

It is necessary to remark, that earths and alkalies unite with acids to form neutral salts without the intervention of any medium, whereas metallic substances are incapable of forming this combination without being previously less or more oxygenated; strictly speaking, therefore, metals are not soluble in acids, but only metallic oxyds. Hence, when we put a metal into an acid for solution, it is necessary, in the first place, that it become oxygenated, either by attracting oxygen from the acid or from the water; or, in other words, that a metal cannot be dissolved in an acid unless the oxygen, either of the acid, or of the water mixed with it, has a stronger affinity to the metal than to the hydrogen or the acidifiable base; or, what amounts to the same thing, that no metallic solution can take place without a previous decomposition of the water, or the acid in which it is made. The explanation of the principal phenomena of metallic solution depends entirely[Pg 162] upon this simple observation, which was overlooked even by the illustrious Bergman.

The first and most striking of these is the effervescence, or, to speak less equivocally, the disengagement of gas which takes place during the solution; in the solutions made in nitric acid this effervescence is produced by the disengagement of nitrous gas; in solutions with sulphuric acid it is either sulphurous acid gas or hydrogen gas, according as the oxydation of the metal happens to be made at the expence of the sulphuric acid or of the water. As both nitric acid and water are composed of elements which, when separate, can only exist in the gasseous form, at least in the common temperature of the atmosphere, it is evident that, whenever either of these is deprived of its oxygen, the remaining element must instantly expand and assume the state of gas; the effervescence is occasioned by this sudden conversion from the liquid to the gasseous state. The same decomposition, and consequent formation of gas, takes place when solutions of metals are made in sulphuric acid: In general, especially by the humid way, metals do not attract all the oxygen it contains; they therefore reduce it, not into sulphur, but into sulphurous acid, and as this acid can only exist as gas in the usual temperature, it is disengaged, and occasions effervescence.[Pg 163]

The second phenomenon is, that, when the metals have been previously oxydated, they all dissolve in acids without effervescence: This is easily explained; because, not having now any occasion for combining with oxygen, they neither decompose the acid nor the water by which, in the former case, the effervescence is occasioned.

A third phenomenon, which requires particular consideration, is, that none of the metals produce effervescence by solution in oxygenated muriatic acid. During this process the metal, in the first place, carries off the excess of oxygen from the oxygenated muriatic acid, by which it becomes oxydated, and reduces the acid to the state of ordinary muriatic acid. In this case there is no production of gas, not that the muriatic acid does not tend to exist in the gasseous state in the common temperature, which it does equally with the acids formerly mentioned, but because this acid, which otherwise would expand into gas, finds more water combined with the oxygenated muriatic acid than is necessary to retain it in the liquid form; hence it does not disengage like the sulphurous acid, but remains, and quietly dissolves and combines with the metallic oxyd previously formed from its superabundant oxygen.

The fourth phenomenon is, that metals are absolutely insoluble in such acids as have their[Pg 164] bases joined to oxygen by a stronger affinity than these metals are capable of exerting upon that acidifying principle. Hence silver, mercury, and lead, in their metallic states, are insoluble in muriatic acid, but, when previously oxydated, they become readily soluble without effervescence.

From these phenomena it appears that oxygen is the bond of union between metals and acids; and from this we are led to suppose that oxygen is contained in all substances which have a strong affinity with acids: Hence it is very probable the four eminently salifiable earths contain oxygen, and their capability of uniting with acids is produced by the intermediation of that element. What I have formerly noticed relative to these earths is considerably strengthened by the above considerations, viz. that they may very possibly be metallic oxyds, with which oxygen has a stronger affinity than with charcoal, and consequently not reducible by any known means.

All the acids hitherto known are enumerated in the following table, the first column of which contains the names of the acids according to the new nomenclature, and in the second column are placed the bases or radicals of these acids, with observations.[Pg 165]

[Note A: This term swerves a little from the rule in making the name of this acid terminate in ac instead of ic. The base and acid are distinguished in French by arsenic and arsenique; but, having chosen the English termination ic to translate the French ique, I was obliged to use this small deviation.—E.]

[Note B: Mr Lavoisier has hydrargirique; but mercurius being used for the base or metal, the name of the acid, as above, is equally regular, and less harsh.—E.]

In this list, which contains 48 acids, I have enumerated 17 metallic acids hitherto very imperfectly known, but upon which Mr Berthollet is about to publish a very important work. It cannot be pretended that all the acids which exist in nature, or rather all the acidifiable bases, are yet discovered; but, on the other hand, there are considerable grounds for supposing that a more accurate investigation than has hitherto been attempted will diminish the number of the vegetable acids, by showing that several of these, at present considered as distinct acids, are only[Pg 167] modifications of others. All that can be done in the present state of our knowledge is, to give a view of chemistry as it really is, and to establish fundamental principles, by which such bodies as may be discovered in future may receive names, in conformity with one uniform system.

The known salifiable bases, or substances capable of being converted into neutral salts by union with acids, amount to 24; viz. 3 alkalies, 4 earths, and 17 metallic substances; so that, in the present state of chemical knowledge, the whole possible number of neutral salts amounts to 1152[33]. This number is upon the supposition that the metallic acids are capable of dissolving other metals, which is a new branch of chemistry not hitherto investigated, upon which depends all the metallic combinations named vitreous. There is reason to believe that many of these supposable saline combinations are not capable of being formed, which must greatly reduce the real number of neutral salts producible by nature and art. Even if we suppose the real number to amount only to five or six hundred species of possible neutral salts, it is evident that, were we to distinguish them, after[Pg 168] the manner of the ancients, either by the names of their first discoverers, or by terms derived from the substances from which they are procured, we should at last have such a confusion of arbitrary designations, as no memory could possibly retain. This method might be tolerable in the early ages of chemistry, or even till within these twenty years, when only about thirty species of salts were known; but, in the present times, when the number is augmenting daily, when every new acid gives us 24 or 48 new salts, according as it is capable of one or two degrees of oxygenation, a new method is certainly necessary. The method we have adopted, drawn from the nomenclature of the acids, is perfectly analogical, and, following nature in the simplicity of her operations, gives a natural and easy nomenclature applicable to every possible neutral salt.

In giving names to the different acids, we express the common property by the generical term acid, and distinguish each species by the name of its peculiar acidifiable base. Hence the acids formed by the oxygenation of sulphur, phosphorus, charcoal, &c. are called sulphuric acid, phosphoric acid, carbonic acid, &c. We thought it likewise proper to indicate the different degrees of saturation with oxygen, by different terminations of the same specific names.[Pg 169] Hence we distinguish between sulphurous and sulphuric, and between phosphorous and phosphoric acids, &c.

By applying these principles to the nomenclature of neutral salts, we give a common term to all the neutral salts arising from the combination of one acid, and distinguish the species by adding the name of the salifiable base. Thus, all the neutral salts having sulphuric acid in their composition are named sulphats; those formed by the phosphoric acid, phosphats, &c. The species being distinguished by the names of the salifiable bases gives us sulphat of potash, sulphat of soda, sulphat of ammoniac, sulphat of lime, sulphat of iron, &c. As we are acquainted with 24 salifiable bases, alkaline, earthy, and metallic, we have consequently 24 sulphats, as many phosphats, and so on through all the acids. Sulphur is, however, susceptible of two degrees of oxygenation, the first of which produces sulphurous, and the second, sulphuric acid; and, as the neutral salts produced by these two acids, have different properties, and are in fact different salts, it becomes necessary to distinguish these by peculiar terminations; we have therefore distinguished the neutral salts formed by the acids in the first or lesser degree of oxygenation, by changing the termination at into ite, as sulphites, phosphites[34], &c. Thus, oxygenated[Pg 170] or acidified sulphur, in its two degrees of oxygenation is capable of forming 48 neutral salts, 24 of which are sulphites, and as many sulphats; which is likewise the case with all the acids capable of two degrees of oxygenation[35].

It were both tiresome and unnecessary to follow these denominations through all the varieties of their possible application; it is enough to have given the method of naming the various salts, which, when once well understood, is easily applied to every possible combination. The name of the combustible and acidifiable body being once known, the names of the acid it is capable of forming, and of all the neutral combinations[Pg 171] the acid is susceptible of entering into, are most readily remembered. Such as require a more complete illustration of the methods in which the new nomenclature is applied will, in the Second Part of this book, find Tables which contain a full enumeration of all the neutral salts, and, in general, all the possible chemical combinations, so far as is consistent with the present state of our knowledge. To these I shall subjoin short explanations, containing the best and most simple means of procuring the different species of acids, and some account of the general properties of the neutral salts they produce.

I shall not deny, that, to render this work more complete, it would have been necessary to add particular observations upon each species of salt, its solubility in water and alkohol, the proportions of acid and of salifiable base in its composition, the quantity of its water of cristallization, the different degrees of saturation it is susceptible of, and, finally, the degree of force or affinity with which the acid adheres to the base. This immense work has been already begun by Messrs Bergman, Morveau, Kirwan, and other celebrated chemists, but is hitherto only in a moderate state of advancement, even the principles upon which it is founded are not perhaps sufficiently accurate.[Pg 172]

These numerous details would have swelled this elementary treatise to much too great a size; besides that, to have gathered the necessary materials, and to have completed all the series of experiments requisite, must have retarded the publication of this book for many years. This is a vast field for employing the zeal and abilities of young chemists, whom I would advise to endeavour rather to do well than to do much, and to ascertain, in the first place, the composition of the acids, before entering upon that of the neutral salts. Every edifice which is intended to resist the ravages of time should be built upon a sure foundation; and, in the present state of chemistry, to attempt discoveries by experiments, either not perfectly exact, or not sufficiently rigorous, will serve only to interrupt its progress, instead of contributing to its advancement.

[Pg 173]

PART II.

Of the Combination of Acids with Salifiable Bases, and of the Formation of Neutral Salts.

INTRODUCTION.

If I had strictly followed the plan I at first laid down for the conduct of this work, I would have confined myself, in the Tables and accompanying observations which compose this Second Part, to short definitions of the several known acids, and abridged accounts of the processes by which they are obtainable, with a mere nomenclature or enumeration of the neutral salts which result from the combination of these acids with the various salifiable bases. But I afterwards found that the addition of similar Tables of all the simple substances which enter[Pg 174] into the composition of the acids and oxyds, together with the various possible combinations of these elements, would add greatly to the utility of this work, without being any great increase to its size. These additions, which are all contained in the twelve first sections of this Part, and the Tables annexed to these, form a kind of recapitulation of the first fifteen Chapters of the First Part: The rest of the Tables and Sections contain all the saline combinations.

It must be very apparent that, in this Part of the Work, I have borrowed greatly from what has been already published by Mr de Morveau in the First Volume of the Encyclopedie par ordre des Matières. I could hardly have discovered a better source of information, especially when the difficulty of consulting books in foreign languages is considered. I make this general acknowledgment on purpose to save the trouble of references to Mr de Morveau's work in the course of the following part of mine.[Pg 175]

TABLE OF SIMPLE SUBSTANCES.

Simple substances belonging to all the kingdoms of nature, which may be considered as the elements of bodies.

Oxydable and Acidifiable simple Substance not Metallic.

Oxydable and Acidifiable simple Metallic Bodies

[Pg 176]

Salifiable simple Earthy Substances.

Sect. I.—Observations upon the Table of Simple Substances.

The principle object of chemical experiments is to decompose natural bodies, so as separately to examine the different substances which enter into their composition. By consulting chemical systems, it will be found that this science of chemical analysis has made rapid progress in our own times. Formerly oil and salt were considered as elements of bodies, whereas later observation and experiment have shown that all salts, instead of being simple, are composed of an acid united to a base. The bounds of analysis have been greatly enlarged by modern discoveries[36]; the acids are shown to be composed of oxygen, as an acidifying principle common to all, united in each to a particular base. I have proved what Mr Haffenfratz had[Pg 177] before advanced, that these radicals of the acids are not all simple elements, many of them being, like the oily principle, composed of hydrogen and charcoal. Even the bases of neutral salts have been proved by Mr Berthollet to be compounds, as he has shown that ammoniac is composed of azote and hydrogen.

Thus, as chemistry advances towards perfection, by dividing and subdividing, it is impossible to say where it is to end; and these things we at present suppose simple may soon be found quite otherwise. All we dare venture to affirm of any substance is, that it must be considered as simple in the present state of our knowledge, and so far as chemical analysis has hitherto been able to show. We may even presume that the earths must soon cease to be considered as simple bodies; they are the only bodies of the salifiable class which have no tendency to unite with oxygen; and I am much inclined to believe that this proceeds from their being already saturated with that element. If so, they will fall to be considered as compounds consisting of simple substances, perhaps metallic, oxydated to a certain degree. This is only hazarded as a conjecture; and I trust the reader will take care not to confound what I have related as truths, fixed on the firm basis of observation and experiment, with mere hypothetical conjectures.[Pg 178]

The fixed alkalies, potash, and soda, are omitted in the foregoing Table, because they are evidently compound substances, though we are ignorant as yet what are the elements they are composed of.[Pg 179]

Table of compound oxydable and acidifiable bases.

Note.—The radicals from the vegetable kingdom are converted by a first degree of oxygenation into vegetable oxyds, such as sugar, starch, and gum or mucus: Those of the animal kingdom by the same means form animal oxyds, as lymph, &c.—A.[Pg 180]

Sect. II.—Observations upon the Table of Compound Radicals.

The older chemists being unacquainted with the composition of acids, and not suspecting them to be formed by a peculiar radical or base for each, united to an acidifying principle or element common to all, could not consequently give any name to substances of which they had not the most distant idea. We had therefore to invent a new nomenclature for this subject, though we were at the same time sensible that this nomenclature must be susceptible of great modification when the nature of the compound radicals shall be better understood[37].

The compound oxydable and acidifiable radicals from the vegetable and animal kingdoms, enumerated in the foregoing table, are not hitherto reducible to systematic nomenclature, because their exact analysis is as yet unknown. We only know in general, by some experiments of my own, and some made by Mr Hassenfratz, that most of the vegetable acids, such as the tartarous, oxalic, citric, malic, acetous, pyro-tartarous, and pyromucous, have radicals composed of hydrogen and charcoal, combined in[Pg 181] such a way as to form single bases, and that these acids only differ from each other by the proportions in which these two substances enter into the composition of their bases, and by the degree of oxygenation which these bases have received. We know farther, chiefly from the experiments of Mr Berthollet, that the radicals from the animal kingdom, and even some of those from vegetables, are of a more compound nature, and, besides hydrogen and charcoal, that they often contain azote, and sometimes phosphorus; but we are not hitherto possessed of sufficiently accurate experiments for calculating the proportions of these several substances. We are therefore forced, in the manner of the older chemists, still to name these acids after the substances from which they are procured. There can be little doubt that these names will be laid aside when our knowledge of these substances becomes more accurate and extensive; the terms hydro-carbonous, hydro-carbonic, carbono-hydrous, and carbono hydric[38], will then become substituted for those we now employ, which will then only remain as testimonies of the imperfect state in which this part of chemistry was transmitted to us by our predecessors.

[Pg 182]

It is evident that the oils, being composed of hydrogen and charcoal combined, are true carbono-hydrous or hydro-carbonous radicals; and, indeed, by adding oxygen, they are convertible into vegetable oxyds and acids, according to their degrees of oxygenation. We cannot, however, affirm that oils enter in their entire state into the composition of vegetable oxyds and acids; it is possible that they previously lose a part either of their hydrogen or charcoal, and that the remaining ingredients no longer exist in the proportions necessary to constitute oils. We still require farther experiments to elucidate these points.

Properly speaking, we are only acquainted with one compound radical from the mineral kingdom, the nitro-muriatic, which is formed by the combination of azote with the muriatic radical. The other compound mineral acids have been much less attended to, from their producing less striking phenomena.

Sect. III.—Observations upon the Combinations of Light and Caloric with different Substances.

I have not constructed any table of the combinations of light and caloric with the various simple and compound substances, because our conceptions of the nature of these combinations are not hitherto sufficiently accurate. We[Pg 183] know, in general, that all bodies in nature are imbued, surrounded, and penetrated in every way with caloric, which fills up every interval left between their particles; that, in certain cases, caloric becomes fixed in bodies, so as to constitute a part even of their solid substance, though it more frequently acts upon them with a repulsive force, from which, or from its accumulation in bodies to a greater or lesser degree, the transformation of solids into fluids, and of fluids to aëriform elasticity, is entirely owing. We have employed the generic name gas to indicate this aëriform state of bodies produced by a sufficient accumulation of caloric; so that, when we wish to express the aëriform state of muriatic acid, carbonic acid, hydrogen, water, alkohol, &c. we do it by adding the word gas to their names; thus muriatic acid gas, carbonic acid gas, hydrogen gas, aqueous gas, alkoholic gas, &c.

The combinations of light, and its mode of acting upon different bodies, is still less known. By the experiments of Mr Berthollet, it appears to have great affinity with oxygen, is susceptible of combining with it, and contributes alongst with caloric to change it into the state of gas. Experiments upon vegetation give reason to believe that light combines with certain parts of vegetables, and that the green of their leaves, and the various colours of their flowers, is chiefly[Pg 184] owing to this combination. This much is certain, that plants which grow in darkness are perfectly white, languid, and unhealthy, and that to make them recover vigour, and to acquire their natural colours, the direct influence of light is absolutely necessary. Somewhat similar takes place even upon animals: Mankind degenerate to a certain degree when employed in sedentary manufactures, or from living in crowded houses, or in the narrow lanes of large cities; whereas they improve in their nature and constitution in most of the country labours which are carried on in the open air. Organization, sensation, spontaneous motion, and all the operations of life, only exist at the surface of the earth, and in places exposed to the influence of light. Without it nature itself would be lifeless and inanimate. By means of light, the benevolence of the Deity hath filled the surface of the earth with organization, sensation, and intelligence. The fable of Promotheus might perhaps be considered as giving a hint of this philosophical truth, which had even presented itself to the knowledge of the ancients. I have intentionally avoided any disquisitions relative to organized bodies in this work, for which reason the phenomena of respiration, sanguification, and animal heat, are not considered; but I hope, at some future time, to be able to elucidate these curious subjects.

[Trancriber's note: The following table has been split into four sections ease reading]

TABLE of the binary Combinations of Oxygen with simple Substances

[Note A: Only one degree of oxygenation of hydrogen is hitherto known.—A.]

[Note B: Ethiops mineral is the sulphuret of mercury; this should have been called black precipitate of mercury.—E.][Pg 185]

Sect. IV.—Observations upon the Combinations of Oxygen with the simple Substances.

Oxygen forms almost a third of the mass of our atmosphere, and is consequently one of the most plentiful substances in nature. All the animals and vegetables live and grow in this immense magazine of oxygen gas, and from it we procure the greatest part of what we employ in experiments. So great is the reciprocal affinity between this element and other substances, that we cannot procure it disengaged from all combination. In the atmosphere it is united with caloric, in the state of oxygen gas, and this again is mixed with about two thirds of its weight of azotic gas.

Several conditions are requisite to enable a body to become oxygenated, or to permit oxygen to enter into combination with it. In the first place, it is necessary that the particles of the body to be oxygenated shall have less reciprocal attraction with each other than they have for the oxygen, which otherwise cannot possibly combine with them. Nature, in this case, may be assisted by art, as we have it in our power to diminish the attraction of the particles of bodies almost at will by heating them, or, in other words, by introducing caloric into the interstices[Pg 186] between their particles; and, as the attraction of these particles for each other is diminished in the inverse ratio of their distance, it is evident that there must be a certain point of distance of particles when the affinity they possess with each other becomes less than that they have for oxygen, and at which oxygenation must necessarily take place if oxygen be present.

We can readily conceive that the degree of heat at which this phenomenon begins must be different in different bodies. Hence, on purpose to oxygenate most bodies, especially the greater part of the simple substances, it is only necessary to expose them to the influence of the air of the atmosphere in a convenient degree of temperature. With respect to lead, mercury, and tin, this needs be but little higher than the medium temperature of the earth; but it requires a more considerable degree of heat to oxygenate iron, copper, &c. by the dry way, or when this operation is not assisted by moisture. Sometimes oxygenation takes place with great rapidity, and is accompanied by great sensible heat, light, and flame; such is the combustion of phosphorus in atmospheric air, and of iron in oxygen gas. That of sulphur is less rapid; and the oxygenation of lead, tin, and most of the metals, takes place vastly slower, and consequently the disengagement of caloric, and more especially of light, is hardly sensible.[Pg 187]

Some substances have so strong an affinity with oxygen, and combine with it in such low degrees of temperature, that we cannot procure them in their unoxygenated state; such is the muriatic acid, which has not hitherto been decomposed by art, perhaps even not by nature, and which consequently has only been found in the state of acid. It is probable that many other substances of the mineral kingdom are necessarily oxygenated in the common temperature of the atmosphere, and that being already saturated with oxygen, prevents their farther action upon that element.

There are other means of oxygenating simple substances besides exposure to air in a certain degree of temperature, such as by placing them in contact with metals combined with oxygen, and which have little affinity with that element. The red oxyd of mercury is one of the best substances for this purpose, especially with bodies which do not combine with that metal. In this oxyd the oxygen is united with very little force to the metal, and can be driven out by a degree of heat only sufficient to make glass red hot; wherefore such bodies as are capable of uniting with oxygen are readily oxygenated, by means of being mixed with red oxyd of mercury, and moderately heated. The same effect may be, to a certain degree, produced by means of the black oxyd of manganese, the red oxyd of lead,[Pg 188] the oxyds of silver, and by most of the metallic oxyds, if we only take care to choose such as have less affinity with oxygen than the bodies they are meant to oxygenate. All the metallic reductions and revivifications belong to this class of operations, being nothing more than oxygenations of charcoal, by means of the several metallic oxyds. The charcoal combines with the oxygen and with caloric, and escapes in form of carbonic acid gas, while the metal remains pure and revivified, or deprived of the oxygen which before combined with it in the form of oxyd.

All combustible substances may likewise be oxygenated by means of mixing them with nitrat of potash or of soda, or with oxygenated muriat of potash, and subjecting the mixture to a certain degree of heat; the oxygen, in this case, quits the nitrat or the muriat, and combines with the combustible body. This species of oxygenation requires to be performed with extreme caution, and only with very small quantities; because, as the oxygen enters into the composition of nitrats, and more especially of oxygenated muriats, combined with almost as much caloric as is necessary for converting it into oxygen gas, this immense quantity of caloric becomes suddenly free the instant of the combination of the oxygen with the combustible[Pg 189] body, and produces such violent explosions as are perfectly irresistible.

By the humid way we can oxygenate most combustible bodies, and convert most of the oxyds of the three kingdoms of nature into acids. For this purpose we chiefly employ the nitric acid, which has a very slight hold of oxygen, and quits it readily to a great number of bodies by the assistance of a gentle heat. The oxygenated muriatic acid may be used for several operations of this kind, but not in them all.

I give the name of binary to the combinations of oxygen with the simple substances, because in these only two elements are combined. When three substances are united in one combination I call it ternary, and quaternary when the combination consists of four substances united.[Pg 190]

Table of the combinations of Oxygen with the compound radicals.

[Note A: These radicals by a first degree of oxygenation form vegetable oxyds, as sugar, starch, mucus, &c.—A.]

[Note B: These radicals by a first degree of oxygenation form the animal oxyds, as lymph, red part of the blood, animal secretions, &c.—A.][Pg 191]

Sect. V.—Observations upon the Combinations of Oxygen with the Compound Radicals.

I published a new theory of the nature and formation of acids in the Memoirs of the Academy for 1776, p. 671. and 1778, p. 535. in which I concluded, that the number of acids must be greatly larger than was till then supposed. Since that time, a new field of inquiry has been opened to chemists; and, instead of five or six acids which were then known, near thirty new acids have been discovered, by which means the number of known neutral salts have been increased in the same proportion. The nature of the acidifiable bases, or radicals of the acids, and the degrees of oxygenation they are susceptible of, still remain to be inquired into. I have already shown, that almost all the oxydable and acidifiable radicals from the mineral kingdom are simple, and that, on the contrary, there hardly exists any radical in the vegetable, and more especially in the animal kingdom, but is composed of at least two substances, hydrogen and charcoal, and that azote and phosphorus are frequently united to these, by which we have compound radicals of two, three, and four bases or simple elements united.[Pg 192]

From these observations, it appears that the vegetable and animal oxyds and acids may differ from each other in three several ways: 1st, According to the number of simple acidifiable elements of which their radicals are composed: 2dly, According to the proportions in which these are combined together: And, 3dly, According to their different degrees of oxygenation: Which circumstances are more than sufficient to explain the great variety which nature produces in these substances. It is not at all surprising, after this, that most of the vegetable acids are convertible into each other, nothing more being requisite than to change the proportions of the hydrogen and charcoal in their composition, and to oxygenate them in a greater or lesser degree. This has been done by Mr Crell in some very ingenious experiments, which have been verified and extended by Mr Hassenfratz. From these it appears, that charcoal and hydrogen, by a first oxygenation, produce tartarous acid, oxalic acid by a second degree, and acetous or acetic acid by a third, or higher oxygenation; only, that charcoal seems to exist in a rather smaller proportion in the acetous and acetic acids. The citric and malic acids differ little from the preceding acids.

Ought we then to conclude that the oils are the radicals of the vegetable and animal acids? I have already expressed my doubts upon this[Pg 193] subject: 1st, Although the oils appear to be formed of nothing but hydrogen and charcoal, we do not know if these are in the precise proportion necessary for constituting the radicals of the acids: 2dly, Since oxygen enters into the composition of these acids equally with hydrogen and charcoal, there is no more reason for supposing them to be composed of oil rather than of water or of carbonic acid. It is true that they contain the materials necessary for all these combinations, but then these do not take place in the common temperature of the atmosphere; all the three elements remain combined in a state of equilibrium, which is readily destroyed by a temperature only a little above that of boiling water[39].

[Pg 194]

Table of the Binary Combinations of Azote with the Simple Substances.

[Pg 195]

Sect. VI.—Observations upon the Combinations of Azote with the Simple Substances.

Azote is one of the most abundant elements; combined with caloric it forms azotic gas, or mephitis, which composes nearly two thirds of the atmosphere. This element is always in the state of gas in the ordinary pressure and temperature, and no degree of compression or of cold has been hitherto capable of reducing it either to a solid or liquid form. This is likewise one of the essential constituent elements of animal bodies, in which it is combined with charcoal and hydrogen, and sometimes with phosphorus; these are united together by a certain portion of oxygen, by which they are formed into oxyds or acids according to the degree of oxygenation. Hence the animal substances may be varied, in the same way with vegetables, in three different manners: 1st, According to the number of elements which enter into the composition of the base or radical: 2dly, According to the proportions of these elements: 3dly, According to the degree of oxygenation.

When combined with oxygen, azote forms the nitrous and nitric oxyds and acids; when with hydrogen, ammoniac is produced. Its combinations with the other simple elements[Pg 196] are very little known; to these we give the name of Azurets, preserving the termination in uret for all nonoxygenated compounds. It is extremely probable that all the alkaline substances may hereafter be found to belong to this genus of azurets.

The azotic gas may be procured from atmospheric air, by absorbing the oxygen gas which is mixed with it by means of a solution of sulphuret of potash, or sulphuret of lime. It requires twelve or fifteen days to complete this process, during which time the surface in contact must be frequently renewed by agitation, and by breaking the pellicle which forms on the top of the solution. It may likewise be procured by dissolving animal substances in dilute nitric acid very little heated. In this operation, the azote is disengaged in form of gas, which we receive under bell glasses filled with water in the pneumato-chemical apparatus. We may procure this gas by deflagrating nitre with charcoal, or any other combustible substance; when with charcoal, the azotic gas is mixed with carbonic acid gas, which may be absorbed by a solution of caustic alkali, or by lime water, after which the azotic gas remains pure. We can procure it in a fourth manner from combinations of ammoniac with metallic oxyds, as pointed out by Mr de Fourcroy: The hydrogen of the ammoniac combines with the oxygen of the[Pg 197] oxyd, and forms water, whilst the azote being left free escapes in form of gas.

The combinations of azote were but lately discovered: Mr Cavendish first observed it in nitrous gas and acid, and Mr Berthollet in ammoniac and the prussic acid. As no evidence of its decomposition has hitherto appeared, we are fully entitled to consider azote as a simple elementary substance.[Pg 198]

Table of the Binary Combinations of Hydrogen with Simple Substances.

[Note A: These combinations take place in the state of gas, and form, respectively, sulphurated and phosphorated oxygen gas—A.]

[Note B: This combination of hydrogen with charcoal includes the fixed and volatile oils, and forms the radicals of a considerable part of the vegetable and animal oxyds and acids. When it takes place in the state of gas it forms carbonated hydrogen gas.—A.]

[Note C: None of these combinations are known, and it is probable that they cannot exist, at least in the usual temperature of the atmosphere, owing to the great affinity of hydrogen for caloric.—A.][Pg 199]

Sect. VII.—Observations upon Hydrogen, and its Combinations with Simple Substances.

Hydrogen, as its name expresses, is one of the constituent elements of water, of which it forms fifteen hundredth parts by weight, combined with eighty-five hundredth parts of oxygen. This substance, the properties and even existence of which was unknown till lately, is very plentifully distributed in nature, and acts a very considerable part in the processes of the animal and vegetable kingdoms. As it possesses so great affinity with caloric as only to exist in the state of gas, it is consequently impossible to procure it in the concrete or liquid state, independent of combination.

To procure hydrogen, or rather hydrogen gas, we have only to subject water to the action of a substance with which oxygen has greater affinity than it has to hydrogen; by this means the hydrogen is set free, and, by uniting with caloric, assumes the form of hydrogen gas. Red hot iron is usually employed for this purpose: The iron, during the process, becomes oxydated, and is changed into a substance resembling the iron ore from the island of Elba. In this state of oxyd it is much less attractible by[Pg 200] the magnet, and dissolves in acids without effervescence.

Charcoal, in a red heat, has the same power of decomposing water, by attracting the oxygen from its combination with hydrogen. In this process carbonic acid gas is formed, and mixes with the hydrogen gas, but is easily separated by means of water or alkalies, which absorb the carbonic acid, and leave the hydrogen gas pure. We may likewise obtain hydrogen gas by dissolving iron or zinc in dilute sulphuric acid. These two metals decompose water very slowly, and with great difficulty, when alone, but do it with great ease and rapidity when assisted by sulphuric acid; the hydrogen unites with caloric during the process, and is disengaged in form of hydrogen gas, while the oxygen of the water unites with the metal in the form of oxyd, which is immediately dissolved in the acid, forming a sulphat of iron or of zinc.

Some very distinguished chemists consider hydrogen as the phlogiston of Stahl; and as that celebrated chemist admitted the existence of phlogiston in sulphur, charcoal, metals, &c. they are of course obliged to suppose that hydrogen exists in all these substances, though they cannot prove their supposition; even if they could, it would not avail much, since this disengagement of hydrogen is quite insufficient to explain the phenomena of calcination and combustion.[Pg 201] We must always recur to the examination of this question, "Are the heat and light, which are disengaged during the different species of combustion, furnished by the burning body, or by the oxygen which combines in all these operations?" And certainly the supposition of hydrogen being disengaged throws no light whatever upon this question. Besides, it belongs to those who make suppositions to prove them; and, doubtless, a doctrine which without any supposition explains the phenomena as well, and as naturally, as theirs does by supposition, has at least the advantage of greater simplicity[40].

[Pg 202]

Table of the Binary Combinations of Sulphur with Simple Substances.

[Pg 203]

Sect. VIII.—Observations on Sulphur, and its Combinations.

Sulphur is a combustible substance, having a very great tendency to combination; it is naturally in a solid state in the ordinary temperature, and requires a heat somewhat higher than boiling water to make it liquify. Sulphur is formed by nature in a considerable degree of purity in the neighbourhood of volcanos; we find it likewise, chiefly in the state of sulphuric acid, combined with argill in aluminous schistus, with lime in gypsum, &c. From these combinations it may be procured in the state of sulphur, by carrying off its oxygen by means of charcoal in a red heat; carbonic acid is formed, and escapes in the state of gas; the sulphur remains combined with the clay, lime, &c. in the state of sulphuret, which is decomposed by acids; the acid unites with the earth into a neutral salt, and the sulphur is precipitated.[Pg 204]

Table of the Binary Combinations of Phosphorus with the Simple Substances.

[Note A: Of all these combinations of phosphorus with metals, that with iron only is hitherto known, forming the substance formerly called Siderite; neither is it yet ascertained whether, in this combination, the phosphorus be oxygenated or not.—A.]

[Note B: These combinations of phosphorus with the alkalies and earths are not yet known; and, from the experiments of Mr Gengembre, they appear to be impossible—A.][Pg 205]

Sect. IX.—Observations upon Phosphorus, and its Combinations.

Phosphorus is a simple combustible substance, which was unknown to chemists till 1667, when it was discovered by Brandt, who kept the process secret; soon after Kunkel found out Brandt's method of preparation, and made it public. It has been ever since known by the name of Kunkel's phosphorus. It was for a long time procured only from urine; and, though Homberg gave an account of the process in the Memoirs of the Academy for 1692, all the philosophers of Europe were supplied with it from England. It was first made in France in 1737, before a committee of the Academy at the Royal Garden. At present it is procured in a more commodious and more oeconomical manner from animal bones, which are real calcareous phosphats, according to the process of Messrs Gahn, Scheele, Rouelle, &c. The bones of adult animals being calcined to whiteness, are pounded, and passed through a fine silk sieve; pour upon the fine powder a quantity of dilute sulphuric acid, less than is sufficient for dissolving the whole. This acid unites with the calcareous earth of the bones into a sulphat of lime, and the phosphoric acid remains free in the liquor. The liquid[Pg 206] is decanted off, and the residuum washed with boiling water; this water which has been used to wash out the adhering acid is joined with what was before decanted off, and the whole is gradually evaporated; the dissolved sulphat of lime cristallizes in form of silky threads, which are removed, and by continuing the evaporation we procure the phosphoric acid under the appearance of a white pellucid glass. When this is powdered, and mixed with one third its weight of charcoal, we procure very pure phosphorus by sublimation. The phosphoric acid, as procured by the above process, is never so pure as that obtained by oxygenating pure phosphorus either by combustion or by means of nitric acid; wherefore this latter should always be employed in experiments of research.

Phosphorus is found in almost all animal substances, and in some plants which give a kind of animal analysis. In all these it is usually combined with charcoal, hydrogen, and azote, forming very compound radicals, which are, for the most part, in the state of oxyds by a first degree of union with oxygen. The discovery of Mr Hassenfratz, of phosphorus being contained in charcoal, gives reason to suspect that it is more common in the vegetable kingdom than has generally been supposed: It is certain, that, by proper processes, it may be procured from every individual of some of the families of plants.[Pg 207]

As no experiment has hitherto given reason to suspect that phosphorus is a compound body, I have arranged it with the simple or elementary substances. It takes fire at the temperature of 32° (104°) of the thermometer.

Table of the Binary Combinations of Charcoal.

[Pg 208]

Sect. X.—Observations upon Charcoal, and its Combinations with Simple Substances.

As charcoal has not been hitherto decomposed, it must, in the present state of our knowledge, be considered as a simple substance. By modern experiments it appears to exist ready formed in vegetables; and I have already remarked, that, in these, it is combined with hydrogen, sometimes with azote and phosphorus, forming compound radicals, which may be changed into oxyds or acids according to their degree of oxygenation.

To obtain the charcoal contained in vegetable or animal substances, we subject them to the action of fire, at first moderate, and afterwards very strong, on purpose to drive off the last portions of water, which adhere very obstinately to the charcoal. For chemical purposes, this is usually done in retorts of stone-ware or porcellain, into which the wood, or other matter, is introduced, and then placed in a reverberatory furnace, raised gradually to its greatest heat: The heat volatilizes, or changes into gas, all the parts of the body susceptible of combining with caloric into that form, and the charcoal, being more fixed in its nature, remains in the retort[Pg 209] combined with a little earth and some fixed salts.

In the business of charring wood, this is done by a less expensive process. The wood is disposed in heaps, and covered with earth, so as to prevent the access of any more air than is absolutely necessary for supporting the fire, which is kept up till all the water and oil is driven off, after which the fire is extinguished by shutting up all the air-holes.

We may analyse charcoal either by combustion in air, or rather in oxygen gas, or by means of nitric acid. In either case we convert it into carbonic acid, and sometimes a little potash and some neutral salts remain. This analysis has hitherto been but little attended to by chemists; and we are not even certain if potash exists in charcoal before combustion, or whether it be formed by means of some unknown combination during that process.

Sect. XI.—Observations upon the Muriatic, Fluoric, and Boracic Radicals, and their Combinations.

As the combinations of these substances, either with each other, or with the other combustible bodies, are hitherto entirely unknown, we have[Pg 210] not attempted to form any table for their nomenclature. We only know that these radicals are susceptible of oxygenation, and of forming the muriatic, fluoric, and boracic acids, and that in the acid state they enter into a number of combinations, to be afterwards detailed. Chemistry has hitherto been unable to disoxygenate any of them, so as to produce them in a simple state. For this purpose, some substance must be employed to which oxygen has a stronger affinity than to their radicals, either by means of single affinity, or by double elective attraction. All that is known relative to the origin of the radicals of these acids will be mentioned in the sections set apart for considering their combinations with the salifiable bases.

Sect. XII.—Observations upon the Combinations of Metals with each other.

Before closing our account of the simple or elementary substances, it might be supposed necessary to give a table of alloys or combinations of metals with each other; but, as such a table would be both exceedingly voluminous and very unsatisfactory, without going into a series of experiments not yet attempted, I have thought it adviseable to omit it altogether. All[Pg 211] that is necessary to be mentioned is, that these alloys should be named according to the metal in largest proportion in the mixture or combination; thus the term alloy of gold and silver, or gold alloyed with silver, indicates that gold is the predominating metal.

Metallic alloys, like all other combinations, have a point of saturation. It would even appear, from the experiments of Mr de la Briche, that they have two perfectly distinct degrees of saturation.[Pg 212]

Table of the Combinations of Azote in the state of Nitrous Acid with the Salifiable Bases, arranged according to the affinities of these Bases with the Acid.

[Pg 213]

Table of the Combinations of Azote, completely saturated with Oxygen, in the state of Nitric Acid, with the Salifiable Bases, in the order of the affinity with the Acid.

[Pg 214]

Sect. XIII.—Observations upon the Nitrous and Nitric Acids, and their Combinations.

The nitrous and nitric acids are procured from a neutral salt long known in the arts under the name of saltpetre. This salt is extracted by lixiviation from the rubbish of old buildings, from the earth of cellars, stables, or barns, and in general of all inhabited places. In these earths the nitric acid is usually combined with lime and magnesia, sometimes with potash, and rarely with argill. As all these salts, excepting the nitrat of potash, attract the moisture of the air, and consequently would be difficultly preserved, advantage is taken, in the manufactures of saltpetre and the royal refining house, of the greater affinity of the nitric acid to potash than these other bases, by which means the lime, magnesia, and argill, are precipitated, and all these nitrats are reduced to the nitrat of potash or saltpetre[41].

The nitric acid is procured from this salt by distillation, from three parts of pure saltpetre decomposed by one part of concentrated sulphuric[Pg 215] acid, in a retort with Woulfe's apparatus, (Pl. IV. fig. 1.) having its bottles half filled with water, and all its joints carefully luted. The nitrous acid passes over in form of red vapours surcharged with nitrous gas, or, in other words, not saturated with oxygen. Part of the acid condenses in the recipient in form of a dark orange red liquid, while the rest combines with the water in the bottles. During the distillation, a large quantity of oxygen gas escapes, owing to the greater affinity of oxygen to caloric, in a high temperature, than to nitrous acid, though in the usual temperature of the atmosphere this affinity is reversed. It is from the disengagement of oxygen that the nitric acid of the neutral salt is in this operation converted into nitrous acid. It is brought back to the state of nitric acid by heating over a gentle fire, which drives off the superabundant nitrous gas, and leaves the nitric acid much diluted with water.

Nitric acid is procurable in a more concentrated state, and with much less loss, by mixing very dry clay with saltpetre. This mixture is put into an earthern retort, and distilled with a strong fire. The clay combines with the potash, for which it has great affinity, and the nitric acid passes over, slightly impregnated with nitrous gas. This is easily disengaged by heating the acid gently in a retort, a small quantity[Pg 216] of nitrous gas passes over into the recipient, and very pure concentrated nitric acid remains in the retort.

We have already seen that azote is the nitric radical. If to 20-1/2 parts, by weight, of azote 43-1/2 parts of oxygen be added, 64 parts of nitrous gas are formed; and, if to this we join 36 additional parts of oxygen, 100 parts of nitric acid result from the combination. Intermediate quantities of oxygen between these two extremes of oxygenation produce different species of nitrous acid, or, in other words, nitric acid less or more impregnated with nitrous gas. I ascertained the above proportions by means of decomposition; and, though I cannot answer for their absolute accuracy, they cannot be far removed from truth. Mr Cavendish, who first showed by synthetic experiments that azote is the base of nitric acid, gives the proportions of azote a little larger than I have done; but, as it is not improbable that he produced the nitrous acid and not the nitric, that circumstance explains in some degree the difference in the results of our experiments.

As, in all experiments of a philosophical nature, the utmost possible degree of accuracy is required, we must procure the nitric acid for experimental purposes, from nitre which has been previously purified from all foreign matter. If, after distillation, any sulphuric acid is suspected[Pg 217] in the nitric acid, it is easily separated by dropping in a little nitrat of barytes, so long as any precipitation takes place; the sulphuric acid, from its greater affinity, attracts the barytes, and forms with it an insoluble neutral salt, which falls to the bottom. It may be purified in the same manner from muriatic acid, by dropping in a little nitrat of silver so long as any precipitation of muriat of silver is produced. When these two precipitations are finished, distill off about seven-eighths of the acid by a gentle heat, and what comes over is in the most perfect degree of purity.

The nitric acid is one of the most prone to combination, and is at the same time very easily decomposed. Almost all the simple substances, with the exception of gold, silver, and platina, rob it less or more of its oxygen; some of them even decompose it altogether. It was very anciently known, and its combinations have been more studied by chemists than those of any other acid. These combinations were named nitres by Messrs Macquer and Beaumé; but we have changed their names to nitrats and nitrites, according as they are formed by nitric or by nitrous acid, and have added the specific name of each particular base, to distinguish the several combinations from each other.[Pg 218]

Table of the Combinations of Sulphuric Acid with the Salifiable Bases, in the order of affinity.

[Pg 219]

Sect. XIV.—Observations upon Sulphuric Acid and its Combinations.

For a long time this acid was procured by distillation from sulphat of iron, in which sulphuric acid and oxyd of iron are combined, according to the process described by Basil Valentine in the fifteenth century; but, in modern times, it is procured more oeconomically by the combustion of sulphur in proper vessels. Both to facilitate the combustion, and to assist the oxygenation of the sulphur, a little powdered saltpetre, nitrat of potash, is mixed with it; the nitre is decomposed, and gives out its oxygen to the sulphur, which contributes to its conversion into acid. Notwithstanding this addition, the sulphur will only continue to burn in close vessels for a limited time; the combination ceases, because the oxygen is exhausted, and the air of the vessels reduced almost to pure azotic gas, and because the acid itself remains long in the state of vapour, and hinders the progress of combustion.

In the manufactories for making sulphuric acid in the large way, the mixture of nitre and sulphur is burnt in large close built chambers lined with lead, having a little water at the bottom for facilitating the condensation of the vapours.[Pg 220] Afterwards, by distillation in large retorts with a gentle heat, the water passes over, slightly impregnated with acid, and the sulphuric acid remains behind in a concentrated state. It is then pellucid, without any flavour, and nearly double the weight of an equal bulk of water. This process would be greatly facilitated, and the combustion much prolonged, by introducing fresh air into the chambers, by means of several pairs of bellows directed towards the flame of the sulphur, and by allowing the nitrous gas to escape through long serpentine canals, in contact with water, to absorb any sulphuric or sulphurous acid gas it might contain.

By one experiment, Mr Berthollet found that 69 parts of sulphur in combustion, united with 31 parts of oxygen, to form 100 parts of sulphuric acid; and, by another experiment, made in a different manner, he calculates that 100 parts of sulphuric acid consists of 72 parts sulphur, combined with 28 parts of oxygen, all by weight.

This acid, in common with every other, can only dissolve metals when they have been previously oxydated; but most of the metals are capable of decomposing a part of the acid, so as to carry off a sufficient quantity of oxygen, to render themselves soluble in the part of the acid which remains undecomposed. This happens with silver, mercury, iron, and zinc, in boiling[Pg 221] concentrated sulphuric acid; they become first oxydated by decomposing part of the acid, and then dissolve in the other part; but they do not sufficiently disoxygenate the decomposed part of the acid to reconvert it into sulphur; it is only reduced to the state of sulphurous acid, which, being volatilised by the heat, flies off in form of sulphurous acid gas.

Silver, mercury, and all the other metals except iron and zinc, are insoluble in diluted sulphuric acid, because they have not sufficient affinity with oxygen to draw it off from its combination either with the sulphur, the sulphurous acid, or the hydrogen; but iron and zinc, being assisted by the action of the acid, decompose the water, and become oxydated at its expence, without the help of heat.[Pg 222]

Table of the Combinations of the Sulphurous Acid with the Salifiable Bases, in the order of affinity.

Note.—The only one of these salts known to the old chemists was the sulphite of potash, under the name of Stahl's sulphureous salt. So that, before our new nomenclature, these compounds must have been named Stahl's sulphureous salt, having base of fixed vegetable alkali, and so of the rest.

In this Table we have followed Bergman's order of affinity of the sulphuric acid, which is the same in regard to the earths and alkalies, but it is not certain if the order be the same for the metallic oxyds.—A.[Pg 223]

Sect. XV.—Observations upon Sulphurous Acid, and its Combinations.

The sulphurous acid is formed by the union of oxygen with sulphur by a lesser degree of oxygenation than the sulphuric acid. It is procurable either by burning sulphur slowly, or by distilling sulphuric acid from silver, antimony, lead, mercury, or charcoal; by which operation a part of the oxygen quits the acid, and unites to these oxydable bases, and the acid passes over in the sulphurous state of oxygenation. This acid, in the common pressure and temperature of the air, can only exist in form of gas; but it appears, from the experiments of Mr Clouet, that, in a very low temperature, it condenses, and becomes fluid. Water absorbs a great deal more of this gas than of carbonic acid gas, but much less than it does of muriatic acid gas.

That the metals cannot be dissolved in acids without being previously oxydated, or by procuring oxygen, for that purpose, from the acids during solution, is a general and well established fact, which I have perhaps repeated too often. Hence, as sulphurous acid is already deprived of great part of the oxygen necessary for forming the sulphuric acid, it is more disposed[Pg 224] to recover oxygen, than to furnish it to the greatest part of the metals; and, for this reason, it cannot dissolve them, unless previously oxydated by other means. From the same principle it is that the metallic oxyds dissolve without effervescence, and with great facility, in sulphurous acid. This acid, like the muriatic, has even the property of dissolving metallic oxyds surcharged with oxygen, and consequently insoluble in sulphuric acid, and in this way forms true sulphats. Hence we might be led to conclude that there are no metallic sulphites, were it not that the phenomena which accompany the solution of iron, mercury, and some other metals, convince us that these metallic substances are susceptible of two degrees of oxydation, during their solution in acids. Hence the neutral salt in which the metal is least oxydated must be named sulphite, and that in which it is fully oxydated must be called sulphat. It is yet unknown whether this distinction is applicable to any of the metallic sulphats, except those of iron and mercury.[Pg 225]

Table of the Combinations of Phosphorous and Phosphoric Acids, with the Salifiable Bases, in the Order of Affinity.

[Note A: The existence of metallic phosphites supposes that metals are susceptible of solution in phosphoric acid at different degrees of oxygenation, which is not yet ascertained.—A.]

[Note B: All the phosphites were unknown till lately, and consequently have not hitherto received names.—A.]

[Note C: The greater part of the phosphats were only discovered of late, and have not yet been named.—A.][Pg 226]

Sect. XVI.—Observations upon Phosphorous and Phosphoric Acids, and their Combinations.

Under the article Phosphorus, Part II. Sect. X. we have already given a history of the discovery of that singular substance, with some observations upon the mode of its existence in vegetable and animal bodies. The best method of obtaining this acid in a state of purity is by burning well purified phosphorus under bell-glasses, moistened on the inside with distilled water; during combustion it absorbs twice and a half its weight of oxygen; so that 100 parts of phosphoric acid is composed of 28-1/2 parts of phosphorus united to 71-1/2 parts of oxygen. This acid may be obtained concrete, in form of white flakes, which greedily attract the moisture of the air, by burning phosphorus in a dry glass over mercury.

To obtain phosphorous acid, which is phosphorus less oxygenated than in the state of phosphoric acid, the phosphorus must be burnt by a very slow spontaneous combustion over a glass-funnel leading into a crystal phial; after a few days, the phosphorus is found oxygenated, and the phosphorous acid, in proportion as it forms, has attracted moisture from the air, and dropped into the phial. The phosphorous[Pg 227] acid is readily changed into phosphoric acid by exposure for a long time to the free air; it absorbs oxygen from the air, and becomes fully oxygenated.

As phosphorus has a sufficient affinity for oxygen to attract it from the nitric and muriatic acids, we may form phosphoric acid, by means of these acids, in a very simple and cheap manner. Fill a tubulated receiver, half full of concentrated nitric acid, and heat it gently, then throw in small pieces of phosphorus through the tube, these are dissolved with effervescence and red fumes of nitrous gas fly off; add phosphorus so long as it will dissolve, and then increase the fire under the retort to drive off the last particles of nitric acid; phosphoric acid, partly fluid and partly concrete, remains in the retort.[Pg 228]

Table of the Combinations of Carbonic Acid, with the Salifiable Bases, in the Order of Affinity.

[Note A: As these salts have only been understood of late, they have not, properly speaking, any old names. Mr Morveau, in the First Volume of the Encyclopedia, calls them Mephites; Mr Bergman gives them the name of aërated; and Mr de Fourcroy, who calls the carbonic acid chalky acid, gives them the name of chalks.—A][Pg 229]

Sect. XVII.—Observations upon Carbonic Acid, and its Combinations.

Of all the known acids, the carbonic is the most abundant in nature; it exists ready formed in chalk, marble, and all the calcareous stones, in which it is neutralized by a particular earth called lime. To disengage it from this combination, nothing more is requisite than to add some sulphuric acid, or any other which has a stronger affinity for lime; a brisk effervescence ensues, which is produced by the disengagement of the carbonic acid which assumes the state of gas immediately upon being set free. This gas, incapable of being condensed into the solid or liquid form by any degree of cold or of pressure hitherto known, unites to about its own bulk of water, and thereby forms a very weak acid. It may likewise be obtained in great abundance from saccharine matter in fermentation, but is then contaminated by a small portion of alkohol which it holds in solution.

As charcoal is the radical of this acid, we may form it artificially, by burning charcoal in oxygen gas, or by combining charcoal and metallic oxyds in proper proportions; the oxygen of the oxyd combines with the charcoal, forming[Pg 230] carbonic acid gas, and the metal being left free, recovers its metallic or reguline form.

We are indebted for our first knowledge of this acid to Dr Black, before whose time its property of remaining always in the state of gas had made it to elude the researches of chemistry.

It would be a most valuable discovery to society, if we could decompose this gas by any cheap process, as by that means we might obtain, for economical purposes, the immense store of charcoal contained in calcareous earths, marbles, limestones, &c. This cannot be effected by single affinity, because, to decompose the carbonic acid, it requires a substance as combustible as charcoal itself, so that we should only make an exchange of one combustible body for another not more valuable; but it may possibly be accomplished by double affinity, since this process is so readily performed by Nature, during vegetation, from the most common materials.[Pg 231]

Table of the Combinations of Muriatic Acid, with the Salifiable Bases, in the Order of Affinity.

[Pg 232]

Table Of the Combinations of Oxygenated Muriatic Acid, with the Salifiable Bases, in the Order of Affinity.

This order of salts, entirely unknown to the ancient chemists, was discovered in 1786 by Mr Berthollet.—A.[Pg 233]

Sect. XIX.—Observations upon Muriatic and Oxygenated Muriatic Acids, and their Combinations.

Muriatic acid is very abundant in the mineral kingdom naturally combined with different salifiable bases, especially with soda, lime, and magnesia. In sea-water, and the water of several lakes, it is combined with these three bases, and in mines of rock-salt it is chiefly united to soda. This acid does not appear to have been hitherto decomposed in any chemical experiment; so that we have no idea whatever of the nature of its radical, and only conclude, from analogy with the other acids, that it contains oxygen as its acidifying principle. Mr Berthollet suspects the radical to be of a metallic nature; but, as Nature appears to form this acid daily, in inhabited places, by combining miasmata with aëriform fluids, this must necessarily suppose a metallic gas to exist in the atmosphere, which is certainly not impossible, but cannot be admitted without proof.

The muriatic acid has only a moderate adherence to the salifiable bases, and can readily be driven from its combination with these by sulphuric acid. Other acids, as the nitric, for instance, may answer the same purpose; but nitric acid being volatile, would mix, during distillation,[Pg 234] with the muriatic. About one part of sulphuric acid is sufficient to decompose two parts of decrepitated sea-salt. This operation is performed in a tubulated retort, having Woulfe's apparatus, (Pl. IV. Fig. 1.), adapted to it. When all the junctures are properly lured, the sea-salt is put into the retort through the tube, the sulphuric acid is poured on, and the opening immediately closed with its ground crystal stopper. As the muriatic acid can only subsist in the gaseous form in the ordinary temperature, we could not condense it without the presence of water. Hence the use of the water with which the bottles in Woulfe's apparatus are half filled; the muriatic acid gas, driven off from the sea-salt in the retort, combines with the water, and forms what the old chemists called smoaking spirit of salt, or Glauber's spirit of sea-salt, which we now name muriatic acid.

The acid obtained by the above process is still capable of combining with a farther dose of oxygen, by being distilled from the oxyds of manganese, lead, or mercury, and the resulting acid, which we name oxygenated muriatic acid, can only, like the former, exist in the gasseous form, and is absorbed, in a much smaller quantity by water. When the impregnation of water with this gas is pushed beyond a certain point, the superabundant acid precipitates to the bottom of the vessels in a concrete form. Mr Berthollet has[Pg 235] shown that this acid is capable of combining with a great number of the salifiable bases; the neutral salts which result from this union are susceptible of deflagrating with charcoal, and many of the metallic substances; these deflagrations are very violent and dangerous, owing to the great quantity of caloric which the oxygen carries alongst with it into the composition of oxygenated muriatic acid.[Pg 236]

Table of the Combinations of Nitro-muriatic Acid with the Salifiable Bases, in the Order of Affinity, so far as is known.

Note.—Most of these combinations, especially those with the earths and alkalies, have been little examined, and we are yet to learn whether they form a mixed salt in which the compound radical remains combined, or if the two acids separate, to form two distinct neutral salts.—A.[Pg 237]

Sect. XX.—Observations upon the Nitro-Muriatic Acid, and its Combinations.

The nitro-muriatic acid, formerly called aqua regia, is formed by a mixture of nitric and muriatic acids; the radicals of these two acids combine together, and form a compound base, from which an acid is produced, having properties peculiar to itself, and distinct from those of all other acids, especially the property of dissolving gold and platina.

In dissolutions of metals in this acid, as in all other acids, the metals are first oxydated by attracting a part of the oxygen from the compound radical. This occasions a disengagement of a particular species of gas not hitherto described, which may be called nitro-muriatic gas; it has a very disagreeable smell, and is fatal to animal life when respired; it attacks iron, and causes it to rust; it is absorbed in considerable quantity by water, which thereby acquires some slight characters of acidity. I had occasion to make these remarks during a course of experiments upon platina, in which I dissolved a considerable quantity of that metal in nitro-muriatic acid.

I at first suspected that, in the mixture of nitric and muriatic acids, the latter attracted a[Pg 238] part of the oxygen from the former, and became converted into oxygenated muriatic acid, which gave it the property of dissolving gold; but several facts remain inexplicable upon this supposition. Were it so, we must be able to disengage nitrous gas by heating this acid, which however does not sensibly happen. From these considerations, I am led to adopt the opinion of Mr Berthollet, and to consider nitro-muriatic acid as a single acid, with a compound base or radical.[Pg 239]

Table of the Combinations of Fluoric Acid, with the Salifiable Bases, in the Order of Affinity.

Note.—These combinations were entirely unknown to the old chemists, and consequently have no names in the old nomenclature.—A.[Pg 240]

Sect. XXI.—Observations upon the Fluoric Acid, and its Combinations.

Fluoric exists ready formed by Nature in the fluoric spars[42], combined with calcareous earth, so as to form an insoluble neutral salt. To obtain it disengaged from that combination, fluor spar, or fluat of lime, is put into a leaden retort, with a proper quantity of sulphuric acid, a recipient likewise of lead, half full of water, is adapted, and fire is applied to the retort. The sulphuric acid, from its greater affinity, expels the fluoric acid which passes over and is absorbed by the water in the receiver. As fluoric acid is naturally in the gasseous form in the ordinary temperature, we can receive it in a pneumato-chemical apparatus over mercury. We are obliged to employ metallic vessels in this process, because fluoric acid dissolves glass and silicious earth, and even renders these bodies volatile, carrying them over with itself in distillation in the gasseous form.

We are indebted to Mr Margraff for our first acquaintance with this acid, though, as he could never procure it free from combination with a considerable quantity of silicious earth, he was[Pg 241] ignorant of its being an acid sui generis. The Duke de Liancourt, under the name of Mr Boulanger, considerably increased our knowledge of its properties; and Mr Scheele seems to have exhausted the subject. The only thing remaining is to endeavour to discover the nature of the fluoric radical, of which we cannot hitherto form any ideas, as the acid does not appear to have been decomposed in any experiment. It is only by means of compound affinity that experiments ought to be made with this view, with any probability of success.[Pg 242]

Table of the Combinations of Boracic Acid, with the Salifiable Bases, in the Order of Affinity.

Note.—Most of these combinations were neither known nor named by the old chemists. The boracic acid was formerly called sedative salt, and its compounds borax, with base of fixed vegetable alkali, &c.—A.[Pg 243]

Sect. XXII.—Observations upon Boracic Add and its Combinations.

This is a concrete acid, extracted from a salt procured from India called borax or tincall. Although borax has been very long employed in the arts, we have as yet very imperfect knowledge of its origin, and of the methods by which it is extracted and purified; there is reason to believe it to be a native salt, found in the earth in certain parts of the east, and in the water of some lakes. The whole trade of borax is in the hands of the Dutch, who have been exclusively possessed of the art of purifying it till very lately, that Messrs L'Eguillier of Paris have rivalled them in the manufacture; but the process still remains a secret to the world.

By chemical analysis we learn that borax is a neutral salt with excess of base, consisting of soda, partly saturated with a peculiar acid long called Homberg's sedative salt, now the boracic acid. This acid is found in an uncombined state in the waters of certain lakes. That of Cherchiais in Italy contains 94-1/2 grains in each pint of water.

To obtain boracic acid, dissolve some borax in boiling water, filtrate the solution, and add sulphuric acid, or any other having greater affinity[Pg 244] to soda than the boracic acid; this latter acid is separated, and is procured in a crystalline form by cooling. This acid was long considered as being formed during the process by which it is obtained, and was consequently supposed to differ according to the nature of the acid employed in separating it from the soda; but it is now universally acknowledged that it is identically the same acid, in whatever way procured, provided it be properly purified from mixture of other acids, by warning, and by repeated solution and cristallization. It is soluble both in water and alkohol, and has the property of communicating a green colour to the flame of that spirit. This circumstance led to a suspicion of its containing copper, which is not confirmed by any decisive experiment. On the contrary, if it contain any of that metal, it must only be considered as an accidental mixture. It combines with the salifiable bases in the humid way; and though, in this manner, it is incapable of dissolving any of the metals directly, this combination is readily affected by compound affinity.

The Table presents its combinations in the order of affinity in the humid way; but there is a considerable change in the order when we operate via sicca; for, in that case, argill, though the last in our list, must be placed immediately after soda.[Pg 245]

The boracic radical is hitherto unknown; no experiments having as yet been able to decompose the acid; We conclude, from analogy with the other acids, that oxygen exists in its composition as the acidifying principle.[Pg 246]

Table of the Combinations of Arseniac Acid, with the Salifiable Bases, in the Order of Affinity.

Note.—This order of salts was entirely unknown to the antient chemists. Mr Macquer, in 1746, discovered the combinations of arseniac acid with potash and soda, to which he gave the name of arsenical neutral salts.—A.[Pg 247]

Sect. XXIII.—Observations upon Arseniac Acid, and its Combinations.

In the Collections of the Academy for 1746, Mr Macquer shows that, when a mixture of white oxyd of arsenic and nitre are subjected to the action of a strong fire, a neutral salt is obtained, which he calls neutral salt of arsenic. At that time, the cause of this singular phenomenon, in which a metal acts the part of an acid, was quite unknown; but more modern experiments teach that, during this process, the arsenic becomes oxygenated, by carrying off the oxygen of the nitric acid; it is thus converted into a real acid, and combines with the potash. There are other methods now known for oxygenating arsenic, and obtaining its acid free from combination. The most simple and most effectual of these is as follows: Dissolve white oxyd of arsenic in three parts, by weight, of muriatic acid; to this solution, in a boiling state, add two parts of nitric acid, and evaporate to dryness. In this process the nitric acid is decomposed, its oxygen unites with the oxyd of arsenic, and converts it into an acid, and the nitrous radical flies off in the state of nitrous gas; whilst the muriatic acid is converted by the heat into muriatic acid gas, and may be collected in proper vessels. The arseniac acid is entirely[Pg 248] freed from the other acids employed during the process by heating it in a crucible till it begins to grow red; what remains is pure concrete arseniac acid.

Mr Scheele's process, which was repeated with great success by Mr Morveau, in the laboratory at Dijon, is as follows: Distil muriatic acid from the black oxyd of manganese, this converts it into oxygenated muriatic acid, by carrying off the oxygen from the manganese, receive this in a recipient containing white oxyd of arsenic, covered by a little distilled water; the arsenic decomposes the oxygenated muriatic acid, by carrying off its supersaturation of oxygen, the arsenic is converted into arseniac acid, and the oxygenated muriatic acid is brought back to the state of common muriatic acid. The two acids are separated by distillation, with a gentle heat increased towards the end of the operation, the muriatic acid passes over, and the arseniac acid remains behind in a white concrete form.

The arseniac acid is considerably less volatile than white oxyd of arsenic; it often contains white oxyd of arsenic in solution, owing to its not being sufficiently oxygenated; this is prevented by continuing to add nitrous acid, as in the former process, till no more nitrous gas is produced. From all these observations I would give the following definition of[Pg 249] arseniac acid. It is a white concrete metallic acid, formed by the combination of arsenic with oxygen, fixed in a red heat, soluble in water, and capable of combining with many of the salifiable bases.

Sect. XXIV.—Observations upon Molybdic Acid, and its Combinations with Acidifiable Bases[43].

Molybdena is a particular metallic body, capable of being oxygenated, so far as to become a true concrete acid[44]. For this purpose, one part ore of molybdena, which is a natural sulphuret of that metal, is put into a retort, with five or six parts nitric acid, diluted with a quarter of its weight of water, and heat is applied to the retort; the oxygen of the nitric acid acts both upon the molybdena and the sulphur, converting the one into molybdic, and the other into sulphuric acid; pour on fresh quantities of nitric acid so long as any red fumes of nitrous[Pg 250] gas escape; the molydbena is then oxygenated as far as is possible, and is found at the bottom of the retort in a pulverulent form, resembling chalk. It must be washed in warm water, to separate any adhering particles of sulphuric acid; and, as it is hardly soluble, we lose very little of it in this operation. All its combinations with salifiable bases were unknown to the ancient chemists.

[Pg 251]

Table of the Combinations of Tungstic Acid with the Salifiable Bases.

[Note A: The combinations with metallic oxyds were set down by Mr Lavoisier in alphabetical order; their order of affinity being unknown, I have omitted them, as serving no purpose.—E.]

[Note B: All these salts were unknown to the ancient chemists.—A.]

Sect. XXV.—Observations upon Tungstic Acid, and its Combinations.

Tungstein is a particular metal, the ore of which has frequently been confounded with that of tin. The specific gravity of this ore is to water as 6 to 1; in its form of cristallization it resembles[Pg 252] the garnet, and varies in colour from a pearl-white to yellow and reddish; it is found in several parts of Saxony and Bohemia. The mineral called Wolfram, which is frequent in the mines of Cornwal, is likewise an ore of this metal. In all these ores the metal is oxydated; and, in some of them, it appears even to be oxygenated to the state of acid, being combined with lime into a true tungstat of lime.

To obtain the acid free, mix one part of ore of tungstein with four parts of carbonat of potash, and melt the mixture in a crucible, then powder and pour on twelve parts of boiling water, add nitric acid, and the tungstic acid precipitates in a concrete form. Afterwards, to insure the complete oxygenation of the metal, add more nitric acid, and evaporate to dryness, repeating this operation so long as red fumes of nitrous gas are produced. To procure tungstic acid perfectly pure, the fusion of the ore with carbonat of potash must be made in a crucible of platina, otherwise the earth of the common crucibles will mix with the products, and adulterate the acid.[Pg 253]

Table of the Combinations of Tartarous Acid, with the Salifiable Bases, in the Order of Affinity.

[Pg 254]

Sect. XXVI.—Observations upon Tartarous Acid, and its Combinations.

Tartar, or the concretion which fixes to the inside of vessels in which the fermentation of wine is completed, is a well known salt, composed of a peculiar acid, united in considerable excess to potash. Mr Scheele first pointed out the method of obtaining this acid pure. Having observed that it has a greater affinity to lime than to potash, he directs us to proceed in the following manner. Dissolve purified tartar in boiling water, and add a sufficient quantity of lime till the acid be completely saturated. The tartarite of lime which is formed, being almost insoluble in cold water, falls to the bottom, and is separated from the solution of potash by decantation; it is afterwards washed in cold water, and dried; then pour on some sulphuric acid, diluted with eight or nine parts of water, digest for twelve hours in a gentle heat, frequently stirring the mixture; the sulphuric acid combines with the lime, and the tartarous acid is left free. A small quantity of gas, not hitherto examined, is disengaged during this process. At the end of twelve hours, having decanted off the clear liquor, wash the sulphat of lime in cold water, which add to the decanted[Pg 255] liquor, then evaporate the whole, and the tartarous acid is obtained in a concrete form. Two pounds of purified tartar, by means of from eight to ten ounces of sulphuric acid, yield about eleven ounces of tartarous acid.

As the combustible radical exists in excess, or as the acid from tartar is not fully saturated with oxygen, we call it tartarous acid, and the neutral salts formed by its combinations with salifiable bases tartarites. The base of the tartarous acid is a carbono-hydrous or hydro-carbonous radical, less oxygenated than in the oxalic acid; and it would appear, from the experiments of Mr Hassenfratz, that azote enters into the composition of the tartarous radical, even in considerable quantity. By oxygenating the tartarous acid, it is convertible into oxalic, malic, and acetous acids; but it is probable the proportions of hydrogen and charcoal in the radical are changed during these conversions, and that the difference between these acids does not alone consist in the different degrees of oxygenation.

The tartarous acid is susceptible of two degrees of saturation in its combinations with the fixed alkalies; by one of these a salt is formed with excess of acid, improperly called cream of tartar, which in our new nomenclature is named acidulous tartarite of potash; by a second or equal degree of saturation a perfectly neutral salt is formed, formerly called vegetable salt,[Pg 256] which we name tartarite of potash. With soda this acid forms tartarite of soda, formerly called sal de Seignette, or sal polychrest of Rochell.

Sect. XXVII.—Observations upon Malic Acid, and its Combinations with the Salifiable Bases[45].

The malic acid exists ready formed in the sour juice of ripe and unripe apples, and many other fruits, and is obtained as follows: Saturate the juice of apples with potash or soda, and add a proper proportion of acetite of lead dissolved in water; a double decomposition takes place, the malic acid combines with the oxyd of lead and precipitates, being almost insoluble, and the acetite of potash or soda remains in the liquor. The malat of lead being separated by decantation, is washed with cold water, and some dilute sulphuric acid is added; this unites with the lead into an insoluble sulphat, and the malic acid remains free in the liquor.

This acid, which is found mixed with citric and tartarous acid in a great number of fruits, is a kind of medium between oxalic and acetous[Pg 257] acids being more oxygenated than the former, and less so than the latter. From this circumstance, Mr Hermbstadt calls it imperfect vinegar; but it differs likewise from acetous acid, by having rather more charcoal, and less hydrogen, in the composition of its radical.

When an acid much diluted has been used in the foregoing process, the liquor contains oxalic as well as malic acid, and probably a little tartarous, these are separated by mixing lime-water with the acids, oxalat, tartarite, and malat of lime are produced; the two former, being insoluble, are precipitated, and the malat of lime remains dissolved; from this the pure malic acid is separated by the acetite of lead, and afterwards by sulphuric acid, as directed above.[Pg 258]

Table of the Combinations of Citric Acid, with the Salifiable Bases, in the Order of Affinity(A).

[Note A: These combinations were unknown to the ancient chemists. The order of affinity of the salifiable bases with this acid was determined by Mr Bergman and by Mr de Breney of the Dijon Academy.—A.][Pg 259]

Sect. XXVIII.—Observations upon Citric Acid, and its Combinations.

The citric acid is procured by expression from lemons, and is found in the juices of many other fruits mixed with malic acid. To obtain it pure and concentrated, it is first allowed to depurate from the mucous part of the fruit by long rest in a cool cellar, and is afterwards concentrated by exposing it to the temperature of 4 or 5 degrees below Zero, from 21° to 23° of Fahrenheit, the water is frozen, and the acid remains liquid, reduced to about an eighth part of its original bulk. A lower degree of cold would occasion the acid to be engaged amongst the ice, and render it difficultly separable. This process was pointed out by Mr Georgius.

It is more easily obtained by saturating the lemon-juice with lime, so as to form a citrat of lime, which is insoluble in water; wash this salt, and pour on a proper quantity of sulphuric acid; this forms a sulphat of lime, which precipitates and leaves the citric acid free in the liquor.[Pg 260]

Table of the Combinations of Pyro-lignous Acid with the Salifiable Bases, in the Order of Affinity(A).

[Note A: The above affinities were determined by Messrs de Morveau and EloI Boursier de Clervaux. These combinations were entirely unknown till lately.—A.][Pg 261]

Sect. XXIX.—Observations upon Pyro-lignous Acid, and its Combinations.

The ancient chemists observed that most of the woods, especially the more heavy and compact ones, gave out a particular acid spirit, by distillation, in a naked fire; but, before Mr Goetling, who gives an account of his experiments upon this subject in Crell's Chemical Journal for 1779, no one had ever made any inquiry into its nature and properties. This acid appears to be the same, whatever be the wood it is procured from. When first distilled, it is of a brown colour, and considerably impregnated with charcoal and oil; it is purified from these by a second distillation. The pyro-lignous radical is chiefly composed of hydrogen and charcoal.

Sect. XXX.—Observations upon Pyro-tartarous Acid, and its Combinations with the Salifiable Bases[46].

The name of Pyro-tartarous acid is given to a dilute empyreumatic acid obtained from purified[Pg 262] acidulous tartarite of potash by distillation in a naked fire. To obtain it, let a retort be half filled with powdered tartar, adapt a tubulated recipient, having a bent tube communicating with a bell-glass in a pneumato-chemical apparatus; by gradually raising the fire under the retort, we obtain the pyro-tartarous acid mixed with oil, which is separated by means of a funnel. A vast quantity of carbonic acid gas is disengaged during the distillation. The acid obtained by the above process is much contaminated with oil, which ought to be separated from it. Some authors advise to do this by a second distillation; but the Dijon academicians inform us, that this is attended with great danger from explosions which take place during the process.[Pg 263]

Table of the Combinations of Pyro-mucous Acid, with the Salifiable Bases, in the Order of Affinity(A).

[Note A: All these combinations were unknown to the ancient chemists.—A.][Pg 264]

Sect. XXXI.—Observations upon Pyro-mucous Acid, and its Combinations.

This acid is obtained by distillation in a naked fire from sugar, and all the saccharine bodies; and, as these substances swell greatly in the fire, it is necessary to leave seven-eighths of the retort empty. It is of a yellow colour, verging to red, and leaves a mark upon the skin, which will not remove but alongst with the epidermis. It may be procured less coloured, by means of a second distillation, and is concentrated by freezing, as is directed for the citric acid. It is chiefly composed of water and oil slightly oxygenated, and is convertible into oxalic and malic acids by farther oxygenation with the nitric acid.

It has been pretended that a large quantity of gas is disengaged during the distillation of this acid, which is not the case if it be conducted slowly, by means of moderate heat.[Pg 265]

Table of the Combinations of the Oxalic Acid, with the Salifiable Bases, in the Order of Affinity(A).

[Note A: All unknown to the ancient chemists.—A.][Pg 266]

Sect. XXXII.—Observations upon Oxalic Acid, and its Combinations.

The oxalic acid is mostly prepared in Switzerland and Germany from the expressed juice of sorrel, from which it cristallizes by being left long at rest; in this state it is partly saturated with potash, forming a true acidulous oxalat of potash, or salt with excess of acid. To obtain it pure, it must be formed artificially by oxygenating sugar, which seems to be the true oxalic radical. Upon one part of sugar pour six or eight parts of nitric acid, and apply a gentle heat; a considerable effervescence takes place, and a great quantity of nitrous gas is disengaged; the nitric acid is decomposed, and its oxygen unites to the sugar: By allowing the liquor to stand at rest, cristals of pure oxalic acid are formed, which must be dried upon blotting paper, to separate any remaining portions of nitric acid; and, to ensure the purity of the acid, dissolve the cristals in distilled water, and cristallize them afresh.

[Pg 267]

From the liquor remaining after the first cristallization of the oxalic acid we may obtain malic acid by refrigeration: This acid is more oxygenated than the oxalic; and, by a further oxygenation, the sugar is convertible into acetous acid, or vinegar.

The oxalic acid, combined with a small quantity of soda or potash, has the property, like the tartarous acid, of entering into a number of combinations without suffering decomposition: These combinations form triple salts, or neutral salts with double bases, which ought to have proper names. The salt of sorrel, which is potash having oxalic acid combined in excess, is named acidulous oxalat of potash in our new nomenclature.

The acid procured from sorrel has been known to chemists for more than a century, being mentioned by Mr Duclos in the Memoirs of the Academy for 1688, and was pretty accurately described by Boerhaave; but Mr Scheele first showed that it contained potash, and demonstrated its identity with the acid formed by the oxygenation of sugar.

Sect. XXXIII.—Observations upon Acetous Acid, and its Combinations.

This acid is composed of charcoal and hydrogen united together, and brought to the state of an acid by the addition of oxygen; it is consequently formed by the same elements with[Pg 268] the tartarous oxalic, citric, malic acids, and others, but the elements exist in different proportions in each of these; and it would appear that the acetous acid is in a higher state of oxygenation than these other acids. I have some reason to believe that the acetous radical contains a small portion of azote; and, as this element is not contained in the radicals of any vegetable acid except the tartarous, this circumstance is one of the causes of difference. The acetous acid, or vinegar, is produced by exposing wine to a gentle heat, with the addition of some ferment: This is usually the ley, or mother, which has separated from other vinegar during fermentation, or some similar matter. The spiritous part of the wine, which consists of charcoal and hydrogen, is oxygenated, and converted into vinegar: This operation can only take place with free access of air, and is always attended by a diminution of the air employed in consequence of the absorption of oxygen; wherefore, it ought always to be carried on in vessels only half filled with the vinous liquor submitted to the acetous fermentation. The acid formed during this process is very volatile, is mixed with a large proportion of water, and with many foreign substances; and, to obtain it pure, it is distilled in stone or glass vessels by a gentle fire. The acid which passes over in distillation is somewhat changed by the[Pg 269] process, and is not exactly of the same nature with what remains in the alembic, but seems less oxygenated: This circumstance has not been formerly observed by chemists.

Distillation is not sufficient for depriving this acid of all its unnecessary water; and, for this purpose, the best way is by exposing it to a degree of cold from 4° to 6° below the freezing point, from 19° to 23° of Fahrenheit; by this means the aqueous part becomes frozen, and leaves the acid in a liquid state, and considerably concentrated. In the usual temperature of the air, this acid can only exist in the gasseous form, and can only be retained by combination with a large proportion of water. There are other chemical processes for obtaining the acetous acid, which consist in oxygenating the tartarous, oxalic, or malic acids, by means of nitric acid; but there is reason to believe the proportions of the elements of the radical are changed during this process. Mr Hassenfratz is at present engaged in repeating the experiments by which these conversions are said to be produced.

The combinations of acetous acid with the various salifiable bases are very readily formed; but most of the resulting neutral salts are not cristallizable, whereas those produced by the tartarous and oxalic acids are, in general, hardly soluble. Tartarite and oxalat of lime are[Pg 270] not soluble in any sensible degree: The malats are a medium between the oxalats and acetites, with respect to solubility, and the malic acid is in the middle degree of saturation between the oxalic and acetous acids. With this, as with all the acids, the metals require to be oxydated previous to solution.

The ancient chemists knew hardly any of the salts formed by the combinations of acetous acid with the salifiable bases, except the acetites of potash, soda, ammoniac, copper, and lead. Mr Cadet discovered the acetite of arsenic[47]; Mr Wenzel, the Dijon academicians Mr de Lassone, and Mr Proust, made us acquainted with the properties of the other acetites. From the property which acetite of potash possesses, of giving out ammoniac in distillation, there is some reason to suppose, that, besides charcoal and hydrogen, the acetous radical contains a small proportion of azote, though it is not impossible but the above production of ammoniac may be occasioned by the decomposition of the potash.

[Pg 271]

Table of the Combinations of Acetic Acid with the Salifiable Bases, in the order of affinity.

Note.—All these salts were unknown to the ancients; and even those chemists who are most versant in modern discoveries, are yet at a lose whether the greater part of the salts produced by the oxygenated acetic radical belong properly to the class of acetites, or to that of acetats.—A.[Pg 272]

Sect. XXXIV.—Observations upon Acetic Acid, and its Combinations.

We have given to radical vinegar the name of acetic acid, from supposing that it consists of the same radical with that of the acetous acid, but more highly saturated with oxygen. According to this idea, acetic acid is the highest degree of oxygenation of which the hydro-carbonous radical is susceptible; but, although this circumstance be extremely probable, it requires to be confirmed by farther, and more decisive experiments, before it be adopted as an absolute chemical truth. We procure this acid as follows: Upon three parts acetite of potash or of copper, pour one part of concentrated sulphuric acid, and, by distillation, a very highly concentrated vinegar is obtained, which we call acetic acid, formerly named radical vinegar. It is not hitherto rigorously proved that this acid is more highly oxygenated than the acetous acid, nor that the difference between them may not consist in a different proportion between the elements of the radical or base.[Pg 273]

Table of the Combinations of Succinic Acid with the Salifiable Bases, in the order of Affinity.

Note.—All the succinats were unknown to the ancient chemists.—A.[Pg 274]

Sect. XXXV.—Observations upon Succinic Acid, and its Combinations.

The succinic acid is drawn from amber by sublimation in a gentle heat, and rises in a concrete form into the neck of the subliming vessel. The operation must not be pushed too far, or by too strong a fire, otherwise the oil of the amber rises alongst with the acid. The salt is dried upon blotting paper, and purified by repeated solution and crystallization.

This acid is soluble in twenty-four times its weight of cold water, and in a much smaller quantity of hot water. It possesses the qualities of an acid in a very small degree, and only affects the blue vegetable colours very slightly. The affinities of this acid, with the salifiable bases, are taken from Mr de Morveau, who is the first chemist that has endeavoured to ascertain them.[Pg 275]

Sect. XXXVI.—Observations upon Benzoic Acid, and its Combinations with Salifiable Bases[48].

This acid was known to the ancient chemists under the name of Flowers of Benjamin, or of Benzoin, and was procured, by sublimation, from the gum or resin called Benzoin: The means of procuring it, via humida, was discovered by Mr Geoffroy, and perfected by Mr Scheele. Upon benzoin, reduced to powder, pour strong lime-water, having rather an excess of lime; keep the mixture continually stirring, and, after half an hour's digestion, pour off the liquor, and use fresh portions of lime-water in the same manner, so long as there is any appearance of neutralization. Join all the decanted liquors, and evaporate, as far as possible, without occasioning cristallization, and, when the liquor is cold, drop in muriatic acid till no more precipitate is formed. By the former part of the process a benzoat of lime is formed, and, by the latter, the muriatic acid combines with the lime, forming muriat of lime, which remains[Pg 276] dissolved, while the benzoic acid, being insoluble, precipitates in a concrete state.

Sect. XXXVII.—Observations upon Camphoric Acid, and its Combinations with Salifiable Bases[49].

Camphor is a concrete essential oil, obtained, by sublimation, from a species of laurus which grows in China and Japan. By distilling nitric acid eight times from camphor, Mr Kosegarten converted it into an acid analogous to the oxalic; but, as it differs from that acid in some circumstances, we have thought necessary to give it a particular name, till its nature be more completely ascertained by farther experiment.

As camphor is a carbono-hydrous or hydro-carbonous radical, it is easily conceived, that, by oxygenation, it should form oxalic, malic, and several other vegetable acids: This conjecture is rendered not improbable by the experiments of Mr Kosegarten; and the principal phenomena exhibited in the combinations of camphoric acid with the salifiable bases, being[Pg 277] very similar to those of the oxalic and malic acids, lead me to believe that it consists of a mixture of these two acids.

Sect. XXXVIII.—Observations upon Gallic Acid, and its Combinations with Salifiable Bases[50].

The Gallic acid, formerly called Principle of Astringency, is obtained from gall nuts, either by infusion or decoction with water, or by distillation with a very gentle heat. This acid has only been attended to within these few years. The Committee of the Dijon Academy have followed it through all its combinations, and give the best account of it hitherto produced. Its acid properties are very weak; it reddens the tincture of turnsol, decomposes sulphurets, and unites to all the metals when they have been previously dissolved in some other acid. Iron, by this combination, is precipitated of a very deep blue or violet colour. The radical of this acid, if it deserves the name of one, is hitherto entirely unknown; it is contained in[Pg 278] oak willow, marsh iris, the strawberry, nymphea, Peruvian bark, the flowers and bark of pomgranate, and in many other woods and barks.

Sect. XXXIX.—Observations upon Lactic Acid, and its Combinations with Salifiable Bases[51].

The only accurate knowledge we have of this acid is from the works of Mr Scheele. It is contained in whey, united to a small quantity of earth, and is obtained as follows: Reduce whey to one eighth part of its bulk by evaporation, and filtrate, to separate all its cheesy matter; then add as much lime as is necessary to combine with the acid; the lime is afterwards disengaged by the addition of oxalic acid, which combines with it into an insoluble neutral salt. When the oxalat of lime has been separated by decantation, evaporate the remaining liquor to the consistence of honey; the lactic acid is dissolved by alkohol, which does not unite with the sugar of milk and other foreign matters;[Pg 279] these are separated by filtration from the alkohol and acid; and the alkohol being evaporated, or distilled off, leaves the lactic acid behind.

This acid unites with all the salifiable bases forming salts which do not cristallize; and it seems considerably to resemble the acetous acid.[Pg 280]

Table of the Combinations of Saccholactic Acid with the Salifiable Bases, in the Order of Affinity.

Note.—All these were unknown to the ancient chemists.—A.[Pg 281]

Sect. XL.—Observations upon Saccholactic Acid, and its Combinations.

A species of sugar may be extracted, by evaporation, from whey, which has long been known in pharmacy, and which has a considerable resemblance to that procured from sugar canes. This saccharine matter, like ordinary sugar, may be oxygenated by means of nitric acid: For this purpose, several portions of nitric acid are distilled from it; the remaining liquid is evaporated, and set to cristallize, by which means cristals of oxalic acid are procured; at the same time a very fine white powder precipitates, which is the saccholactic acid discovered by Scheele. It is susceptible of combining with the alkalies, ammoniac, the earths, and even with the metals: Its action upon the latter is hitherto but little known, except that, with them, it forms difficultly soluble salts. The order of affinity in the table is taken from Bergman.[Pg 282]

Table of the Combinations of Formic Acid, with the Salifiable Bases, in the Order of Affinity.

Note.—All unknown to the ancient chemists.—A.[Pg 283]

Sect. XLI.—Observations upon Formic Acid, and its Combinations.

This acid was first obtained by distillation from ants, in the last century, by Samuel Fisher. The subject was treated of by Margraff in 1749, and by Messrs Ardwisson and Ochrn of Leipsic in 1777. The formic acid is drawn from a large species of red ants, formica rufa, Lin. which form large ant hills in woody places. It is procured, either by distilling the ants with a gentle heat in a glass retort or an alembic; or, after having washed the ants in cold water, and dried them upon a cloth, by pouring on boiling water, which dissolves the acid; or the acid may be procured by gentle expression from the insects, in which case it is stronger than in any of the former ways. To obtain it pure, we must rectify, by means of distillation, which separates it from the uncombined oily and charry matter; and it may be concentrated by freezing, in the manner recommended for treating the acetous acid.[Pg 284]

Sect. XLII.—Observations upon Bombic Acid, and its Combinations with Acidifiable Bases[52].

The juices of the silk worm seem to assume an acid quality when that insect changes from a larva to a chrysalis. At the moment of its escape from the latter to the butterfly form, it emits a reddish liquor which reddens blue paper, and which was first attentively observed by Mr Chaussier of the Dijon academy, who obtains the acid by infusing silk worm chrysalids in alkohol, which dissolves their acid without being charged with any of the gummy parts of the insect; and, by evaporating the alkohol, the acid remains tollerably pure. The properties and affinities of this acid are not hitherto ascertained with any precision; and we have reason to believe that analogous acids may be procured from other insects. The radical of this acid is probably, like that of the other acids from the animal kingdom, composed of charcoal, hydrogen, and azote, with the addition, perhaps, of phosphorus.

[Pg 285]

Table of the Combinations of Sebacic Acid, with the Salifiable Bases, in the Order of Affinity.

Note.—All these were unknown to the ancient chemists.—A.[Pg 286]

Sect. XLIII.—Observations upon Sebacid Acid, and its Combinations.

To obtain the sebacic acid, let some suet be melted in a skillet over the fire, alongst with some quick-lime in fine powder, and constantly stirred, raising the fire towards the end of the operation, and taking care to avoid the vapours, which are very offensive. By this process the sebacic acid unites with the lime into a sebat of lime, which is difficultly soluble in water; it is, however, separated from the fatty matters with which it is mixed by solution in a large quantity of boiling water. From this the neutral salt is separated by evaporation; and, to render it pure, is calcined, redissolved, and again cristallized. After this we pour on a proper quantity of sulphuric acid, and the sebacic acid passes over by distillation.[Pg 287]

Sect. XLIV.—Observations upon the Lithic Acid, and its Combinations with the Salifiable Bases[53].

From the later experiments of Bergman and Scheele, the urinary calculus appears to be a species of salt with an earthy basis; it is slightly acidulous, and requires a large quantity of water for solution, three grains being scarcely soluble in a thousand grains of boiling water, and the greater part again cristallizes when cold. To this concrete acid, which Mr de Morveau calls Lithiasic Acid, we give the name of Lithic Acid, the nature and properties of which are hitherto very little known. There is some appearance that it is an acidulous neutral salt, or acid combined in excess with a salifiable base; and I have reason to believe that it really is an acidulous phosphat of lime; if so, it must be excluded from the class of peculiar acids.

[Pg 288]

Table of the Combinations of the Prussic Acid with the Salifiable Bases, in the order of affinity.